Borophosphonate Cages: Easily Accessible and Constitutionally Dynamic Heterocubane Scaffolds
A versatile and experimentally facile procedure for the synthesis of borophosphonate cages of the general formula [tBuPO3BR′]4 is described. The method involves heating of tert-butylphosphonic acid with a boronic acid in toluene to give borophosphonates in [4+4] condensation reactions. The products...
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