Industrial Stack Evaluation With Ground-Based Passive FT-IR Spectrometry
The methodology for producing absorbance and transmittance spectra with a passive Fourier transform infrared (FT-IR) spectrometer from an industrial stack and blackbody source is demonstrated. The knowledge of the stack temperature is shown to be key in generating the single-beam spectral ratio of d...
Gespeichert in:
| Hauptverfasser: | , , , |
|---|---|
| Format: | Report |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext bestellen |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | |
| container_start_page | |
| container_title | |
| container_volume | |
| creator | Combs, Roger J Knapp, Robert B Kroutil, Robert T Thomas, Mark J |
| description | The methodology for producing absorbance and transmittance spectra with a passive Fourier transform infrared (FT-IR) spectrometer from an industrial stack and blackbody source is demonstrated. The knowledge of the stack temperature is shown to be key in generating the single-beam spectral ratio of differences for removal of instrumental effects from the absorbance and transmittance spectra. The difference removes self emission (i.e., offset) terms, and the ratio eliminates the responsivity (i.e., gain) term. The experimental procedure for acquiring the interferograms and single-beam spectra is documented. The experimental results that are obtained for three types of industrial stack are presented in the form of summary graphs and tables. Representative spectral data are also furnished in the Appendixes. Stack target analytes in the study are sulfur dioxide, nitrous oxide, and ammonia. |
| format | Report |
| fullrecord | <record><control><sourceid>dtic_1RU</sourceid><recordid>TN_cdi_dtic_stinet_ADA387321</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ADA387321</sourcerecordid><originalsourceid>FETCH-dtic_stinet_ADA3873213</originalsourceid><addsrcrecordid>eNrjZPDwzEspLS4pykzMUQguSUzOVnAtS8wpTSzJzM9TCM8syVBwL8ovzUvRdUosTk1RCEgsLs4sS1VwC9H1DFIILkhNLinKz00tKarkYWBNS8wpTuWF0twMMm6uIc4euiklmcnxxSWZeakl8Y4ujsYW5sZGhsYEpAFZ6DDN</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>report</recordtype></control><display><type>report</type><title>Industrial Stack Evaluation With Ground-Based Passive FT-IR Spectrometry</title><source>DTIC Technical Reports</source><creator>Combs, Roger J ; Knapp, Robert B ; Kroutil, Robert T ; Thomas, Mark J</creator><creatorcontrib>Combs, Roger J ; Knapp, Robert B ; Kroutil, Robert T ; Thomas, Mark J ; EDGEWOOD CHEMICAL BIOLOGICAL CENTER ABERDEEN PROVING GROUND MD</creatorcontrib><description>The methodology for producing absorbance and transmittance spectra with a passive Fourier transform infrared (FT-IR) spectrometer from an industrial stack and blackbody source is demonstrated. The knowledge of the stack temperature is shown to be key in generating the single-beam spectral ratio of differences for removal of instrumental effects from the absorbance and transmittance spectra. The difference removes self emission (i.e., offset) terms, and the ratio eliminates the responsivity (i.e., gain) term. The experimental procedure for acquiring the interferograms and single-beam spectra is documented. The experimental results that are obtained for three types of industrial stack are presented in the form of summary graphs and tables. Representative spectral data are also furnished in the Appendixes. Stack target analytes in the study are sulfur dioxide, nitrous oxide, and ammonia.