OLEFINPOLYMERISATIONSKATALYSATOR

The present invention concerns a catalyst for polymerization of olefins, said catalyst comprising an inorganic support material with catalytically active chromium and titanium compounds bound on its surface. The catalyst is prepared according to the invention by bringing the catalytically active met...

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Hauptverfasser: KNUUTTILA, HILKKA, LAKOMAA, EEVA-LIISA
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creator KNUUTTILA, HILKKA
LAKOMAA, EEVA-LIISA
description The present invention concerns a catalyst for polymerization of olefins, said catalyst comprising an inorganic support material with catalytically active chromium and titanium compounds bound on its surface. The catalyst is prepared according to the invention by bringing the catalytically active metal compounds sequentially in vapour phase onto the support material surface in excess amounts in relation to the binding sites available on the support material surface. The support material temperature is maintained above the condensation temperature of the vapour, preferably above 160 DEG C, and simultaneously sufficiently high so as to achieve the thermal activation energy necessary for the generation of bonds between the support material and the catalytically active material or its compound. To avoid desorption of the chemisorbed compounds, the temperature is kept below approx. 500 DEG C. The activity of a catalyst in accordance with the invention even with very low contents of the catalytic metals is as high as the activity of a catalyst of multiply higher metal contents that has been prepared by the methods of the conventional technology.
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The catalyst is prepared according to the invention by bringing the catalytically active metal compounds sequentially in vapour phase onto the support material surface in excess amounts in relation to the binding sites available on the support material surface. The support material temperature is maintained above the condensation temperature of the vapour, preferably above 160 DEG C, and simultaneously sufficiently high so as to achieve the thermal activation energy necessary for the generation of bonds between the support material and the catalytically active material or its compound. To avoid desorption of the chemisorbed compounds, the temperature is kept below approx. 500 DEG C. 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subjects CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
title OLEFINPOLYMERISATIONSKATALYSATOR
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