VERFAHREN ZUR HERSTELLUNG VON OPTISCH AKTIVEM TERT-LEUCINOL UND DESSEN VERWENDUNG
Prodn. of optically active tert.-leucinol of formula (I) comprises reacting (RS)-tert.-leucinol with an optically active N-acyl-tert.-leucine of formula (II), separating the resulting diastereomeric salts by fractional crystn., and releasing the desired isomer from its salt: R = H or an up to 20C al...
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creator | JAHN, WILFRIED DRAUZ, KARLHEINZ, DR SCHWARM, MICHAEL |
description | Prodn. of optically active tert.-leucinol of formula (I) comprises reacting (RS)-tert.-leucinol with an optically active N-acyl-tert.-leucine of formula (II), separating the resulting diastereomeric salts by fractional crystn., and releasing the desired isomer from its salt: R = H or an up to 20C alky, arylalkyl or aryl gp. opt. substd. by or contg. heteroatoms. |
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subjects | ACYCLIC OR CARBOCYCLIC COMPOUNDS APPARATUS THEREFOR CHEMISTRY GENERAL METHODS OF ORGANIC CHEMISTRY METALLURGY ORGANIC CHEMISTRY |
title | VERFAHREN ZUR HERSTELLUNG VON OPTISCH AKTIVEM TERT-LEUCINOL UND DESSEN VERWENDUNG |
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