</description><language>eng</language><subject>AMMONIA DETECTION ; Atomic and Molecular Physics and Spectroscopy ; BEAMS(RADIATION) ; BLACKBODY RADIATION ; DIOXIDES ; EMISSION ; FOURIER TRANSFORMATION ; GRAPHS ; INDUSTRIES ; INFRARED RADIATION ; INTERFEROGRAMS ; NITROUS OXIDE ; NITROUS OXIDE EFFLUENTS ; Nuclear Instrumentation ; Optical Detection and Detectors ; PASSIVE SYSTEMS ; SPECTRA ; SPECTROMETERS ; STACKING ; SULFUR DIOXIDE EMISSIONS ; SULFUR OXIDES ; TARGETS ; TEMPERATURE ; TEST AND EVALUATION ; TRANSMITTANCE</subject><creationdate>2001</creationdate><rights>APPROVED FOR PUBLIC RELEASE</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,780,885,27567,27568</link.rule.ids><linktorsrc>$$Uhttps://apps.dtic.mil/sti/citations/ADA387321$$EView_record_in_DTIC$$FView_record_in_$$GDTIC$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Combs, Roger J</creatorcontrib><creatorcontrib>Knapp, Robert B</creatorcontrib><creatorcontrib>Kroutil, Robert T</creatorcontrib><creatorcontrib>Thomas, Mark J</creatorcontrib><creatorcontrib>EDGEWOOD CHEMICAL BIOLOGICAL CENTER ABERDEEN PROVING GROUND MD</creatorcontrib><title>Industrial Stack Evaluation With Ground-Based Passive FT-IR Spectrometry</title><description>The methodology for producing absorbance and transmittance spectra with a passive Fourier transform infrared (FT-IR) spectrometer from an industrial stack and blackbody source is demonstrated. The knowledge of the stack temperature is shown to be key in generating the single-beam spectral ratio of differences for removal of instrumental effects from the absorbance and transmittance spectra. The difference removes self emission (i.e., offset) terms, and the ratio eliminates the responsivity (i.e., gain) term. The experimental procedure for acquiring the interferograms and single-beam spectra is documented. The experimental results that are obtained for three types of industrial stack are presented in the form of summary graphs and tables. Representative spectral data are also furnished in the Appendixes. Stack target analytes in the study are sulfur dioxide, nitrous oxide, and ammonia.</description><subject>AMMONIA DETECTION</subject><subject>Atomic and Molecular Physics and Spectroscopy</subject><subject>BEAMS(RADIATION)</subject><subject>BLACKBODY RADIATION</subject><subject>DIOXIDES</subject><subject>EMISSION</subject><subject>FOURIER TRANSFORMATION</subject><subject>GRAPHS</subject><subject>INDUSTRIES</subject><subject>INFRARED RADIATION</subject><subject>INTERFEROGRAMS</subject><subject>NITROUS OXIDE</subject><subject>NITROUS OXIDE EFFLUENTS</subject><subject>Nuclear Instrumentation</subject><subject>Optical Detection and Detectors</subject><subject>PASSIVE SYSTEMS</subject><subject>SPECTRA</subject><subject>SPECTROMETERS</subject><subject>STACKING</subject><subject>SULFUR DIOXIDE EMISSIONS</subject><subject>SULFUR OXIDES</subject><subject>TARGETS</subject><subject>TEMPERATURE</subject><subject>TEST AND EVALUATION</subject><subject>TRANSMITTANCE</subject><fulltext>true</fulltext><rsrctype>report</rsrctype><creationdate>2001</creationdate><recordtype>report</recordtype><sourceid>1RU</sourceid><recordid>eNrjZPDwzEspLS4pykzMUQguSUzOVnAtS8wpTSzJzM9TCM8syVBwL8ovzUvRdUosTk1RCEgsLs4sS1VwC9H1DFIILkhNLinKz00tKarkYWBNS8wpTuWF0twMMm6uIc4euiklmcnxxSWZeakl8Y4ujsYW5sZGhsYEpAFZ6DDN</recordid><startdate>200101</startdate><enddate>200101</enddate><creator>Combs, Roger J</creator><creator>Knapp, Robert B</creator><creator>Kroutil, Robert T</creator><creator>Thomas, Mark J</creator><scope>1RU</scope><scope>BHM</scope></search><sort><creationdate>200101</creationdate><title>Industrial Stack Evaluation With Ground-Based Passive FT-IR Spectrometry</title><author>Combs, Roger J ; Knapp, Robert B ; Kroutil, Robert T ; Thomas, Mark J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-dtic_stinet_ADA3873213</frbrgroupid><rsrctype>reports</rsrctype><prefilter>reports</prefilter><language>eng</language><creationdate>2001</creationdate><topic>AMMONIA