Iron oxide nanoparticle dispersions and fuel additives for soot combustion

Aqueous and substantially crystalline iron oxide nanoparticle dispersions and processes for making them are disclosed. The nanoparticle size and size distribution width are advantageous for use in a fuel additive for catalytic reduction of soot combustion in diesel particulate filters. Nanoparticles...

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Hauptverfasser: Irving, Lyn Marie, Hailstone, Richard Kenneth, Difrancesco, Albert Gary, Sandford, David Wallace
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creator Irving, Lyn Marie
Hailstone, Richard Kenneth
Difrancesco, Albert Gary
Sandford, David Wallace
description Aqueous and substantially crystalline iron oxide nanoparticle dispersions and processes for making them are disclosed. The nanoparticle size and size distribution width are advantageous for use in a fuel additive for catalytic reduction of soot combustion in diesel particulate filters. Nanoparticles of the aqueous colloid are transferred to a substantially non-polar liquid comprising a carboxylic acid and one or more low-polarity solvents. The transfer is achieved by mixing the aqueous and substantially non-polar materials, forming an emulsion, followed by a phase separation into a substantially metal-free remnant polar phase and a substantially non-polar organic colloid phase. A method for rapid and substantially complete transfer of non-agglomerated nanoparticles to the low polarity phase in the presence of an organic amine, and a rapid phase separation of the substantially non-polar colloid from a remnant aqueous phase, are provided.
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The nanoparticle size and size distribution width are advantageous for use in a fuel additive for catalytic reduction of soot combustion in diesel particulate filters. Nanoparticles of the aqueous colloid are transferred to a substantially non-polar liquid comprising a carboxylic acid and one or more low-polarity solvents. The transfer is achieved by mixing the aqueous and substantially non-polar materials, forming an emulsion, followed by a phase separation into a substantially metal-free remnant polar phase and a substantially non-polar organic colloid phase. 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subjects ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSESC01D OR C01F
FIRELIGHTERS
FUELS
FUELS NOT OTHERWISE PROVIDED FOR
INORGANIC CHEMISTRY
LIQUEFIED PETROLEUM GAS
LUBRICANTS
METALLURGY
NATURAL GAS
PEAT
PERFORMING OPERATIONS
PETROLEUM, GAS OR COKE INDUSTRIES
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K
TECHNICAL GASES CONTAINING CARBON MONOXIDE
THEIR RELEVANT APPARATUS
TRANSPORTING
title Iron oxide nanoparticle dispersions and fuel additives for soot combustion
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