Poly(p-phenylene) Derivatives New High Performance Nonlinear Optical Polymers
NLO polymers (NLOPS) based on the poly(p-phenylene) (PPP) backbone were prepared in the study. The thermal stability for the new materials is presented. The polymer displayed a Tg of 220 deg C. The TGA scan of the material indicated reasonable thermal stability to 300 deg C. A thin film of the mater...
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| creator | Wright, Michael E Toplikar, Edward G |
| description | NLO polymers (NLOPS) based on the poly(p-phenylene) (PPP) backbone were prepared in the study. The thermal stability for the new materials is presented. The polymer displayed a Tg of 220 deg C. The TGA scan of the material indicated reasonable thermal stability to 300 deg C. A thin film of the material was supported on a glass slide and heated at 200 deg C and monitored by UV-vis spectroscopy. These experiments indicated less than 10% loss of the absorption band due to the NLO-phore (i.e. chromophore) over a period of 24 h. NonLinear optical, Polymers, Conjugated polymers, Polyphenylenes. |
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The thermal stability for the new materials is presented. The polymer displayed a Tg of 220 deg C. The TGA scan of the material indicated reasonable thermal stability to 300 deg C. A thin film of the material was supported on a glass slide and heated at 200 deg C and monitored by UV-vis spectroscopy. These experiments indicated less than 10% loss of the absorption band due to the NLO-phore (i.e. chromophore) over a period of 24 h. NonLinear optical, Polymers, Conjugated polymers, Polyphenylenes.</description><language>eng</language><subject>ABSORPTION ; Atomic and Molecular Physics and Spectroscopy ; CHROMOPHORES ; COMPOSITE MATERIALS ; CONJUGATED ; GLASS ; HIGH PERFORMANCE ; MATERIALS ; NLO-PHORES ; NLOP ; NONLINEAR OPTICS ; Optics ; Organic Chemistry ; PHOTONICS ; Polymer Chemistry ; POLYMERS ; POLYPHENYLENES ; PPP BACKBONE ; SPECTROSCOPY ; THERMAL STABILITY ; THIN FILMS ; ULTRAVIOLET SPECTROSCOPY</subject><creationdate>1994</creationdate><rights>Approved for public release; distribution is unlimited.</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,780,885,27567,27568</link.rule.ids><linktorsrc>$$Uhttps://apps.dtic.mil/sti/citations/ADA280248$$EView_record_in_DTIC$$FView_record_in_$$GDTIC$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Wright, Michael E</creatorcontrib><creatorcontrib>Toplikar, Edward G</creatorcontrib><creatorcontrib>UTAH STATE UNIV LOGAN DEPT OF CHEMISTRY AND BIOCHEMISTRY</creatorcontrib><title>Poly(p-phenylene) Derivatives New High Performance Nonlinear Optical Polymers</title><description>NLO polymers (NLOPS) based on the poly(p-phenylene) (PPP) backbone were prepared in the study. The thermal stability for the new materials is presented. The polymer displayed a Tg of 220 deg C. The TGA scan of the material indicated reasonable thermal stability to 300 deg C. A thin film of the material was supported on a glass slide and heated at 200 deg C and monitored by UV-vis spectroscopy. These experiments indicated less than 10% loss of the absorption band due to the NLO-phore (i.e. chromophore) over a period of 24 h. NonLinear optical, Polymers, Conjugated polymers, Polyphenylenes.