PHOTOPOLYMERISIERBARES GEMISCH UND DARAUS HERGESTELLTES AUFZEICHNUNGSMATERIAL

Photopolymerisable mixt. based on a polymeric binder (I), a cpd. (II) with polymerisable gp(s), capable of free radical polymerisation and a photo-reducible dyestuff (III) also contains a dicyclopentadienyl-bis- 2,4,6-tri-fluorophenyl-Ti or Zr cpd. (IV). Pref. (I) is insol. in H2O and soluble in aq....

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MOHR, DIETER
description Photopolymerisable mixt. based on a polymeric binder (I), a cpd. (II) with polymerisable gp(s), capable of free radical polymerisation and a photo-reducible dyestuff (III) also contains a dicyclopentadienyl-bis- 2,4,6-tri-fluorophenyl-Ti or Zr cpd. (IV). Pref. (I) is insol. in H2O and soluble in aq. alkaline solns. (II) is an (alk)acrylate ester with gp(s). capable of photo-oxidn. when exposed in the presence of (III), and is pref. an amino, urea, thio or enol gp. (III) is a xanthene, thiazine, pyronine, porphyrin or acridine dyestuff. In (IC), at least one of the cyclopentadienyl gps. is substd. The mixt. may also contain a trihalomethyl cpd. (V) decomposed by radiation, (pref. an s-triazine cpd. with trihalomethyl gp(s). and opt. another substit.; or an aryl trihalomethyl sulphone). An acridine, phenazine or quinoxaline cpd. may be added as photoinitiator. The mixt. contains 20-90 (wt.)% 10-80% (II) and 0.05-20% initiators activated by radiation, w.r.t. non-volatiles. The recording material has a base coated with the mixt. and pref. also another transparent layer with low permeability for atmos. O2, whichis soluble in the developer liquid for the photopolymerisable layer.
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(II) with polymerisable gp(s), capable of free radical polymerisation and a photo-reducible dyestuff (III) also contains a dicyclopentadienyl-bis- 2,4,6-tri-fluorophenyl-Ti or Zr cpd. (IV). Pref. (I) is insol. in H2O and soluble in aq. alkaline solns. (II) is an (alk)acrylate ester with gp(s). capable of photo-oxidn. when exposed in the presence of (III), and is pref. an amino, urea, thio or enol gp. (III) is a xanthene, thiazine, pyronine, porphyrin or acridine dyestuff. In (IC), at least one of the cyclopentadienyl gps. is substd. The mixt. may also contain a trihalomethyl cpd. (V) decomposed by radiation, (pref. an s-triazine cpd. with trihalomethyl gp(s). and opt. another substit.; or an aryl trihalomethyl sulphone). An acridine, phenazine or quinoxaline cpd. may be added as photoinitiator. The mixt. contains 20-90 (wt.)% 10-80% (II) and 0.05-20% initiators activated by radiation, w.r.t. non-volatiles. The recording material has a base coated with the mixt. and pref. also another transparent layer with low permeability for atmos. O2, whichis soluble in the developer liquid for the photopolymerisable layer.</abstract><edition>6</edition><oa>free_for_read</oa></addata></record>
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subjects APPARATUS SPECIALLY ADAPTED THEREFOR
BASIC ELECTRIC ELEMENTS
CHEMISTRY
CINEMATOGRAPHY
COMPOSITIONS BASED THEREON
ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR
ELECTRICITY
ELECTROGRAPHY
HOLOGRAPHY
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
MATERIALS THEREFOR
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
ORIGINALS THEREFOR
PHOTOGRAPHY
PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES,e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTORDEVICES
PHYSICS
SEMICONDUCTOR DEVICES
THEIR PREPARATION OR CHEMICAL WORKING-UP
title PHOTOPOLYMERISIERBARES GEMISCH UND DARAUS HERGESTELLTES AUFZEICHNUNGSMATERIAL
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