Regeneration of supported catalysts for carbon monoxide hydrogenation
There is provided a process for renewing the activity of used, supported metal catalysts for the hydrogenation of carbon monoxide to form a mixture of hydrocarbons comprising decreasing the hydrocarbon content of the catalyst, impregnating said catalyst under an non-oxidative atmosphere with a solut...
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| creator | JANET RENEE CLARK MICHEL DAAGE RUSSELL JOHN KOVEAL |
| description | There is provided a process for renewing the activity of used, supported metal catalysts for the hydrogenation of carbon monoxide to form a mixture of hydrocarbons comprising decreasing the hydrocarbon content of the catalyst, impregnating said catalyst under an non-oxidative atmosphere with a solution at least one weak organic acid, preferably a mono- or di-carboxylic acid, to the point where it has absorbed a volume of said solution equal to at least about 10% of its calculated pore volume, oxidizing the catalyst with a gaseous oxidant in the presence of the impregnating solution and activating the catalyst by reduction with hydrogen at elevated temperatures. Optionally, the catalyst is calcined after the oxidation step, and passivated after the activation step. A preferred means of decreasing the hydrocarbon content of the catalyst is contacting it with a hydrogen-containing gas at elevated temperatures. |
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Optionally, the catalyst is calcined after the oxidation step, and passivated after the activation step. A preferred means of decreasing the hydrocarbon content of the catalyst is contacting it with a hydrogen-containing gas at elevated temperatures.</description><language>eng</language><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS ; APPARATUS THEREFOR ; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY ; CHEMISTRY ; CRACKING HYDROCARBON OILS ; FUELS ; GENERAL METHODS OF ORGANIC CHEMISTRY ; LUBRICANTS ; METALLURGY ; MINERAL WAXES ; ORGANIC CHEMISTRY ; PEAT ; PERFORMING OPERATIONS ; PETROLEUM, GAS OR COKE INDUSTRIES ; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL ; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION ; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES ; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS ; REFORMING OF NAPHTHA ; TECHNICAL GASES CONTAINING CARBON MONOXIDE ; THEIR RELEVANT APPARATUS ; TRANSPORTING</subject><creationdate>2008</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20080403&DB=EPODOC&CC=AU&NR=2002358297B2$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,780,885,25564,76547</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20080403&DB=EPODOC&CC=AU&NR=2002358297B2$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>JANET RENEE CLARK</creatorcontrib><creatorcontrib>MICHEL DAAGE</creatorcontrib><creatorcontrib>RUSSELL JOHN KOVEAL</creatorcontrib><title>Regeneration of supported catalysts for carbon monoxide hydrogenation</title><description>There is provided a process for renewing the activity of used, supported metal catalysts for the hydrogenation of carbon monoxide to form a mixture of hydrocarbons comprising decreasing the hydrocarbon content of the catalyst, impregnating said catalyst under an non-oxidative atmosphere with a solution at least one weak organic acid, preferably a mono- or di-carboxylic acid, to the point where it has absorbed a volume of said solution equal to at least about 10% of its calculated pore volume, oxidizing the catalyst with a gaseous oxidant in the presence of the impregnating solution and activating the catalyst by reduction with hydrogen at elevated temperatures. 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A preferred means of decreasing the hydrocarbon content of the catalyst is contacting it with a hydrogen-containing gas at elevated temperatures.