Surface Enhanced NMR Spectroscopy by Dynamic Nuclear Polarization
It is shown that surface NMR spectra can be greatly enhanced using dynamic nuclear polarization. Polarization is transferred from the protons of the solvent to the rare nuclei (here carbon-13 at natural isotopic abundance) at the surface, yielding at least a 50-fold signal enhancement for surface sp...
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| creator | Lesage, Anne Lelli, Moreno Gajan, David Benjamin Roger Antoine Caporini, Marc Anthony Vitzthum, Veronika Miéville, Pascal Alauzun, Johan Roussey, Arthur Thieuleux, Chloé Ahmadi, Mehdi Bodenhausen, Geoffrey Copéret, Christophe Emsley, Lyndon |
| description | It is shown that surface NMR spectra can be greatly enhanced using dynamic nuclear polarization. Polarization is transferred from the protons of the solvent to the rare nuclei (here carbon-13 at natural isotopic abundance) at the surface, yielding at least a 50-fold signal enhancement for surface species covalently incorporated into a silica framework. |
| doi_str_mv | 10.1021/ja104771z |
| format | Web Resource |
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| source | Infoscience: EPF Lausanne |
| title | Surface Enhanced NMR Spectroscopy by Dynamic Nuclear Polarization |
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