Liquid Azide Salts
Ionic liquid azides from azidoethyl, alkyl and alkenyl substituted derivatives of 1,2,4- and 1,2,3-amino-triazoles, were prepared and examined for the first time in order to investigate their structural and physical properties. All reported salts possess melting points below 100 deg C. The unique ch...
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| creator | Schneider, Stefan Rosander, Michael Hudgens, Leslie Warmoth, Greg Hawkins, Tommy Mills, Jeffrey Brand, Adam Vij, Ashwani |
| description | Ionic liquid azides from azidoethyl, alkyl and alkenyl substituted derivatives of 1,2,4- and 1,2,3-amino-triazoles, were prepared and examined for the first time in order to investigate their structural and physical properties. All reported salts possess melting points below 100 deg C. The unique character of these newly discovered ionic liquid azides is based upon the fact that these molecules are not simple protonated salts like previously reported substituted hydrazinium azides. The presence of quaternary nitrogen confers both thermal stability and negligible volatility.
Published in Inorganic Chemistry, v47 n9 p3617-3624, 2008. |
| format | Report |
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Published in Inorganic Chemistry, v47 n9 p3617-3624, 2008.</description><language>eng</language><subject>AZIDES ; AZIDOETHYL ; HYDRAZINIUM AZIDES ; Inorganic Chemistry ; IONIC LIQUID AZIDES ; LIQUIDS ; MOLECULES ; NITROGEN ; Physical Chemistry ; PHYSICAL PROPERTIES ; QUATERNARY NITROGEN ; REPRINTS ; SALTS ; THERMAL STABILITY ; Thermodynamics ; VOLATILITY</subject><creationdate>2007</creationdate><rights>Approved for public release; distribution is unlimited.</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,780,885,27565,27566</link.rule.ids><linktorsrc>$$Uhttps://apps.dtic.mil/sti/citations/ADA489371$$EView_record_in_DTIC$$FView_record_in_$$GDTIC$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Schneider, Stefan</creatorcontrib><creatorcontrib>Rosander, Michael</creatorcontrib><creatorcontrib>Hudgens, Leslie</creatorcontrib><creatorcontrib>Warmoth, Greg</creatorcontrib><creatorcontrib>Hawkins, Tommy</creatorcontrib><creatorcontrib>Mills, Jeffrey</creatorcontrib><creatorcontrib>Brand, Adam</creatorcontrib><creatorcontrib>Vij, Ashwani</creatorcontrib><creatorcontrib>AIR FORCE RESEARCH LAB EDWARDS AFB CA PROPULSION DIRECTORATE</creatorcontrib><title>Liquid Azide Salts</title><description>Ionic liquid azides from azidoethyl, alkyl and alkenyl substituted derivatives of 1,2,4- and 1,2,3-amino-triazoles, were prepared and examined for the first time in order to investigate their structural and physical properties. All reported salts possess melting points below 100 deg C. The unique character of these newly discovered ionic liquid azides is based upon the fact that these molecules are not simple protonated salts like previously reported substituted hydrazinium azides. The presence of quaternary nitrogen confers both thermal stability and negligible volatility.
