Optical Properties of Nanocellulose Dispersions in Water, Dimethylformamide and Poly(Methyl Methacrylate)
The effects of cellulose nanocrystal filler concentration on the optical properties of transmittance, haze, and clarity were studied for solutions and composites. Cellulose nanocrystal (CNC) solutions were studied in both water and dimethylformamide (DMF). Cellulose composites employing poly(methyl...
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creator | Snyder, James F Steele, Joshua Dong, Hong Orlicki, Joshua A Reiner, Richard S Rudie, Alan W |
description | The effects of cellulose nanocrystal filler concentration on the optical properties of transmittance, haze, and clarity were studied for solutions and composites. Cellulose nanocrystal (CNC) solutions were studied in both water and dimethylformamide (DMF). Cellulose composites employing poly(methyl methacrylate) (PMMA) as the matrix were tested with and without surfactants to aid dispersion. Increasing concentrations of cellulose in solution and in solid films caused light transmittance to decrease and light scattering, as measured by clarity and haze, to increase. The same optical trends were observed in solution samples as the path length (sample thickness) increased. The CNCs in DMF exhibited similar transmittance as those in water, but noticeably reduced light scattering.
The original document contains color images. Prepared in collaboration with the USDA Forest Service. |
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The original document contains color images. Prepared in collaboration with the USDA Forest Service.</description><language>eng</language><subject>CELLULOSE ; CLARITY ; CNC(CELLULOSE NANOCRYSTALS) ; CRYSTALS ; DISPERSIONS ; DMF(DIMETHYLFORMAMIDE) ; HAZE ; LIGHT SCATTERING ; NANOCELLULOSE ; OPTICAL PROPERTIES ; OPTICAL TRANSPARENCY ; Optics ; Physical Chemistry ; PMMA(POLYMETHYL METHACRYLATE) ; POLYMETHYL METHACRYLATE ; REFRACTIVE INDEX ; SOLUTIONS(MIXTURES) ; THIN FILMS ; TRANSMITTANCE ; WATER</subject><creationdate>2013</creationdate><rights>Approved for public release; distribution is unlimited.</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,776,881,27544,27545</link.rule.ids><linktorsrc>$$Uhttps://apps.dtic.mil/sti/citations/ADA587694$$EView_record_in_DTIC$$FView_record_in_$$GDTIC$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Snyder, James F</creatorcontrib><creatorcontrib>Steele, Joshua</creatorcontrib><creatorcontrib>Dong, Hong</creatorcontrib><creatorcontrib>Orlicki, Joshua A</creatorcontrib><creatorcontrib>Reiner, Richard S</creatorcontrib><creatorcontrib>Rudie, Alan W</creatorcontrib><creatorcontrib>ARMY RESEARCH LAB ABERDEEN PROVING GROUND MD WEAPONS AND MATERIALS RESEARCH DIRECTORATE</creatorcontrib><title>Optical Properties of Nanocellulose Dispersions in Water, Dimethylformamide and Poly(Methyl Methacrylate)</title><description>The effects of cellulose nanocrystal filler concentration on the optical properties of transmittance, haze, and clarity were studied for solutions and composites. Cellulose nanocrystal (CNC) solutions were studied in both water and dimethylformamide (DMF). Cellulose composites employing poly(methyl methacrylate) (PMMA) as the matrix were tested with and without surfactants to aid dispersion. Increasing concentrations of cellulose in solution and in solid films caused light transmittance to decrease and light scattering, as measured by clarity and haze, to increase. The same optical trends were observed in solution samples as the path length (sample thickness) increased. The CNCs in DMF exhibited similar transmittance as those in water, but noticeably reduced light scattering.
