OLEFINPOLYMERISATIONSKATALYSATOREN

1. The invention concerns olefin polymerization catalyst component comprising an organometallic compound of general formula I wherein: M is a transition metal of groups 3, 4-10, lanthanide or actinide of the periodic table of the elements; each R is independently a structural bridge rigidly connecti...

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Hauptverfasser: ROYO GRACIA, PASCUAL, FLORES DE PACO, MIGUEL ANGEL, CANO SIERRA, JESUS, PENA GARCIA, BEGONA
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creator ROYO GRACIA, PASCUAL
FLORES DE PACO, MIGUEL ANGEL
CANO SIERRA, JESUS
PENA GARCIA, BEGONA
description 1. The invention concerns olefin polymerization catalyst component comprising an organometallic compound of general formula I wherein: M is a transition metal of groups 3, 4-10, lanthanide or actinide of the periodic table of the elements; each R is independently a structural bridge rigidly connecting two ligands L1, L2 and L3 and is constituted by 1 to 4 chain atoms selected from carbon, silicon, germanium, oxygen, boron; m, n and o are 0 or 1, with the proviso that m+n+o is 2 or 3; L1 is a ligand of the cyclopentadienyl type or is isolobal to cyclopentadienyl, L2 is a ligand of the cyclopentadienyl type or is isolobal to cyclopentadienyl, or a monovalent anionic ligand selected from the group consisting of N, P, B when m+n =2, it is selected from the group consisting of NR , PR , BR , O and S when m+n =1; L3 is a monovalent anionic ligand selected from the group consisting of N, P, B when n+o =2, it is selected from the group consisting of NR , PR , BR , O and S when n+o =1; R is hydrogen, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C3-C20 alkenyl, optionally comprising 1 to 5 heteroatoms such as Si, N, P, O, F, Cl, Br; each X is independently selected from the group consisting of hydrogen, halogen, NR 2, R with R equal to C1-C20 alkyl, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C3-C20 alkenyl, optionally comprising 1 to 5 heteroatoms such as Si, N, P, O, F, Cl, Br; q is a number whose value is: 0, 1, 2 or 3, depending on the valence of the metal M; D is a neutral Lewis base, p is a number whose value is: 0, 1, 2 or 3. The invention also concerns catalysts comprising compounds of formula (I) and the polymerization process making use of a catalyst comprising the claimed compounds.
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The invention concerns olefin polymerization catalyst component comprising an organometallic compound of general formula I wherein: M is a transition metal of groups 3, 4-10, lanthanide or actinide of the periodic table of the elements; each R is independently a structural bridge rigidly connecting two ligands L1, L2 and L3 and is constituted by 1 to 4 chain atoms selected from carbon, silicon, germanium, oxygen, boron; m, n and o are 0 or 1, with the proviso that m+n+o is 2 or 3; L1 is a ligand of the cyclopentadienyl type or is isolobal to cyclopentadienyl, L2 is a ligand of the cyclopentadienyl type or is isolobal to cyclopentadienyl, or a monovalent anionic ligand selected from the group consisting of N, P, B when m+n =2, it is selected from the group consisting of NR , PR , BR , O and S when m+n =1; L3 is a monovalent anionic ligand selected from the group consisting of N, P, B when n+o =2, it is selected from the group consisting of NR , PR , BR , O and S when n+o =1; R is hydrogen, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C3-C20 alkenyl, optionally comprising 1 to 5 heteroatoms such as Si, N, P, O, F, Cl, Br; each X is independently selected from the group consisting of hydrogen, halogen, NR 2, R with R equal to C1-C20 alkyl, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C3-C20 alkenyl, optionally comprising 1 to 5 heteroatoms such as Si, N, P, O, F, Cl, Br; q is a number whose value is: 0, 1, 2 or 3, depending on the valence of the metal M; D is a neutral Lewis base, p is a number whose value is: 0, 1, 2 or 3. The invention also concerns catalysts comprising compounds of formula (I) and the polymerization process making use of a catalyst comprising the claimed compounds.</description><edition>7</edition><language>ger</language><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM ; CHEMISTRY ; COMPOSITIONS BASED THEREON ; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS ; METALLURGY ; ORGANIC CHEMISTRY ; ORGANIC MACROMOLECULAR COMPOUNDS ; THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><creationdate>2004</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20040415&amp;DB=EPODOC&amp;CC=AT&amp;NR=E264335T1$$EHTML$$P50$$Gepo$$Hfree_for_read</linktohtml><link.rule.ids>230,308,776,881,25542,76516</link.rule.ids><linktorsrc>$$Uhttps://worldwide.espacenet.com/publicationDetails/biblio?FT=D&amp;date=20040415&amp;DB=EPODOC&amp;CC=AT&amp;NR=E264335T1$$EView_record_in_European_Patent_Office$$FView_record_in_$$GEuropean_Patent_Office$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>ROYO GRACIA, PASCUAL</creatorcontrib><creatorcontrib>FLORES DE PACO, MIGUEL ANGEL</creatorcontrib><creatorcontrib>CANO SIERRA, JESUS</creatorcontrib><creatorcontrib>PENA GARCIA, BEGONA</creatorcontrib><title>OLEFINPOLYMERISATIONSKATALYSATOREN</title><description>1. The invention concerns olefin polymerization catalyst component comprising an organometallic compound of general formula I wherein: M is a transition metal of groups 3, 4-10, lanthanide or actinide of the periodic table of the elements; each R is independently a structural bridge rigidly connecting two ligands L1, L2 and L3 and is constituted by 1 to 4 chain