A method of continuous electrochemical dinitrogen reduction

A method of continuous electrochemical dinitrogen reduction

The invention provides a method of continuous electrochemical dinitrogen reduction to produce ammonia, the method comprising: supplying dinitrogen to an electrochemical cell comprising an electrolyte in contact with at least a cathode; introducing protons to the electrolyte by anodic oxidation of a...

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Hauptverfasser: MACFARLANE, Douglas R, SURYANTO, Bryan Harry Rahmat, SIMONOV, Alexandr Nikolaevich, MATUSZEK, Karolina, CHEREPANOV, Pavel
Format: Patent
Sprache:eng
Schlagworte:
AMMONIA
APPARATUS THEREFOR
CHEMISTRY
COMPOUNDS THEREOF
CYANOGEN
ELECTROLYTIC OR ELECTROPHORETIC PROCESSES
ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTIONOF COMPOUNDS OR NON-METALS
INORGANIC CHEMISTRY
METALLURGY
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creator MACFARLANE, Douglas R
SURYANTO, Bryan Harry Rahmat
SIMONOV, Alexandr Nikolaevich
MATUSZEK, Karolina
CHEREPANOV, Pavel
description The invention provides a method of continuous electrochemical dinitrogen reduction to produce ammonia, the method comprising: supplying dinitrogen to an electrochemical cell comprising an electrolyte in contact with at least a cathode; introducing protons to the electrolyte by anodic oxidation of a hydrogen-containing species; and cathodically reducing the dinitrogen in the presence of a metal selected from lithium, magnesium, calcium, strontium, barium, zinc, aluminium and vanadium to produce ammonia, wherein the electrolyte comprises a cationic proton carrier capable of reversible deprotonation to form a neutral proton acceptor, wherein the neutral proton acceptor is an ylide.
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subjects AMMONIA
APPARATUS THEREFOR
CHEMISTRY
COMPOUNDS THEREOF
CYANOGEN
ELECTROLYTIC OR ELECTROPHORETIC PROCESSES
ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTIONOF COMPOUNDS OR NON-METALS
INORGANIC CHEMISTRY
METALLURGY
title A method of continuous electrochemical dinitrogen reduction
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