Growth of High-Quality Carbon Nanotudes on Free-Standing Diamond Substrates (Postprint)

Carbon nanotubes (CJTs) were grown on diamond-coated Si substrates and free-standing diamond wafers to develop efficient thermal interface materials for thermal management applications. High-quality, translucent, free-standing diamond substrates were processed in a 5 kW microwave plasma chemical vap...

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Hauptverfasser: Varanasi, C, Burke, J, Brunke, L, Lanter, W, Wang, H, Petry, J, Yang, B T, Bulmer, J S, Scofield, J, Barnes, P N
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creator Varanasi, C
Burke, J
Brunke, L
Lanter, W
Wang, H
Petry, J
Yang, B T
Bulmer, J S
Scofield, J
Barnes, P N
description Carbon nanotubes (CJTs) were grown on diamond-coated Si substrates and free-standing diamond wafers to develop efficient thermal interface materials for thermal management applications. High-quality, translucent, free-standing diamond substrates were processed in a 5 kW microwave plasma chemical vapor deposition (CVD) system using CH4 as precursor. Ji and Ni-9%W-l.5% Fe catalyst islands were deposited to nucleate CNTs directly onto the diamond substrates. Randomly-oriented multi-walled CNTs forming a mat of 5 1m thickness and consisting of 20 nm diameter tubes were observed to grow in a thermal CVD system using C2H2 as precursor, Transmission electron microscopy and Raman analyses confirmed the presence of high-quality CNTs on diamond showing a DIG peak ratio of 0,2-0.3 in Raman spectra. Prepared in cooperation with Texas A & M University, College Station, TX and University of Dayton Research Institute, Dayton, OH. and collaboration with Army Research Office, Research Traingle Park, NC. This paper contains color. PA Case Number: 88ABW-2010-1418; Clearance Date: 23 Mar 2010. Post print published in: Carbon, V48, pp 2442-2446 (2010).
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subjects CARBON NANOTUBES
CATALYST
CATALYSTS
CHEMICAL VAPOR DEPOSITION
DIAMONDS
EFFICIENCY
Inorganic Chemistry
INTERFACES
MATERIALS
MICROWAVES
RAMAN SPECTRA
TEMPERATURE CONTROL
THERMAL MANAGEMENT
THERMAL MICROWAVE
THERMAL PROPERTIES
Thermodynamics
TRANSLUCENT
TRANSMISSION ELECTRON MICROSCOPY
TRANSMITTANCE
WAFERS
title Growth of High-Quality Carbon Nanotudes on Free-Standing Diamond Substrates (Postprint)
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