</description><subject>ABSORPTION</subject><subject>Atomic and Molecular Physics and Spectroscopy</subject><subject>CHROMOPHORES</subject><subject>COMPOSITE MATERIALS</subject><subject>CONJUGATED</subject><subject>GLASS</subject><subject>HIGH PERFORMANCE</subject><subject>MATERIALS</subject><subject>NLO-PHORES</subject><subject>NLOP</subject><subject>NONLINEAR OPTICS</subject><subject>Optics</subject><subject>Organic Chemistry</subject><subject>PHOTONICS</subject><subject>Polymer Chemistry</subject><subject>POLYMERS</subject><subject>POLYPHENYLENES</subject><subject>PPP BACKBONE</subject><subject>SPECTROSCOPY</subject><subject>THERMAL STABILITY</subject><subject>THIN FILMS</subject><subject>ULTRAVIOLET SPECTROSCOPY</subject><fulltext>true</fulltext><rsrctype>report</rsrctype><creationdate>1994</creationdate><recordtype>report</recordtype><sourceid>1RU</sourceid><recordid>eNrjZPANyM-p1CjQLchIzavMSc1L1VRwSS3KLEssySxLLVbwSy1X8MhMz1AISC1Kyy_KTcxLTlXwy8_LycxLTSxS8C8oyUxOzFEAGZKbWlTMw8CalphTnMoLpbkZZNxcQ5w9dFOA6uKLS4C6SuIdXRyNLAyMTCyMCUgDAJJGMwk</recordid><startdate>19940528</startdate><enddate>19940528</enddate><creator>Wright, Michael E</creator><creator>Toplikar, Edward G</creator><scope>1RU</scope><scope>BHM</scope></search><sort><creationdate>19940528</creationdate><title>Poly(p-phenylene) Derivatives New High Performance Nonlinear Optical Polymers</title><author>Wright, Michael E ; Toplikar, Edward G</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-dtic_stinet_ADA2802483</frbrgroupid><rsrctype>reports</rsrctype><prefilter>reports</prefilter><language>eng</language><creationdate>1994</creationdate><topic>ABSORPTION</topic><topic>Atomic and Molecular Physics and Spectroscopy</topic><topic>CHROMOPHORES</topic><topic>COMPOSITE MATERIALS</topic><topic>CONJUGATED</topic><topic>GLASS</topic><topic>HIGH PERFORMANCE</topic><topic>MATERIALS</topic><topic>NLO-PHORES</topic><topic>NLOP</topic><topic>NONLINEAR OPTICS</topic><topic>Optics</topic><topic>Organic Chemistry</topic><topic>PHOTONICS</topic><topic>Polymer Chemistry</topic><topic>POLYMERS</topic><topic>POLYPHENYLENES</topic><topic>PPP BACKBONE</topic><topic>SPECTROSCOPY</topic><topic>THERMAL STABILITY</topic><topic>THIN FILMS</topic><topic>ULTRAVIOLET SPECTROSCOPY</topic><toplevel>online_resources</toplevel><creatorcontrib>Wright, Michael E</creatorcontrib><creatorcontrib>Toplikar, Edward G</creatorcontrib><creatorcontrib>UTAH STATE UNIV LOGAN DEPT OF CHEMISTRY AND BIOCHEMISTRY</creatorcontrib><collection>DTIC Technical Reports</collection><collection>DTIC STINET</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Wright, Michael E</au><au>Toplikar, Edward G</au><aucorp>UTAH STATE UNIV LOGAN DEPT OF CHEMISTRY AND BIOCHEMISTRY</aucorp><format>book</format><genre>unknown</genre><ristype>RPRT</ristype><btitle>Poly(p-phenylene) Derivatives New High Performance Nonlinear Optical Polymers</btitle><date>1994-05-28</date><risdate>1994</risdate><abstract>NLO polymers (NLOPS) based on the poly(p-phenylene) (PPP) backbone were prepared in the study. The thermal stability for the new materials is presented. The polymer displayed a Tg of 220 deg C. The TGA scan of the material indicated reasonable thermal stability to 300 deg C. A thin film of the material was supported on a glass slide and heated at 200 deg C and monitored by UV-vis spectroscopy. These experiments indicated less than 10% loss of the absorption band due to the NLO-phore (i.e. chromophore) over a period of 24 h. NonLinear optical, Polymers, Conjugated polymers, Polyphenylenes.</abstract><oa>free_for_read</oa></addata></record> |
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| language | eng |
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| source | DTIC Technical Reports |
| subjects | ABSORPTION Atomic and Molecular Physics and Spectroscopy CHROMOPHORES COMPOSITE MATERIALS CONJUGATED GLASS HIGH PERFORMANCE MATERIALS NLO-PHORES NLOP NONLINEAR OPTICS Optics Organic Chemistry PHOTONICS Polymer Chemistry POLYMERS POLYPHENYLENES PPP BACKBONE SPECTROSCOPY THERMAL STABILITY THIN FILMS ULTRAVIOLET SPECTROSCOPY |
| title | Poly(p-phenylene) Derivatives New High Performance Nonlinear Optical Polymers |
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