</description><subject>ACYCLIC OR CARBOCYCLIC COMPOUNDS</subject><subject>APPARATUS THEREFOR</subject><subject>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</subject><subject>CHEMISTRY</subject><subject>CRACKING HYDROCARBON OILS</subject><subject>FUELS</subject><subject>GENERAL METHODS OF ORGANIC CHEMISTRY</subject><subject>LUBRICANTS</subject><subject>METALLURGY</subject><subject>MINERAL WAXES</subject><subject>ORGANIC CHEMISTRY</subject><subject>PEAT</subject><subject>PERFORMING OPERATIONS</subject><subject>PETROLEUM, GAS OR COKE INDUSTRIES</subject><subject>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</subject><subject>PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION</subject><subject>RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES</subject><subject>REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS</subject><subject>REFORMING OF NAPHTHA</subject><subject>TECHNICAL GASES CONTAINING CARBON MONOXIDE</subject><subject>THEIR RELEVANT APPARATUS</subject><subject>TRANSPORTING</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2008</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZHANSk1PzUstSizJzM9TyE9TKC4tKMgvKklNUUhOLEnMqSwuKVZIyy8C8oqSgCpy8_PyKzJTUhUyKlOK8oFawRp5GFjTEnOKU3mhNDeDiptriLOHbmpBfnxqcUFiMtCOknjHUCMDAyNjUwsjS3MnJyNjIpUBAJd8NYI</recordid><startdate>20080403</startdate><enddate>20080403</enddate><creator>JANET RENEE CLARK</creator><creator>MICHEL DAAGE</creator><creator>RUSSELL JOHN KOVEAL</creator><scope>EVB</scope></search><sort><creationdate>20080403</creationdate><title>Regeneration of supported catalysts for carbon monoxide hydrogenation</title><author>JANET RENEE CLARK ; MICHEL DAAGE ; RUSSELL JOHN KOVEAL</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_AU2002358297BB23</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2008</creationdate><topic>ACYCLIC OR CARBOCYCLIC COMPOUNDS</topic><topic>APPARATUS THEREFOR</topic><topic>CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY</topic><topic>CHEMISTRY</topic><topic>CRACKING HYDROCARBON OILS</topic><topic>FUELS</topic><topic>GENERAL METHODS OF ORGANIC CHEMISTRY</topic><topic>LUBRICANTS</topic><topic>METALLURGY</topic><topic>MINERAL WAXES</topic><topic>ORGANIC CHEMISTRY</topic><topic>PEAT</topic><topic>PERFORMING OPERATIONS</topic><topic>PETROLEUM, GAS OR COKE INDUSTRIES</topic><topic>PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL</topic><topic>PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION</topic><topic>RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES</topic><topic>REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS</topic><topic>REFORMING OF NAPHTHA</topic><topic>TECHNICAL GASES CONTAINING CARBON MONOXIDE</topic><topic>THEIR RELEVANT APPARATUS</topic><topic>TRANSPORTING</topic><toplevel>online_resources</toplevel><creatorcontrib>JANET RENEE CLARK</creatorcontrib><creatorcontrib>MICHEL DAAGE</creatorcontrib><creatorcontrib>RUSSELL JOHN KOVEAL</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>JANET RENEE CLARK</au><au>MICHEL DAAGE</au><au>RUSSELL JOHN KOVEAL</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Regeneration of supported catalysts for carbon monoxide hydrogenation</title><date>2008-04-03</date><risdate>2008</risdate><abstract>There is provided a process for renewing the activity of used, supported metal catalysts for the hydrogenation of carbon monoxide to form a mixture of hydrocarbons comprising decreasing the hydrocarbon content of the catalyst, impregnating said catalyst under an non-oxidative atmosphere with a solution at least one weak organic acid, preferably a mono- or di-carboxylic acid, to the point where it has absorbed a volume of said solution equal to at least about 10% of its calculated pore volume, oxidizing the catalyst with a gaseous oxidant in the presence of the impregnating solution and activating the catalyst by reduction with hydrogen at elevated temperatures. 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| subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY CHEMISTRY CRACKING HYDROCARBON OILS FUELS GENERAL METHODS OF ORGANIC CHEMISTRY LUBRICANTS METALLURGY MINERAL WAXES ORGANIC CHEMISTRY PEAT PERFORMING OPERATIONS PETROLEUM, GAS OR COKE INDUSTRIES PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS REFORMING OF NAPHTHA TECHNICAL GASES CONTAINING CARBON MONOXIDE THEIR RELEVANT APPARATUS TRANSPORTING |
| title | Regeneration of supported catalysts for carbon monoxide hydrogenation |
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