SYNTHESE DIRECTE DE DICHLORURE DE DIALCOYLETAIN

1,222,642. Dialkyl tin dichlorides. CARLISLE CHEMICAL WORKS Inc. 3 Jan., 1969 [25 Jan., 1968], No. 574/69. Heading C2J. (R1) 2 SnCl 2 , where the groups R1, which may be the same or different, are alkyl groups having 1 to 4 carbon atoms, is prepared by reacting tin with at least one alkyl chloride R...

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K.R. MOLT
description 1,222,642. Dialkyl tin dichlorides. CARLISLE CHEMICAL WORKS Inc. 3 Jan., 1969 [25 Jan., 1968], No. 574/69. Heading C2J. (R1) 2 SnCl 2 , where the groups R1, which may be the same or different, are alkyl groups having 1 to 4 carbon atoms, is prepared by reacting tin with at least one alkyl chloride R1Cl in the presence of a quaternary ammonium or phosphonium iodide, or a tertiary ammonium or phosphonium diiodide (the ammonium compounds containing at least 6 carbon atoms), separating the product and recycling the residue, which contains other tin compounds and catalyst, to form more (R1) 2 SnCl 2 by reacting R1Cl and tin in its presence. The catalyst may be formed in situ, for example, by reacting an alkyl iodide with a secondary or tertiary phosphine. Preferably the recycling is performed at least 4 times.
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(R1) 2 SnCl 2 , where the groups R1, which may be the same or different, are alkyl groups having 1 to 4 carbon atoms, is prepared by reacting tin with at least one alkyl chloride R1Cl in the presence of a quaternary ammonium or phosphonium iodide, or a tertiary ammonium or phosphonium diiodide (the ammonium compounds containing at least 6 carbon atoms), separating the product and recycling the residue, which contains other tin compounds and catalyst, to form more (R1) 2 SnCl 2 by reacting R1Cl and tin in its presence. The catalyst may be formed in situ, for example, by reacting an alkyl iodide with a secondary or tertiary phosphine. 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MOLT</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>SYNTHESE DIRECTE DE DICHLORURE DE DIALCOYLETAIN</title><date>1971-07-19</date><risdate>1971</risdate><abstract>1,222,642. Dialkyl tin dichlorides. CARLISLE CHEMICAL WORKS Inc. 3 Jan., 1969 [25 Jan., 1968], No. 574/69. Heading C2J. (R1) 2 SnCl 2 , where the groups R1, which may be the same or different, are alkyl groups having 1 to 4 carbon atoms, is prepared by reacting tin with at least one alkyl chloride R1Cl in the presence of a quaternary ammonium or phosphonium iodide, or a tertiary ammonium or phosphonium diiodide (the ammonium compounds containing at least 6 carbon atoms), separating the product and recycling the residue, which contains other tin compounds and catalyst, to form more (R1) 2 SnCl 2 by reacting R1Cl and tin in its presence. The catalyst may be formed in situ, for example, by reacting an alkyl iodide with a secondary or tertiary phosphine. 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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
title SYNTHESE DIRECTE DE DICHLORURE DE DIALCOYLETAIN
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