POLYMERISATIONSVERFAHREN
A process of preparing water soluble or water swellable polymer comprising the steps, (a) forming an aqueous mixture comprising, (i) a water soluble ethylenically unsaturated monomer or blend of monomers and, (ii) an ultra violet initiator, (b) effecting polymerisation by subjecting the aqueous mixt...
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creator | RAISTRICK, LEE NAYLOR, GARETH IAN FLISHER, ANNE |
description | A process of preparing water soluble or water swellable polymer comprising the steps, (a) forming an aqueous mixture comprising, (i) a water soluble ethylenically unsaturated monomer or blend of monomers and, (ii) an ultra violet initiator, (b) effecting polymerisation by subjecting the aqueous mixture formed in step (a) to polymerisation conditions to form a polymer of said monomer or monomer blend, (c) subjecting the polymer formed in step (b) to ultra violet light radiation, characterised in that the polymerisation step (b) is conducted substantially in the absence of ultra violet radiation. In one preferred aspect the ultra violet initiator is distributed throughout the polymer formed in step (b). In another preferred aspect the step (c) is conducted ultra violet light at an intensity of up to 500 milli Watts/cm2. Also claimed is a method of reducing the residual monomer content in a water soluble or water swellable polymer by subjecting the polymer to ultra violet irradiation in the presence of an ultra violet initiator. The process is particularly suitable for making highly effective water soluble and water swellable polymers useful as flocculants, coagulants, rheology modifiers, dispersants, superabsorbents and binders etc. |
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In one preferred aspect the ultra violet initiator is distributed throughout the polymer formed in step (b). In another preferred aspect the step (c) is conducted ultra violet light at an intensity of up to 500 milli Watts/cm2. Also claimed is a method of reducing the residual monomer content in a water soluble or water swellable polymer by subjecting the polymer to ultra violet irradiation in the presence of an ultra violet initiator. The process is particularly suitable for making highly effective water soluble and water swellable polymers useful as flocculants, coagulants, rheology modifiers, dispersants, superabsorbents and binders etc.</description><edition>7</edition><language>ger</language><subject>AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; GENERAL PROCESSES OF COMPOUNDING ; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS ; METALLURGY ; ORGANIC MACROMOLECULAR COMPOUNDS ; THEIR PREPARATION OR CHEMICAL WORKING-UP ; WORKING-UP</subject><creationdate>2006</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20060915&DB=EPODOC&CC=AT&NR=E335769T1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,777,882,25545,76296</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&date=20060915&DB=EPODOC&CC=AT&NR=E335769T1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>RAISTRICK, LEE</creatorcontrib><creatorcontrib>NAYLOR, GARETH IAN</creatorcontrib><creatorcontrib>FLISHER, ANNE</creatorcontrib><title>POLYMERISATIONSVERFAHREN</title><description>A process of preparing water soluble or water swellable polymer comprising the steps, (a) forming an aqueous mixture comprising, (i) a water soluble ethylenically unsaturated monomer or blend of monomers and, (ii) an ultra violet initiator, (b) effecting polymerisation by subjecting the aqueous mixture formed in step (a) to polymerisation conditions to form a polymer of said monomer or monomer blend, (c) subjecting the polymer formed in step (b) to ultra violet light radiation, characterised in that the polymerisation step (b) is conducted substantially in the absence of ultra violet radiation. In one preferred aspect the ultra violet initiator is distributed throughout the polymer formed in step (b). In another preferred aspect the step (c) is conducted ultra violet light at an intensity of up to 500 milli Watts/cm2. Also claimed is a method of reducing the residual monomer content in a water soluble or water swellable polymer by subjecting the polymer to ultra violet irradiation in the presence of an ultra violet initiator. 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In one preferred aspect the ultra violet initiator is distributed throughout the polymer formed in step (b). In another preferred aspect the step (c) is conducted ultra violet light at an intensity of up to 500 milli Watts/cm2. Also claimed is a method of reducing the residual monomer content in a water soluble or water swellable polymer by subjecting the polymer to ultra violet irradiation in the presence of an ultra violet initiator. The process is particularly suitable for making highly effective water soluble and water swellable polymers useful as flocculants, coagulants, rheology modifiers, dispersants, superabsorbents and binders etc.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record> |
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subjects | AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G CHEMISTRY COMPOSITIONS BASED THEREON GENERAL PROCESSES OF COMPOUNDING MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP WORKING-UP |
title | POLYMERISATIONSVERFAHREN |
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