VERFAHREN ZUR GEMEINSAMEN ABTRENNUNG VON STOERELEMENTEN AUS WERTMETALL-ELEKTROLYTLOESUNGEN

A process for the common or simultaneous separation of arsenic, antimony, bismuth and iron from electrolyte solutions of valuable metals by solvent extraction and subsequent recovery of the contaminating elements, which process is characterized in that aqueous mineral-acidic electrolyte solutions of...

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Hauptverfasser: SUDDERTH, ROBERT BRANTLEY, KORDOSKY, GARY ALAN, SCHWAB, WERNER, KEHL, RALF
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creator SUDDERTH, ROBERT BRANTLEY
KORDOSKY, GARY ALAN
SCHWAB, WERNER
KEHL, RALF
description A process for the common or simultaneous separation of arsenic, antimony, bismuth and iron from electrolyte solutions of valuable metals by solvent extraction and subsequent recovery of the contaminating elements, which process is characterized in that aqueous mineral-acidic electrolyte solutions of valuable metals are admixed with a sparingly water soluble organic solvent containing at least one hydroxamic acid, the aqueous and organic phases are thoroughly mixed, the contaminating elements arsenic, antimony and bismuth are precipitated from the organic phase by direct sulfide precipitation, the sulfides are separated, and the extracted iron is subsequently reextracted with a water soluble iron-complexing agent into an aqueous phase and recovered.
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subjects APPARATUS THEREFOR
CHEMISTRY
ELECTROLYTIC OR ELECTROPHORETIC PROCESSES
FERROUS OR NON-FERROUS ALLOYS
METALLURGY
PERFORMING OPERATIONS
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
PRETREATMENT OF RAW MATERIALS
PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY ORREFINING OF METALS
PRODUCTION AND REFINING OF METALS
SEPARATION
TRANSPORTING
TREATMENT OF ALLOYS OR NON-FERROUS METALS
title VERFAHREN ZUR GEMEINSAMEN ABTRENNUNG VON STOERELEMENTEN AUS WERTMETALL-ELEKTROLYTLOESUNGEN
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