Published in Inorganic Chemistry, v47 n9 p3617-3624, 2008.</description><subject>AZIDES</subject><subject>AZIDOETHYL</subject><subject>HYDRAZINIUM AZIDES</subject><subject>Inorganic Chemistry</subject><subject>IONIC LIQUID AZIDES</subject><subject>LIQUIDS</subject><subject>MOLECULES</subject><subject>NITROGEN</subject><subject>Physical Chemistry</subject><subject>PHYSICAL PROPERTIES</subject><subject>QUATERNARY NITROGEN</subject><subject>REPRINTS</subject><subject>SALTS</subject><subject>THERMAL STABILITY</subject><subject>Thermodynamics</subject><subject>VOLATILITY</subject><fulltext>true</fulltext><rsrctype>report</rsrctype><creationdate>2007</creationdate><recordtype>report</recordtype><sourceid>1RU</sourceid><recordid>eNrjZBDyySwszUxRcKzKTElVCE7MKSnmYWBNS8wpTuWF0twMMm6uIc4euiklmcnxxSWZeakl8Y4ujiYWlsbmhsYEpAGd9hzR</recordid><startdate>20070913</startdate><enddate>20070913</enddate><creator>Schneider, Stefan</creator><creator>Rosander, Michael</creator><creator>Hudgens, Leslie</creator><creator>Warmoth, Greg</creator><creator>Hawkins, Tommy</creator><creator>Mills, Jeffrey</creator><creator>Brand, Adam</creator><creator>Vij, Ashwani</creator><scope>1RU</scope><scope>BHM</scope></search><sort><creationdate>20070913</creationdate><title>Liquid Azide Salts</title><author>Schneider, Stefan ; Rosander, Michael ; Hudgens, Leslie ; Warmoth, Greg ; Hawkins, Tommy ; Mills, Jeffrey ; Brand, Adam ; Vij, Ashwani</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-dtic_stinet_ADA4893713</frbrgroupid><rsrctype>reports</rsrctype><prefilter>reports</prefilter><language>eng</language><creationdate>2007</creationdate><topic>AZIDES</topic><topic>AZIDOETHYL</topic><topic>HYDRAZINIUM AZIDES</topic><topic>Inorganic Chemistry</topic><topic>IONIC LIQUID AZIDES</topic><topic>LIQUIDS</topic><topic>MOLECULES</topic><topic>NITROGEN</topic><topic>Physical Chemistry</topic><topic>PHYSICAL PROPERTIES</topic><topic>QUATERNARY NITROGEN</topic><topic>REPRINTS</topic><topic>SALTS</topic><topic>THERMAL STABILITY</topic><topic>Thermodynamics</topic><topic>VOLATILITY</topic><toplevel>online_resources</toplevel><creatorcontrib>Schneider, Stefan</creatorcontrib><creatorcontrib>Rosander, Michael</creatorcontrib><creatorcontrib>Hudgens, Leslie</creatorcontrib><creatorcontrib>Warmoth, Greg</creatorcontrib><creatorcontrib>Hawkins, Tommy</creatorcontrib><creatorcontrib>Mills, Jeffrey</creatorcontrib><creatorcontrib>Brand, Adam</creatorcontrib><creatorcontrib>Vij, Ashwani</creatorcontrib><creatorcontrib>AIR FORCE RESEARCH LAB EDWARDS AFB CA PROPULSION DIRECTORATE</creatorcontrib><collection>DTIC Technical Reports</collection><collection>DTIC STINET</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Schneider, Stefan</au><au>Rosander, Michael</au><au>Hudgens, Leslie</au><au>Warmoth, Greg</au><au>Hawkins, Tommy</au><au>Mills, Jeffrey</au><au>Brand, Adam</au><au>Vij, Ashwani</au><aucorp>AIR FORCE RESEARCH LAB EDWARDS AFB CA PROPULSION DIRECTORATE</aucorp><format>book</format><genre>unknown</genre><ristype>RPRT</ristype><btitle>Liquid Azide Salts</btitle><date>2007-09-13</date><risdate>2007</risdate><abstract>Ionic liquid azides from azidoethyl, alkyl and alkenyl substituted derivatives of 1,2,4- and 1,2,3-amino-triazoles, were prepared and examined for the first time in order to investigate their structural and physical properties. All reported salts possess melting points below 100 deg C. The unique character of these newly discovered ionic liquid azides is based upon the fact that these molecules are not simple protonated salts like previously reported substituted hydrazinium azides. The presence of quaternary nitrogen confers both thermal stability and negligible volatility.
Published in Inorganic Chemistry, v47 n9 p3617-3624, 2008.</abstract><oa>free_for_read</oa></addata></record> |
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| source | DTIC Technical Reports |
| subjects | AZIDES AZIDOETHYL HYDRAZINIUM AZIDES Inorganic Chemistry IONIC LIQUID AZIDES LIQUIDS MOLECULES NITROGEN Physical Chemistry PHYSICAL PROPERTIES QUATERNARY NITROGEN REPRINTS SALTS THERMAL STABILITY Thermodynamics VOLATILITY |
| title | Liquid Azide Salts |
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