Silicone macromonomers and methods of preparation thereof

A composition which is curable to an elastomer comprising: A polymer or mixture of polymers of the formula wherein: X are monovalent moieties having ethylenic unsaturation which can be the same or different; Y are divalent linking groups which can be the same or different; m is an integer of 0 to 1;...

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Hauptverfasser: MIECZYSLAW HENRYK MAZUREK, CHARLES MARTIN LEIR, ROBERT KENNETH GALKIEWICZ, YVAN ADRIEN BOGAERT, STEVEN SHEPARD KANTNER, AUDREY ANNE SHERMAN
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creator MIECZYSLAW HENRYK MAZUREK
CHARLES MARTIN LEIR
ROBERT KENNETH GALKIEWICZ
YVAN ADRIEN BOGAERT
STEVEN SHEPARD KANTNER
AUDREY ANNE SHERMAN
description A composition which is curable to an elastomer comprising: A polymer or mixture of polymers of the formula wherein: X are monovalent moieties having ethylenic unsaturation which can be the same or different; Y are divalent linking groups which can be the same or different; m is an integer of 0 to 1; D are monovalent moieties which can be the same or different selected from the group consisting of hydrogen, an alkyl group of 1 to about 10 carbon atoms, aryl, and substituted aryl; R are divalent hydrocarbon groups which can be the same or different; R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl; R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl; R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; and n is an integer of about 270 to about 1000. A composition which is curable to a pressure sensitive adhesive comprising the above polymer and a sufficient amount of tackifier. The invention also relates to fluorosilane compounds useful in the preparation of silicone macromonomer, their preparation and the preparation of silicone macromonomer.
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Y are divalent linking groups which can be the same or different; m is an integer of 0 to 1; D are monovalent moieties which can be the same or different selected from the group consisting of hydrogen, an alkyl group of 1 to about 10 carbon atoms, aryl, and substituted aryl; R are divalent hydrocarbon groups which can be the same or different; R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl; R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl; R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, vinyl, aryl, and substituted aryl; and n is an integer of about 270 to about 1000. A composition which is curable to a pressure sensitive adhesive comprising the above polymer and a sufficient amount of tackifier. The invention also relates to fluorosilane compounds useful in the preparation of silicone macromonomer, their preparation and the preparation of silicone macromonomer.</abstract><edition>5</edition><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE
ADHESIVES
CHEMISTRY
COMPOSITIONS BASED THEREON
DYES
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
MISCELLANEOUS APPLICATIONS OF MATERIALS
MISCELLANEOUS COMPOSITIONS
NATURAL RESINS
NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
PAINTS
POLISHES
THEIR PREPARATION OR CHEMICAL WORKING-UP
USE OF MATERIALS AS ADHESIVES
title Silicone macromonomers and methods of preparation thereof
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