Preparation and characterisation of modified VAc-VeoVa10 latex
Purpose Fluorine and silicon materials have received the keen attention of many researchers because of their water repellency and low surface free energy. The purpose this study was to prepare vinyl acetate (VAc)-vinyl ester of neodecanoic acid (VeoVa 10) copolymer latex modified with fluorine and s...
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| Veröffentlicht in: | Pigment & resin technology 2019-05, Vol.48 (3), p.210-215 |
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| creator | Gong, Yilu Shao, Tantan Wang, Xiuming Zhang, Xin Sun, Zhijuan Chen, Lijun |
| description | Purpose
Fluorine and silicon materials have received the keen attention of many researchers because of their water repellency and low surface free energy. The purpose this study was to prepare vinyl acetate (VAc)-vinyl ester of neodecanoic acid (VeoVa 10) copolymer latex modified with fluorine and silicone monomer, which is emulsified with the novel surfactants of disodium laureth sulfosuccinate (MES) and octylphenol polyoxyethylene ether (OP-10).
Design/methodology/approach
A series of modified latices containing fluorine-silicon have been prepared by semi-continuous seeded emulsion polymerisation of mixed monomers of VAc, VeoVa10, hexafluorobutylmethacrylate (HFMA) and vinyltriethoxysilane (VTES) and emulsified by novel surfactants of MES and OP-10.
Findings
The optimum conditions for preparing the modified latex is as follows: the amount of the surfactant was 4.0 Wt.% and the mass ratio of the anionic and nonionic surfactant was 3:1; the dosage of initiator was 0.4 Wt.% and the mass ratio of the main monomer was 3:1; and the amounts of VTES and HFMA were 2.0 and 6.0 Wt.%, respectively. In comparison with the conventional latex, the hydrophobicity of latex film was improved further.
Originality/value
The modified p (VAC-VeoVa) latex is prepared via semi-continuous seeded emulsion polymerisation, which is emulsified with the novel mixed surfactants of MES and OP-10. There are two main innovations. One is that the novel p (VAC-VeoVa) latex containing fluorine-silicon is prepared successfully. The other is that the emulsifier is composed of the novel mixed surfactants of MES and OP-10. |
| doi_str_mv | 10.1108/PRT-05-2018-0045 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_emera</sourceid><recordid>TN_cdi_emerald_primary_10_1108_PRT-05-2018-0045</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2227410746</sourcerecordid><originalsourceid>FETCH-LOGICAL-c311t-c620408856e624cd3b0f74e4c21b1772a7062f0ee418bc029c07ce62ca8052fe3</originalsourceid><addsrcrecordid>eNptkE1LAzEQhoMoWD_uHhc8x85ks0n2IpTiFxQsUnsNaXaCW9puTbag_96U9SJ4GmZ4nxnmYewG4Q4RzHj-tuBQcQFoOICsTtgIdWW4qiWeshGUqua1FHDOLlJaA4AQuh6x-3mkvYuub7td4XZN4T9y53uKbRqGXSi2XdOGlppiOfF8Sd3SIRQb19PXFTsLbpPo-rdesvfHh8X0mc9en16mkxn3JWLPvRIgwZhKkRLSN-UKgpYkvcAVai2cBiUCEEk0Kw-i9qB9jnpnoBKBykt2O-zdx-7zQKm36-4Qd_mkFfkRiaClyikYUj52KUUKdh_brYvfFsEeLdlsyUJlj5bs0VJGxgNCW4pu0_xH_PFa_gDrpmaY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2227410746</pqid></control><display><type>article</type><title>Preparation and characterisation of modified VAc-VeoVa10 latex</title><source>Emerald Journals</source><creator>Gong, Yilu ; Shao, Tantan ; Wang, Xiuming ; Zhang, Xin ; Sun, Zhijuan ; Chen, Lijun</creator><creatorcontrib>Gong, Yilu ; Shao, Tantan ; Wang, Xiuming ; Zhang, Xin ; Sun, Zhijuan ; Chen, Lijun</creatorcontrib><description>Purpose
Fluorine and silicon materials have received the keen attention of many researchers because of their water repellency and low surface free energy. The purpose this study was to prepare vinyl acetate (VAc)-vinyl ester of neodecanoic acid (VeoVa 10) copolymer latex modified with fluorine and silicone monomer, which is emulsified with the novel surfactants of disodium laureth sulfosuccinate (MES) and octylphenol polyoxyethylene ether (OP-10).
Design/methodology/approach
A series of modified latices containing fluorine-silicon have been prepared by semi-continuous seeded emulsion polymerisation of mixed monomers of VAc, VeoVa10, hexafluorobutylmethacrylate (HFMA) and vinyltriethoxysilane (VTES) and emulsified by novel surfactants of MES and OP-10.
Findings
The optimum conditions for preparing the modified latex is as follows: the amount of the surfactant was 4.0 Wt.% and the mass ratio of the anionic and nonionic surfactant was 3:1; the dosage of initiator was 0.4 Wt.% and the mass ratio of the main monomer was 3:1; and the amounts of VTES and HFMA were 2.0 and 6.0 Wt.%, respectively. In comparison with the conventional latex, the hydrophobicity of latex film was improved further.
Originality/value
The modified p (VAC-VeoVa) latex is prepared via semi-continuous seeded emulsion polymerisation, which is emulsified with the novel mixed surfactants of MES and OP-10. There are two main innovations. One is that the novel p (VAC-VeoVa) latex containing fluorine-silicon is prepared successfully. The other is that the emulsifier is composed of the novel mixed surfactants of MES and OP-10.</description><identifier>ISSN: 0369-9420</identifier><identifier>EISSN: 1758-6941</identifier><identifier>DOI: 10.1108/PRT-05-2018-0045</identifier><language>eng</language><publisher>Bradford: Emerald Publishing Limited</publisher><subject>Contact angle ; Design modifications ; Emulsion polymerization ; Fluorine ; Fourier transforms ; Free energy ; Hydrophobicity ; Latex ; Monomers ; Particle size ; Polymerization ; Polymers ; Polyoxyethylene ; Ratios ; Researchers ; Silicon ; Silicones ; Spectrum analysis ; Sulfosuccinates ; Surfactants ; Vinyl acetate ; Vinyl ester resins ; Water</subject><ispartof>Pigment & resin technology, 2019-05, Vol.48 (3), p.210-215</ispartof><rights>Emerald Publishing Limited</rights><rights>Emerald Publishing Limited 2019</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c311t-c620408856e624cd3b0f74e4c21b1772a7062f0ee418bc029c07ce62ca8052fe3</citedby><cites>FETCH-LOGICAL-c311t-c620408856e624cd3b0f74e4c21b1772a7062f0ee418bc029c07ce62ca8052fe3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.emerald.com/insight/content/doi/10.1108/PRT-05-2018-0045/full/html$$EHTML$$P50$$Gemerald$$H</linktohtml><link.rule.ids>314,776,780,961,11615,27903,27904,52667</link.rule.ids></links><search><creatorcontrib>Gong, Yilu</creatorcontrib><creatorcontrib>Shao, Tantan</creatorcontrib><creatorcontrib>Wang, Xiuming</creatorcontrib><creatorcontrib>Zhang, Xin</creatorcontrib><creatorcontrib>Sun, Zhijuan</creatorcontrib><creatorcontrib>Chen, Lijun</creatorcontrib><title>Preparation and characterisation of modified VAc-VeoVa10 latex</title><title>Pigment & resin technology</title><description>Purpose
Fluorine and silicon materials have received the keen attention of many researchers because of their water repellency and low surface free energy. The purpose this study was to prepare vinyl acetate (VAc)-vinyl ester of neodecanoic acid (VeoVa 10) copolymer latex modified with fluorine and silicone monomer, which is emulsified with the novel surfactants of disodium laureth sulfosuccinate (MES) and octylphenol polyoxyethylene ether (OP-10).
