PROCESS FOR SEPARATING HAFNIUM AND ZIRCONIUM

A process for separating hafnium and zirconium, in particular from a sulfate based solution is provided. The process includes the steps of: concentrating an acidic sulfate based solution containing zirconium and hafnium, the solution having a hafnium:zirconium weight ratio as given by Hf/(Hf+Zr) gre...

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Hauptverfasser: FAINERMAN-MELNIKOVA, Marina, SOLDENHOFF, Karin Helene, QUINN, James, GOUGH, Ian
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SOLDENHOFF, Karin Helene
QUINN, James
GOUGH, Ian
description A process for separating hafnium and zirconium, in particular from a sulfate based solution is provided. The process includes the steps of: concentrating an acidic sulfate based solution containing zirconium and hafnium, the solution having a hafnium:zirconium weight ratio as given by Hf/(Hf+Zr) greater than the typical weight ratio of naturally occurring zirconium ores and/or concentrates; heating the solution; contacting the solution with an amine based solvent to create a hafnium rich, high purity rafinate and a zirconium loaded solvent; and stripping the zirconium loaded solvent to produce a stripped solvent and a zirconium loaded strip.
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subjects CHEMISTRY
COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F
FERROUS OR NON-FERROUS ALLOYS
INORGANIC CHEMISTRY
METALLURGY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PRETREATMENT OF RAW MATERIALS
PRODUCTION AND REFINING OF METALS
SEPARATION
TRANSPORTING
TREATMENT OF ALLOYS OR NON-FERROUS METALS
title PROCESS FOR SEPARATING HAFNIUM AND ZIRCONIUM
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