Lanthanide-promoted rhodium catalysts and process for producing synthesis gas

Lanthanide-promoted rhodium-containing supported catalysts that are active for catalyzing the net partial oxidation of methane to CO and H2 are disclosed, along with their manner of making and high efficiency processes for producing synthesis gas employing the new catalysts. A preferred catalyst com...

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Hauptverfasser: HAROLD A. WRIGHT, GLORIA I. STRAGUZZI, DAVID M. MINAHAN, DAXIANG WANG, SRIRAM RAMANI, LARRY D. SWINNEY, KEVIN L. RICKETSON, TIANYAN NIU, JOE, D. ALLISON, BAILI HU
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creator HAROLD A. WRIGHT
GLORIA I. STRAGUZZI
DAVID M. MINAHAN
DAXIANG WANG
SRIRAM RAMANI
LARRY D. SWINNEY
KEVIN L. RICKETSON
TIANYAN NIU
JOE, D. ALLISON
BAILI HU
description Lanthanide-promoted rhodium-containing supported catalysts that are active for catalyzing the net partial oxidation of methane to CO and H2 are disclosed, along with their manner of making and high efficiency processes for producing synthesis gas employing the new catalysts. A preferred catalyst comprises highly dispersed, high surface area rhodium on a granular zirconia support with an intermediate coating of a lanthanide metal and/or oxide thereof and is thermally conditioned during catalyst preparation. In a preferred syngas production process a stream of methane-containing gas and O2 is passed over a thermally conditioned, high surface area Rh/Sm/zirconia granular catalyst in a short contact time reactor to produce a mixture of carbon monoxide and hydrogen.
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subjects CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY
CHEMISTRY
COMPOUNDS THEREOF
INORGANIC CHEMISTRY
METALLURGY
NON-METALLIC ELEMENTS
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
THEIR RELEVANT APPARATUS
TRANSPORTING
title Lanthanide-promoted rhodium catalysts and process for producing synthesis gas
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