Method for polymerizing monomers to produce linear, low density polymer

A method for producing a low density copolymer of ethylene and 1-hexene having a density in the range of about 0.915 to about 0.930 grams/cc in a continuous loop reactor under slurry phase reactor conditions in the presence of a liquid diluent comprising (a) using a prepolymerized solid particulate...

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Hauptverfasser: MICHAEL CURTIS CARTER, ROBERT WILLIAM BOHMER, CARLETON E. STOUFFER, STEVEN JOSEPH SECORA, ELIZABETH ANN BENHAM, JOSE MANUEL DIONISIO, JOHN NORMAN DEGOOD III
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creator MICHAEL CURTIS CARTER
ROBERT WILLIAM BOHMER
CARLETON E. STOUFFER
STEVEN JOSEPH SECORA
ELIZABETH ANN BENHAM
JOSE MANUEL DIONISIO
JOHN NORMAN DEGOOD III
description A method for producing a low density copolymer of ethylene and 1-hexene having a density in the range of about 0.915 to about 0.930 grams/cc in a continuous loop reactor under slurry phase reactor conditions in the presence of a liquid diluent comprising (a) using a prepolymerized solid particulate metallocene catalyst system, (b) combining the catalyst system with a liquid diluent, and (c) agitating the mixture of (b) to form a liquid mixture containing catalyst system particles that are substantially uniform in size, (d) passing this liquid mixture into the loop reactor, (e) not adding any hydrogen, (f) employing the temperature in the range of about 170 DEG F. to about 180 DEG F., (g) employing ethylene in an amount equal to about 5 to about 6 weight % of the liquid diluent and the loop reactor, and (h) employing 1-hexene in an amount equal to about 1.5 to about 2.5 weight % of the liquid diluent in the loop reactor.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title Method for polymerizing monomers to produce linear, low density polymer
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