POLYURETHANE FROM POLYOL CONTAINING DISPERSED ACRYLONITRILE POLYMER
A normally liquid, stable polymer/polyol composition which imparts improved combustion resistance to polyurethane foams prepared therefrom while retaining satisfactory foam tensile properties are formed by polymerizing in the presence of a free radical catalyst and in the essential absence of an alk...
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creator | FRANK EDWARD CRITCHFIELD RICHARD CREBS MYERLY DONALD WAYNE SIMROTH |
description | A normally liquid, stable polymer/polyol composition which imparts improved combustion resistance to polyurethane foams prepared therefrom while retaining satisfactory foam tensile properties are formed by polymerizing in the presence of a free radical catalyst and in the essential absence of an alkyl mercaptan, (1) from about 25 to about 60 weight percent of an ethylenically unsaturated monomer or monomers, for example, a mixture of acrylonitrile and styrene in weight ratio respectively of 25:75 to 0:100, dissolved or dispersed in (2) from about 40 to about 75 weight precent of a polyol comprising a base polyol having a hydroxyl number of less than about 150, wherein the polymer is characterized by a crosslinking coefficient of less than 55 and an intrinsic viscosity of at least 0.30.The resulting polymer/polyol composition is treated to reduce the product viscosity to essentially the indigenous system viscosity in polymer/polyol compositions of this type. |
format | Patent |
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RICHARD CREBS MYERLY ; DONALD WAYNE SIMROTH</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_AU589595BB23</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>1989</creationdate><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS</topic><topic>METALLURGY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><toplevel>online_resources</toplevel><creatorcontrib>FRANK EDWARD CRITCHFIELD</creatorcontrib><creatorcontrib>RICHARD CREBS MYERLY</creatorcontrib><creatorcontrib>DONALD WAYNE SIMROTH</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>FRANK EDWARD CRITCHFIELD</au><au>RICHARD CREBS MYERLY</au><au>DONALD WAYNE SIMROTH</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>POLYURETHANE FROM POLYOL CONTAINING DISPERSED ACRYLONITRILE POLYMER</title><date>1989-10-19</date><risdate>1989</risdate><abstract>A normally liquid, stable polymer/polyol composition which imparts improved combustion resistance to polyurethane foams prepared therefrom while retaining satisfactory foam tensile properties are formed by polymerizing in the presence of a free radical catalyst and in the essential absence of an alkyl mercaptan, (1) from about 25 to about 60 weight percent of an ethylenically unsaturated monomer or monomers, for example, a mixture of acrylonitrile and styrene in weight ratio respectively of 25:75 to 0:100, dissolved or dispersed in (2) from about 40 to about 75 weight precent of a polyol comprising a base polyol having a hydroxyl number of less than about 150, wherein the polymer is characterized by a crosslinking coefficient of less than 55 and an intrinsic viscosity of at least 0.30.The resulting polymer/polyol composition is treated to reduce the product viscosity to essentially the indigenous system viscosity in polymer/polyol compositions of this type.</abstract><edition>4</edition><oa>free_for_read</oa></addata></record> |
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subjects | CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP |
title | POLYURETHANE FROM POLYOL CONTAINING DISPERSED ACRYLONITRILE POLYMER |
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