atoms selected from carbon, silicon, germanium, oxygen, boron; m, n and o are 0 or 1, with the proviso that m+n+o is 2 or 3; L1 is a ligand of the cyclopentadienyl type or is isolobal to cyclopentadienyl, L2 is a ligand of the cyclopentadienyl type or is isolobal to cyclopentadienyl, or a monovalent anionic ligand selected from the group consisting of N, P, B when m+n =2, it is selected from the group consisting of NR , PR , BR , O and S when m+n =1; L3 is a monovalent anionic ligand selected from the group consisting of N, P, B when n+o =2, it is selected from the group consisting of NR , PR , BR , O and S when n+o =1; R is hydrogen, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C3-C20 alkenyl, optionally comprising 1 to 5 heteroatoms such as Si, N, P, O, F, Cl, Br; each X is independently selected from the group consisting of hydrogen, halogen, NR 2, R with R equal to C1-C20 alkyl, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C3-C20 alkenyl, optionally comprising 1 to 5 heteroatoms such as Si, N, P, O, F, Cl, Br; q is a number whose value is: 0, 1, 2 or 3, depending on the valence of the metal M; D is a neutral Lewis base, p is a number whose value is: 0, 1, 2 or 3. The invention also concerns catalysts comprising compounds of formula (I) and the polymerization process making use of a catalyst comprising the claimed compounds.</description><subject>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</subject><subject>CHEMISTRY</subject><subject>COMPOSITIONS BASED THEREON</subject><subject>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</subject><subject>METALLURGY</subject><subject>ORGANIC CHEMISTRY</subject><subject>ORGANIC MACROMOLECULAR COMPOUNDS</subject><subject>THEIR PREPARATION OR CHEMICAL WORKING-UP</subject><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2004</creationdate><recordtype>patent</recordtype><sourceid>EVB</sourceid><recordid>eNrjZFDy93F18_QL8PeJ9HUN8gx2DPH09wv2dgxx9IkEcvyDXP14GFjTEnOKU3mhNDeDoptriLOHbmpBfnxqcUFicmpeakm8Y4irkZmJsbFpSIihMTFqAJjYI8o</recordid><startdate>20040415</startdate><enddate>20040415</enddate><creator>ROYO GRACIA, PASCUAL</creator><creator>FLORES DE PACO, MIGUEL ANGEL</creator><creator>CANO SIERRA, JESUS</creator><creator>PENA GARCIA, BEGONA</creator><scope>EVB</scope></search><sort><creationdate>20040415</creationdate><title>OLEFINPOLYMERISATIONSKATALYSATOREN</title><author>ROYO GRACIA, PASCUAL ; FLORES DE PACO, MIGUEL ANGEL ; CANO SIERRA, JESUS ; PENA GARCIA, BEGONA</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-epo_espacenet_ATE264335TT13</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>ger</language><creationdate>2004</creationdate><topic>ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM</topic><topic>CHEMISTRY</topic><topic>COMPOSITIONS BASED THEREON</topic><topic>MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS</topic><topic>METALLURGY</topic><topic>ORGANIC CHEMISTRY</topic><topic>ORGANIC MACROMOLECULAR COMPOUNDS</topic><topic>THEIR PREPARATION OR CHEMICAL WORKING-UP</topic><toplevel>online_resources</toplevel><creatorcontrib>ROYO GRACIA, PASCUAL</creatorcontrib><creatorcontrib>FLORES DE PACO, MIGUEL ANGEL</creatorcontrib><creatorcontrib>CANO SIERRA, JESUS</creatorcontrib><creatorcontrib>PENA GARCIA, BEGONA</creatorcontrib><collection>esp@cenet</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>ROYO GRACIA, PASCUAL</au><au>FLORES DE PACO, MIGUEL ANGEL</au><au>CANO SIERRA, JESUS</au><au>PENA GARCIA, BEGONA</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>OLEFINPOLYMERISATIONSKATALYSATOREN</title><date>2004-04-15</date><risdate>2004</risdate><abstract>1. The invention concerns olefin polymerization catalyst component comprising an organometallic compound of general formula I wherein: M is a transition metal of groups 3, 4-10, lanthanide or actinide of the periodic table of the elements; each R is independently a structural bridge rigidly connecting two ligands L1, L2 and L3 and is constituted by 1 to 4 chain atoms selected from carbon, silicon, germanium, oxygen, boron; m, n and o are 0 or 1, with the proviso that m+n+o is 2 or 3; L1 is a ligand of the cyclopentadienyl type or is isolobal to cyclopentadienyl, L2 is a ligand of the cyclopentadienyl type or is isolobal to cyclopentadienyl, or a monovalent anionic ligand selected from the group consisting of N, P, B when m+n =2, it is selected from the group consisting of NR , PR , BR , O and S when m+n =1; L3 is a monovalent anionic ligand selected from the group consisting of N, P, B when n+o =2, it is selected from the group consisting of NR , PR , BR , O and S when n+o =1; R is hydrogen, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C3-C20 alkenyl, optionally comprising 1 to 5 heteroatoms such as Si, N, P, O, F, Cl, Br; each X is independently selected from the group consisting of hydrogen, halogen, NR 2, R with R equal to C1-C20 alkyl, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C3-C20 alkenyl, optionally comprising 1 to 5 heteroatoms such as Si, N, P, O, F, Cl, Br; q is a number whose value is: 0, 1, 2 or 3, depending on the valence of the metal M; D is a neutral Lewis base, p is a number whose value is: 0, 1, 2 or 3. The invention also concerns catalysts comprising compounds of formula (I) and the polymerization process making use of a catalyst comprising the claimed compounds.</abstract><edition>7</edition><oa>free_for_read</oa></addata></record>
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subjects ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title OLEFINPOLYMERISATIONSKATALYSATOREN
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