VERFAHREN ZUR HERSTELLUNG EINES BLOCKCOPOLYMERS

The invention relates to a process for the preparation of a block copolymer, the process being carried out in the presence of a multifunctional initiator and comprising at least one enzymatically catalyzed homo- or copolymerization reaction and at least one non-enzymatically catalyzed controlled hom...

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Hauptverfasser: THOMASSEN, PAUL, PALMANS, ANN, HEISE, ANDREAS
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creator THOMASSEN, PAUL
PALMANS, ANN
HEISE, ANDREAS
description The invention relates to a process for the preparation of a block copolymer, the process being carried out in the presence of a multifunctional initiator and comprising at least one enzymatically catalyzed homo- or copolymerization reaction and at least one non-enzymatically catalyzed controlled homo- or copolymerization reaction, wherein the non-enzymatically catalyzed controlled homo- or copolymerization reaction is chosen from the group comprising a free radical polymerization reaction, an ionic polymerization reaction, a polycondensation reaction, and a ring opening polymerization (ROP) reaction. The invention also relates to a chiral block copolymer wherein at least one block comprises at least one substituted epsilon-caprolactone derivative.
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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title VERFAHREN ZUR HERSTELLUNG EINES BLOCKCOPOLYMERS
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