VERFAHREN ZUR HERSTELLUNG VON SALPETERSÄURE MIT EINER KONZENTRATION IM BEREICH VON 50 BIS 77,8 GEW

A process for preparing nitric acid by: catalytically oxidizing ammonia, to obtain a gas mixture containing NO and O2; cooling and condensing the gas mixture, thereby further oxidizing NO with O2, to obtain a gas stream containing NO2/N2O4 and an aqueous solution containing nitric acid; and counterc...

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Hauptverfasser: LOENING, JAN-MARTIN, KNEUPER, HEINZ-JOSEF, MOLLNER, STEPHANIE, NICKEL, JOERG TORSTEN
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KNEUPER, HEINZ-JOSEF
MOLLNER, STEPHANIE
NICKEL, JOERG TORSTEN
description A process for preparing nitric acid by: catalytically oxidizing ammonia, to obtain a gas mixture containing NO and O2; cooling and condensing the gas mixture, thereby further oxidizing NO with O2, to obtain a gas stream containing NO2/N2O4 and an aqueous solution containing nitric acid; and countercurrently absorbing the NO2/N2O4 from the gas stream in an absorber with process water (H2O), to obtain nitric acid and an NOx-containing absorber offgas, wherein the water content of the nitric acid is regulated to a concentration in the range from 50 to 77.8% by weight and the NOx content of the absorber offgas to a concentration in the range from 20 to 500 ppm, by continuously measuring the water content of the process air supplied to the catalytic gas phase oxidation and, as a function of this, adjusting the amount of process water (Q-H2O) fed to the absorber.
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title VERFAHREN ZUR HERSTELLUNG VON SALPETERSÄURE MIT EINER KONZENTRATION IM BEREICH VON 50 BIS 77,8 GEW
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