The original document contains color images. Prepared in collaboration with the USDA Forest Service.</description><subject>CELLULOSE</subject><subject>CLARITY</subject><subject>CNC(CELLULOSE NANOCRYSTALS)</subject><subject>CRYSTALS</subject><subject>DISPERSIONS</subject><subject>DMF(DIMETHYLFORMAMIDE)</subject><subject>HAZE</subject><subject>LIGHT SCATTERING</subject><subject>NANOCELLULOSE</subject><subject>OPTICAL PROPERTIES</subject><subject>OPTICAL TRANSPARENCY</subject><subject>Optics</subject><subject>Physical Chemistry</subject><subject>PMMA(POLYMETHYL METHACRYLATE)</subject><subject>POLYMETHYL METHACRYLATE</subject><subject>REFRACTIVE INDEX</subject><subject>SOLUTIONS(MIXTURES)</subject><subject>THIN FILMS</subject><subject>TRANSMITTANCE</subject><subject>WATER</subject><fulltext>true</fulltext><rsrctype>report</rsrctype><creationdate>2013</creationdate><recordtype>report</recordtype><sourceid>1RU</sourceid><recordid>eNqFjrEKwkAQBdNYiPoHFlsqaKVGLYNRbNQUgmVYkg0ubG7D7Vnk7z3F3mrgDQNvmPCtC1yhQOG1Ix-YDLSBKzqtSOQlagQ5W3TG6gzYwQMD-UVcWwrPXhr1LbZcE6CroVDpZ5evgA-w8r3EYD5OBg2K0eTHUTI9He-H87KOB0oL7CiUWZ5tdtt0v1790W_cZz4H</recordid><startdate>201310</startdate><enddate>201310</enddate><creator>Snyder, James F</creator><creator>Steele, Joshua</creator><creator>Dong, Hong</creator><creator>Orlicki, Joshua A</creator><creator>Reiner, Richard S</creator><creator>Rudie, Alan W</creator><scope>1RU</scope><scope>BHM</scope></search><sort><creationdate>201310</creationdate><title>Optical Properties of Nanocellulose Dispersions in Water, Dimethylformamide and Poly(Methyl Methacrylate)</title><author>Snyder, James F ; Steele, Joshua ; Dong, Hong ; Orlicki, Joshua A ; Reiner, Richard S ; Rudie, Alan W</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-dtic_stinet_ADA5876943</frbrgroupid><rsrctype>reports</rsrctype><prefilter>reports</prefilter><language>eng</language><creationdate>2013</creationdate><topic>CELLULOSE</topic><topic>CLARITY</topic><topic>CNC(CELLULOSE NANOCRYSTALS)</topic><topic>CRYSTALS</topic><topic>DISPERSIONS</topic><topic>DMF(DIMETHYLFORMAMIDE)</topic><topic>HAZE</topic><topic>LIGHT SCATTERING</topic><topic>NANOCELLULOSE</topic><topic>OPTICAL PROPERTIES</topic><topic>OPTICAL TRANSPARENCY</topic><topic>Optics</topic><topic>Physical Chemistry</topic><topic>PMMA(POLYMETHYL METHACRYLATE)</topic><topic>POLYMETHYL METHACRYLATE</topic><topic>REFRACTIVE INDEX</topic><topic>SOLUTIONS(MIXTURES)</topic><topic>THIN FILMS</topic><topic>TRANSMITTANCE</topic><topic>WATER</topic><toplevel>online_resources</toplevel><creatorcontrib>Snyder, James F</creatorcontrib><creatorcontrib>Steele, Joshua</creatorcontrib><creatorcontrib>Dong, Hong</creatorcontrib><creatorcontrib>Orlicki, Joshua A</creatorcontrib><creatorcontrib>Reiner, Richard S</creatorcontrib><creatorcontrib>Rudie, Alan W</creatorcontrib><creatorcontrib>ARMY RESEARCH LAB ABERDEEN PROVING GROUND MD WEAPONS AND MATERIALS RESEARCH DIRECTORATE</creatorcontrib><collection>DTIC Technical Reports</collection><collection>DTIC STINET</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Snyder, James F</au><au>Steele, Joshua</au><au>Dong, Hong</au><au>Orlicki, Joshua A</au><au>Reiner, Richard S</au><au>Rudie, Alan W</au><aucorp>ARMY RESEARCH LAB ABERDEEN PROVING GROUND MD WEAPONS AND MATERIALS RESEARCH DIRECTORATE</aucorp><format>book</format><genre>unknown</genre><ristype>RPRT</ristype><btitle>Optical Properties of Nanocellulose Dispersions in Water, Dimethylformamide and Poly(Methyl Methacrylate)</btitle><date>2013-10</date><risdate>2013</risdate><abstract>The effects of cellulose nanocrystal filler concentration on the optical properties of transmittance, haze, and clarity were studied for solutions and composites. Cellulose nanocrystal (CNC) solutions were studied in both water and dimethylformamide (DMF). Cellulose composites employing poly(methyl methacrylate) (PMMA) as the matrix were tested with and without surfactants to aid dispersion. Increasing concentrations of cellulose in solution and in solid films caused light transmittance to decrease and light scattering, as measured by clarity and haze, to increase. The same optical trends were observed in solution samples as the path length (sample thickness) increased. The CNCs in DMF exhibited similar transmittance as those in water, but noticeably reduced light scattering.
The original document contains color images. Prepared in collaboration with the USDA Forest Service.</abstract><oa>free_for_read</oa></addata></record> |
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source | DTIC Technical Reports |
subjects | CELLULOSE CLARITY CNC(CELLULOSE NANOCRYSTALS) CRYSTALS DISPERSIONS DMF(DIMETHYLFORMAMIDE) HAZE LIGHT SCATTERING NANOCELLULOSE OPTICAL PROPERTIES OPTICAL TRANSPARENCY Optics Physical Chemistry PMMA(POLYMETHYL METHACRYLATE) POLYMETHYL METHACRYLATE REFRACTIVE INDEX SOLUTIONS(MIXTURES) THIN FILMS TRANSMITTANCE WATER |
title | Optical Properties of Nanocellulose Dispersions in Water, Dimethylformamide and Poly(Methyl Methacrylate) |
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