Ceramic with perovskite structure, use thereof as ph measuring electrode

The invention concerns a ceramic, a method for preparing same, and a pH measuring electrode containing same. The ceramic has a perovskite structure and the following properties: its composition is of formula L(2/3)-xA3x (1/3)-2xEO3, wherein L is Bi, Sb, a lanthanide or an alkaline-earth metal; A is...

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Hauptverfasser: ANDRE LEBLE, CLAUDE BOHNKE, ODILE BOHNKE, JEAN-LOUIS FOURQUET, HUGUETTE DUROY
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creator ANDRE LEBLE
CLAUDE BOHNKE
ODILE BOHNKE
JEAN-LOUIS FOURQUET
HUGUETTE DUROY
description The invention concerns a ceramic, a method for preparing same, and a pH measuring electrode containing same. The ceramic has a perovskite structure and the following properties: its composition is of formula L(2/3)-xA3x (1/3)-2xEO3, wherein L is Bi, Sb, a lanthanide or an alkaline-earth metal; A is Ag or an alkali metal; E is a transition metal oxidizable up to +5 oxidation level, alone or combined with Al or a transition metal oxidizable up to +5 or +6 oxidation level, is a vacancy and 0.06
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The ceramic has a perovskite structure and the following properties: its composition is of formula L(2/3)-xA3x (1/3)-2xEO3, wherein L is Bi, Sb, a lanthanide or an alkaline-earth metal; A is Ag or an alkali metal; E is a transition metal oxidizable up to +5 oxidation level, alone or combined with Al or a transition metal oxidizable up to +5 or +6 oxidation level, is a vacancy and 0.06&lt;/=x&lt;/=0.16; it consists mainly of regular interstice-free octahedral grains having a dimension of the order of 1 to 3 mu m; it has a specific surface area ranging between 20000 cm /g and 30000 cm /g.</description><edition>7</edition><language>eng</language><subject>ARTIFICIAL STONE ; BASIC ELECTRIC ELEMENTS ; CEMENTS ; CERAMICS ; CHEMISTRY ; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDINGMATERIALS ; CONCRETE ; ELECTRICITY ; INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIRCHEMICAL OR PHYSICAL PROPERTIES ; LIME, MAGNESIA ; MEASURING ; METALLURGY ; PERFORMING OPERATIONS ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; PHYSICS ; PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY ; REFRACTORIES ; SEPARATION ; SLAG ; TESTING ; TRANSPORTING ; TREATMENT OF NATURAL STONE</subject><creationdate>2004</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20040319&amp;DB=EPODOC&amp;CC=AU&amp;NR=2003274273A8$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76289</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20040319&amp;DB=EPODOC&amp;CC=AU&amp;NR=2003274273A8$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>ANDRE LEBLE</creatorcontrib><creatorcontrib>CLAUDE BOHNKE</creatorcontrib><creatorcontrib>ODILE BOHNKE</creatorcontrib><creatorcontrib>JEAN-LOUIS FOURQUET</creatorcontrib><creatorcontrib>HUGUETTE DUROY</creatorcontrib><title>Ceramic with perovskite structure, use thereof as ph measuring electrode</title><description>The invention concerns a ceramic, a method for preparing same, and a pH measuring electrode containing same. 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subjects ARTIFICIAL STONE
BASIC ELECTRIC ELEMENTS
CEMENTS
CERAMICS
CHEMISTRY
COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDINGMATERIALS
CONCRETE
ELECTRICITY
INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIRCHEMICAL OR PHYSICAL PROPERTIES
LIME, MAGNESIA
MEASURING
METALLURGY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PHYSICS
PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY
REFRACTORIES
SEPARATION
SLAG
TESTING
TRANSPORTING
TREATMENT OF NATURAL STONE
title Ceramic with perovskite structure, use thereof as ph measuring electrode
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