Aqueous dye solutions

Concentrated aqueous dye solutions (A) and (B) contain NOTLESS 5 wt.% red disazo dye of formula (I), formic acid or a 1-4 carbon (C) alkylcarboxylic acid, water and optionally other additives. Concentrate (A) also contains a solvent aid, whilst (B) contains no solvent aid and < 1 wt.% alkali hali...

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Hauptverfasser: ADOLF KASER, ALFRED HOHENER, ROLAND FRICK
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ALFRED HOHENER
ROLAND FRICK
description Concentrated aqueous dye solutions (A) and (B) contain NOTLESS 5 wt.% red disazo dye of formula (I), formic acid or a 1-4 carbon (C) alkylcarboxylic acid, water and optionally other additives. Concentrate (A) also contains a solvent aid, whilst (B) contains no solvent aid and < 1 wt.% alkali halide; (where R, R1 = hydrogen (H), chlorine (Cl), methyl (Me) or methoxy (MeO); R2, R3 = H, Me or MeO; R-4, R5 = H or 1-4 C alkyl; A = alkylene, optionally with oxygen (O) in the chain; R6, R7 = H or 1-6 C alkyl; or NR6R7 = an optionally substituted 5-, 6- or 7-membered ring, which may contains other hetero-atom(s)). Preferably the solvent aid is selected from: (i) alkali metal and ammonium salts of 1-4 C alkylcarboxylic acids; (ii) low molecular acid amides; (iii) low molecular lactams or lactones; and (iv) alkanolamines or their reaction products with ethylene oxide and/or propylene oxide. Especially suitable compounds are sodium or ammonium acetate, formamide, urea, epsilon -caprolactam or a compound of formula N-ÄCH2-CH2O-(CH(R8)(R9)CH-O)pCH3 (II); p = 1-6, especially 1; one of R8 and R9 = H and the other = H or Me. The solution contains 6-20, especially 8-10 wt.% (I) and 3-20, especially 6-15 wt.% 1-4 C alkylcarboxylic acid. The amount of solvent aid in (A) is 1-5, especially 1-3 wt.% (i) or 3-20, especially 6-15 wt.% (ii), (iii) or (iv).
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Concentrate (A) also contains a solvent aid, whilst (B) contains no solvent aid and &lt; 1 wt.% alkali halide; (where R, R1 = hydrogen (H), chlorine (Cl), methyl (Me) or methoxy (MeO); R2, R3 = H, Me or MeO; R-4, R5 = H or 1-4 C alkyl; A = alkylene, optionally with oxygen (O) in the chain; R6, R7 = H or 1-6 C alkyl; or NR6R7 = an optionally substituted 5-, 6- or 7-membered ring, which may contains other hetero-atom(s)). Preferably the solvent aid is selected from: (i) alkali metal and ammonium salts of 1-4 C alkylcarboxylic acids; (ii) low molecular acid amides; (iii) low molecular lactams or lactones; and (iv) alkanolamines or their reaction products with ethylene oxide and/or propylene oxide. Especially suitable compounds are sodium or ammonium acetate, formamide, urea, epsilon -caprolactam or a compound of formula N-ÄCH2-CH2O-(CH(R8)(R9)CH-O)pCH3 (II); p = 1-6, especially 1; one of R8 and R9 = H and the other = H or Me. The solution contains 6-20, especially 8-10 wt.% (I) and 3-20, especially 6-15 wt.% 1-4 C alkylcarboxylic acid. 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Concentrate (A) also contains a solvent aid, whilst (B) contains no solvent aid and &lt; 1 wt.% alkali halide; (where R, R1 = hydrogen (H), chlorine (Cl), methyl (Me) or methoxy (MeO); R2, R3 = H, Me or MeO; R-4, R5 = H or 1-4 C alkyl; A = alkylene, optionally with oxygen (O) in the chain; R6, R7 = H or 1-6 C alkyl; or NR6R7 = an optionally substituted 5-, 6- or 7-membered ring, which may contains other hetero-atom(s)). Preferably the solvent aid is selected from: (i) alkali metal and ammonium salts of 1-4 C alkylcarboxylic acids; (ii) low molecular acid amides; (iii) low molecular lactams or lactones; and (iv) alkanolamines or their reaction products with ethylene oxide and/or propylene oxide. Especially suitable compounds are sodium or ammonium acetate, formamide, urea, epsilon -caprolactam or a compound of formula N-ÄCH2-CH2O-(CH(R8)(R9)CH-O)pCH3 (II); p = 1-6, especially 1; one of R8 and R9 = H and the other = H or Me. The solution contains 6-20, especially 8-10 wt.% (I) and 3-20, especially 6-15 wt.% 1-4 C alkylcarboxylic acid. 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Concentrate (A) also contains a solvent aid, whilst (B) contains no solvent aid and &lt; 1 wt.% alkali halide; (where R, R1 = hydrogen (H), chlorine (Cl), methyl (Me) or methoxy (MeO); R2, R3 = H, Me or MeO; R-4, R5 = H or 1-4 C alkyl; A = alkylene, optionally with oxygen (O) in the chain; R6, R7 = H or 1-6 C alkyl; or NR6R7 = an optionally substituted 5-, 6- or 7-membered ring, which may contains other hetero-atom(s)). Preferably the solvent aid is selected from: (i) alkali metal and ammonium salts of 1-4 C alkylcarboxylic acids; (ii) low molecular acid amides; (iii) low molecular lactams or lactones; and (iv) alkanolamines or their reaction products with ethylene oxide and/or propylene oxide. Especially suitable compounds are sodium or ammonium acetate, formamide, urea, epsilon -caprolactam or a compound of formula N-ÄCH2-CH2O-(CH(R8)(R9)CH-O)pCH3 (II); p = 1-6, especially 1; one of R8 and R9 = H and the other = H or Me. The solution contains 6-20, especially 8-10 wt.% (I) and 3-20, especially 6-15 wt.% 1-4 C alkylcarboxylic acid. The amount of solvent aid in (A) is 1-5, especially 1-3 wt.% (i) or 3-20, especially 6-15 wt.% (ii), (iii) or (iv).</abstract><edition>6</edition><oa>free_for_read</oa></addata></record>
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subjects ADHESIVES
CHEMISTRY
DYES
IMPREGNATING OR COATING OF PAPER
LAKES
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
MORDANTS
NATURAL RESINS
ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES
PAINTS
PAPER NOT OTHERWISE PROVIDED FOR
PAPER-MAKING
POLISHES
PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D
PRODUCTION OF CELLULOSE
PULP COMPOSITIONS
TEXTILES
TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G
title Aqueous dye solutions
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