DETECTION</topic><topic>Atomic and Molecular Physics and Spectroscopy</topic><topic>BEAMS(RADIATION)</topic><topic>BLACKBODY RADIATION</topic><topic>DIOXIDES</topic><topic>EMISSION</topic><topic>FOURIER TRANSFORMATION</topic><topic>GRAPHS</topic><topic>INDUSTRIES</topic><topic>INFRARED RADIATION</topic><topic>INTERFEROGRAMS</topic><topic>NITROUS OXIDE</topic><topic>NITROUS OXIDE EFFLUENTS</topic><topic>Nuclear Instrumentation</topic><topic>Optical Detection and Detectors</topic><topic>PASSIVE SYSTEMS</topic><topic>SPECTRA</topic><topic>SPECTROMETERS</topic><topic>STACKING</topic><topic>SULFUR DIOXIDE EMISSIONS</topic><topic>SULFUR OXIDES</topic><topic>TARGETS</topic><topic>TEMPERATURE</topic><topic>TEST AND EVALUATION</topic><topic>TRANSMITTANCE</topic><toplevel>online_resources</toplevel><creatorcontrib>Combs, Roger J</creatorcontrib><creatorcontrib>Knapp, Robert B</creatorcontrib><creatorcontrib>Kroutil, Robert T</creatorcontrib><creatorcontrib>Thomas, Mark J</creatorcontrib><creatorcontrib>EDGEWOOD CHEMICAL BIOLOGICAL CENTER ABERDEEN PROVING GROUND MD</creatorcontrib><collection>DTIC Technical Reports</collection><collection>DTIC STINET</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Combs, Roger J</au><au>Knapp, Robert B</au><au>Kroutil, Robert T</au><au>Thomas, Mark J</au><aucorp>EDGEWOOD CHEMICAL BIOLOGICAL CENTER ABERDEEN PROVING GROUND MD</aucorp><format>book</format><genre>unknown</genre><ristype>RPRT</ristype><btitle>Industrial Stack Evaluation With Ground-Based Passive FT-IR Spectrometry</btitle><date>2001-01</date><risdate>2001</risdate><abstract>The methodology for producing absorbance and transmittance spectra with a passive Fourier transform infrared (FT-IR) spectrometer from an industrial stack and blackbody source is demonstrated. The knowledge of the stack temperature is shown to be key in generating the single-beam spectral ratio of differences for removal of instrumental effects from the absorbance and transmittance spectra. The difference removes self emission (i.e., offset) terms, and the ratio eliminates the responsivity (i.e., gain) term. The experimental procedure for acquiring the interferograms and single-beam spectra is documented. The experimental results that are obtained for three types of industrial stack are presented in the form of summary graphs and tables. Representative spectral data are also furnished in the Appendixes. Stack target analytes in the study are sulfur dioxide, nitrous oxide, and ammonia.</abstract><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext_linktorsrc |
| identifier | |
| ispartof | |
| issn | |
| language | eng |
| recordid | cdi_dtic_stinet_ADA387321 |
| source | DTIC Technical Reports |
| subjects | AMMONIA DETECTION Atomic and Molecular Physics and Spectroscopy BEAMS(RADIATION) BLACKBODY RADIATION DIOXIDES EMISSION FOURIER TRANSFORMATION GRAPHS INDUSTRIES INFRARED RADIATION INTERFEROGRAMS NITROUS OXIDE NITROUS OXIDE EFFLUENTS Nuclear Instrumentation Optical Detection and Detectors PASSIVE SYSTEMS SPECTRA SPECTROMETERS STACKING SULFUR DIOXIDE EMISSIONS SULFUR OXIDES TARGETS TEMPERATURE TEST AND EVALUATION TRANSMITTANCE |
| title | Industrial Stack Evaluation With Ground-Based Passive FT-IR Spectrometry |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-19T16%3A56%3A35IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-dtic_1RU&rft_val_fmt=info:ofi/fmt:kev:mtx:book&rft.genre=unknown&rft.btitle=Industrial%20Stack%20Evaluation%20With%20Ground-Based%20Passive%20FT-IR%20Spectrometry&rft.au=Combs,%20Roger%20J&rft.aucorp=EDGEWOOD%20CHEMICAL%20BIOLOGICAL%20CENTER%20ABERDEEN%20PROVING%20GROUND%20MD&rft.date=2001-01&rft_id=info:doi/&rft_dat=%3Cdtic_1RU%3EADA387321%3C/dtic_1RU%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |