Interactions investigation of new composite material formed from bauxite and melamine-urea formaldehyde copolymer

In this study the Bauxite has been activated and used to prepare two complexes: Bauxite - urea and Bauxite - melamine, these complexes were merged and polymerized with formaldehyde to prepare the complex Bauxite polymer - urea - melamine - formaldehyde (modified Bauxite). In the Bauxite-urea complex...

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Veröffentlicht in:Ibn Al-Haitham Journal for Pure and Applied Sciences 2016, Vol.29 (1), p.181-192
Hauptverfasser: al-Fadli, Isra Muhammad Radi, Hamdan, Taqi al-Din Abd al-Hadi, Abu Zayd, Yusuf Ibrahim Muhammad
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container_title Ibn Al-Haitham Journal for Pure and Applied Sciences
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creator al-Fadli, Isra Muhammad Radi
Hamdan, Taqi al-Din Abd al-Hadi
Abu Zayd, Yusuf Ibrahim Muhammad
description In this study the Bauxite has been activated and used to prepare two complexes: Bauxite - urea and Bauxite - melamine, these complexes were merged and polymerized with formaldehyde to prepare the complex Bauxite polymer - urea - melamine - formaldehyde (modified Bauxite). In the Bauxite-urea complex XRD results indicate that the urea molecules penetrate among the layers of the crystal plane (110) of the Gibbsite mineral while in the Bauxite-melamine the interaction was at the outer surface of the Bauxite forming minerals because the relatively large volume of the melamine molecule. FT-IR results show the interaction of these two bases with Bauxite was mainly based on the hydrogen bonding and in less extent on the coordination between N loan pair atom and aluminum empty orbital in the above complexes. Finally the copolymer was formed around the micro-crystals of Bauxite minerals.
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subjects Bauxite
Boehmite
Composite materials
Copolymers
Crystals
Formaldehyde
Infrared spectroscopy
Inorganic polymers
Melamine
Nanocomposites (Materials)
Nanotechnology
Spectrophotometer
Surface chemistry
X-ray spectroscopy
الأجسام الصلبة
الألدهيدات
الصخور الرسوبية
المطهرات
المواد المركبة
تكنولوجيا النانو
خامات الألومنيوم
مقاييس الطيف
title Interactions investigation of new composite material formed from bauxite and melamine-urea formaldehyde copolymer
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