Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure

Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure

MIL-100(Fe), a mesoporous metal-organic framework (MOF), has a large BET specific surface area and pore volume with the presence of a significant amount of accessible Lewis acid metal sites upon dehydration. The structural characteristics of MIL-100(Fe) make it a good candidate for potential applica...

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Veröffentlicht in:Journal of chemistry 2013, Vol.2013 (2013), p.1-4
Hauptverfasser: Hei, Shengtao, Shi, Jing, Liu, Huanhuan, Fu, Yanghe, Zhang, Fumin, Zhong, Yijun, Zhu, Weidong
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container_issue 2013
container_start_page 1
container_title Journal of chemistry
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creator Hei, Shengtao
Shi, Jing
Liu, Huanhuan
Fu, Yanghe
Zhang, Fumin
Zhong, Yijun
Zhu, Weidong
description MIL-100(Fe), a mesoporous metal-organic framework (MOF), has a large BET specific surface area and pore volume with the presence of a significant amount of accessible Lewis acid metal sites upon dehydration. The structural characteristics of MIL-100(Fe) make it a good candidate for potential applications in gas storage, separation, and heterogeneous catalysis. Mainly, this MOF is obtained by the hydrothermal synthesis in a Teflon-lined autoclave at high temperature (>150°C) under static conditions. However, this method has several disadvantages such as high temperature, high (autogenous) pressure, long time, and comparable low MOF yield. Therefore, development of a facile method for synthesis of MIL-100(Fe) is vitally important for fundamental understanding and practical application. Herein, MIL-100(Fe) is synthesized by a facile low-temperature (90%) still could be achieved, suggesting that this simple and energy saving method has the potential to be used practically.
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title Synthesis of MIL-100(Fe) at Low Temperature and Atmospheric Pressure
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