Design/methodology/approach
A series of modified latices containing fluorine-silicon have been prepared by semi-continuous seeded emulsion polymerisation of mixed monomers of VAc, VeoVa10, hexafluorobutylmethacrylate (HFMA) and vinyltriethoxysilane (VTES) and emulsified by novel surfactants of MES and OP-10.
Findings
The optimum conditions for preparing the modified latex is as follows: the amount of the surfactant was 4.0 Wt.% and the mass ratio of the anionic and nonionic surfactant was 3:1; the dosage of initiator was 0.4 Wt.% and the mass ratio of the main monomer was 3:1; and the amounts of VTES and HFMA were 2.0 and 6.0 Wt.%, respectively. In comparison with the conventional latex, the hydrophobicity of latex film was improved further.
Originality/value
The modified p (VAC-VeoVa) latex is prepared via semi-continuous seeded emulsion polymerisation, which is emulsified with the novel mixed surfactants of MES and OP-10. There are two main innovations. One is that the novel p (VAC-VeoVa) latex containing fluorine-silicon is prepared successfully. The other is that the emulsifier is composed of the novel mixed surfactants of MES and OP-10.</description><subject>Contact angle</subject><subject>Design modifications</subject><subject>Emulsion polymerization</subject><subject>Fluorine</subject><subject>Fourier transforms</subject><subject>Free energy</subject><subject>Hydrophobicity</subject><subject>Latex</subject><subject>Monomers</subject><subject>Particle size</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Polyoxyethylene</subject><subject>Ratios</subject><subject>Researchers</subject><subject>Silicon</subject><subject>Silicones</subject><subject>Spectrum analysis</subject><subject>Sulfosuccinates</subject><subject>Surfactants</subject><subject>Vinyl acetate</subject><subject>Vinyl ester resins</subject><subject>Water</subject><issn>0369-9420</issn><issn>1758-6941</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNptkE1LAzEQhoMoWD_uHhc8x85ks0n2IpTiFxQsUnsNaXaCW9puTbag_96U9SJ4GmZ4nxnmYewG4Q4RzHj-tuBQcQFoOICsTtgIdWW4qiWeshGUqua1FHDOLlJaA4AQuh6x-3mkvYuub7td4XZN4T9y53uKbRqGXSi2XdOGlppiOfF8Sd3SIRQb19PXFTsLbpPo-rdesvfHh8X0mc9en16mkxn3JWLPvRIgwZhKkRLSN-UKgpYkvcAVai2cBiUCEEk0Kw-i9qB9jnpnoBKBykt2O-zdx-7zQKm36-4Qd_mkFfkRiaClyikYUj52KUUKdh_brYvfFsEeLdlsyUJlj5bs0VJGxgNCW4pu0_xH_PFa_gDrpmaY</recordid><startdate>20190501</startdate><enddate>20190501</enddate><creator>Gong, Yilu</creator><creator>Shao, Tantan</creator><creator>Wang, Xiuming</creator><creator>Zhang, Xin</creator><creator>Sun, Zhijuan</creator><creator>Chen, Lijun</creator><general>Emerald Publishing Limited</general><general>Emerald Group Publishing Limited</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7WY</scope><scope>7XB</scope><scope>8AF</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>F28</scope><scope>FR3</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>K6~</scope><scope>KB.</scope><scope>L.-</scope><scope>M0F</scope><scope>M2P</scope><scope>PDBOC</scope><scope>PQBIZ</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope></search><sort><creationdate>20190501</creationdate><title>Preparation and characterisation of modified VAc-VeoVa10 latex</title><author>Gong, Yilu ; Shao, Tantan ; Wang, Xiuming ; Zhang, Xin ; Sun, Zhijuan ; Chen, Lijun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c311t-c620408856e624cd3b0f74e4c21b1772a7062f0ee418bc029c07ce62ca8052fe3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Contact angle</topic><topic>Design modifications</topic><topic>Emulsion polymerization</topic><topic>Fluorine</topic><topic>Fourier transforms</topic><topic>Free energy</topic><topic>Hydrophobicity</topic><topic>Latex</topic><topic>Monomers</topic><topic>Particle size</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Polyoxyethylene</topic><topic>Ratios</topic><topic>Researchers</topic><topic>Silicon</topic><topic>Silicones</topic><topic>Spectrum analysis</topic><topic>Sulfosuccinates</topic><topic>Surfactants</topic><topic>Vinyl acetate</topic><topic>Vinyl ester resins</topic><topic>Water</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gong, Yilu</creatorcontrib><creatorcontrib>Shao, Tantan</creatorcontrib><creatorcontrib>Wang, Xiuming</creatorcontrib><creatorcontrib>Zhang, Xin</creatorcontrib><creatorcontrib>Sun, Zhijuan</creatorcontrib><creatorcontrib>Chen, Lijun</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>ABI/INFORM Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>STEM Database</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Business Premium Collection</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>ProQuest Business Collection</collection><collection>Materials Science Database</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Trade & Industry</collection><collection>Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Business</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Pigment & resin technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gong, Yilu</au><au>Shao, Tantan</au><au>Wang, Xiuming</au><au>Zhang, Xin</au><au>Sun, Zhijuan</au><au>Chen, Lijun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and characterisation of modified VAc-VeoVa10 latex</atitle><jtitle>Pigment & resin technology</jtitle><date>2019-05-01</date><risdate>2019</risdate><volume>48</volume><issue>3</issue><spage>210</spage><epage>215</epage><pages>210-215</pages><issn>0369-9420</issn><eissn>1758-6941</eissn><abstract>Purpose
Fluorine and silicon materials have received the keen attention of many researchers because of their water repellency and low surface free energy. The purpose this study was to prepare vinyl acetate (VAc)-vinyl ester of neodecanoic acid (VeoVa 10) copolymer latex modified with fluorine and silicone monomer, which is emulsified with the novel surfactants of disodium laureth sulfosuccinate (MES) and octylphenol polyoxyethylene ether (OP-10).
Design/methodology/approach
A series of modified latices containing fluorine-silicon have been prepared by semi-continuous seeded emulsion polymerisation of mixed monomers of VAc, VeoVa10, hexafluorobutylmethacrylate (HFMA) and vinyltriethoxysilane (VTES) and emulsified by novel surfactants of MES and OP-10.
Findings
The optimum conditions for preparing the modified latex is as follows: the amount of the surfactant was 4.0 Wt.% and the mass ratio of the anionic and nonionic surfactant was 3:1; the dosage of initiator was 0.4 Wt.% and the mass ratio of the main monomer was 3:1; and the amounts of VTES and HFMA were 2.0 and 6.0 Wt.%, respectively. In comparison with the conventional latex, the hydrophobicity of latex film was improved further.
Originality/value
The modified p (VAC-VeoVa) latex is prepared via semi-continuous seeded emulsion polymerisation, which is emulsified with the novel mixed surfactants of MES and OP-10. There are two main innovations. One is that the novel p (VAC-VeoVa) latex containing fluorine-silicon is prepared successfully. The other is that the emulsifier is composed of the novel mixed surfactants of MES and OP-10.</abstract><cop>Bradford</cop><pub>Emerald Publishing Limited</pub><doi>10.1108/PRT-05-2018-0045</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0369-9420 |
| ispartof | Pigment & resin technology, 2019-05, Vol.48 (3), p.210-215 |
| issn | 0369-9420 1758-6941 |
| language | eng |
| recordid | cdi_emerald_primary_10_1108_PRT-05-2018-0045 |
| source | Emerald Journals |
| subjects | Contact angle Design modifications Emulsion polymerization Fluorine Fourier transforms Free energy Hydrophobicity Latex Monomers Particle size Polymerization Polymers Polyoxyethylene Ratios Researchers Silicon Silicones Spectrum analysis Sulfosuccinates Surfactants Vinyl acetate Vinyl ester resins Water |
| title | Preparation and characterisation of modified VAc-VeoVa10 latex |
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