Synthesis, Structure, and Properties of Anti-perovskite Nitrides Ca3MN, M=P,As,Sb,Bi,Ge,Sn, and Pb
A family of anti-perovskite nitrides of the formula Ca3MN, where M is a Group IV or a Group V element, is reported. Ca3BiN, synthesized by mixing and pressing powders of Ca3N2 and Bi into a pellet and subsequently heating the pellet at 1000 deg C in flowing, dry N2 gas, is prototypical of this famil...
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| creator | Chern, Ming Y Vennos, D A DiSalvo, F J |
| description | A family of anti-perovskite nitrides of the formula Ca3MN, where M is a Group IV or a Group V element, is reported. Ca3BiN, synthesized by mixing and pressing powders of Ca3N2 and Bi into a pellet and subsequently heating the pellet at 1000 deg C in flowing, dry N2 gas, is prototypical of this family of compounds. The bismuth in Ca3BiN has an uncommon oxidation state of 3- as suggested by the properties (semiconducting and diamagnetic) of the compound. The anionic bismuth can be substituted for by other trivalent anions Sb3-, As3-, and P3- as expected. The structure of Ca3AsN and Ca3PN are distorted from the simple cubic anti-perovskite cell at room temperature because of the small size of As3- and P3-. More interestingly, Ca3N2 also reacts with Ge, Sn, and Pb at 1300 deg C to form similar anti-perovskites, resulting in metallic phases and the unusual open shell oxidation state of 3- for the Group IV elements. |
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Ca3BiN, synthesized by mixing and pressing powders of Ca3N2 and Bi into a pellet and subsequently heating the pellet at 1000 deg C in flowing, dry N2 gas, is prototypical of this family of compounds. The bismuth in Ca3BiN has an uncommon oxidation state of 3- as suggested by the properties (semiconducting and diamagnetic) of the compound. The anionic bismuth can be substituted for by other trivalent anions Sb3-, As3-, and P3- as expected. The structure of Ca3AsN and Ca3PN are distorted from the simple cubic anti-perovskite cell at room temperature because of the small size of As3- and P3-. More interestingly, Ca3N2 also reacts with Ge, Sn, and Pb at 1300 deg C to form similar anti-perovskites, resulting in metallic phases and the unusual open shell oxidation state of 3- for the Group IV elements.</description><language>eng</language><subject>ANIONS ; ANTI-PEROVSKITES ; BISMUTH ; ELECTRICAL PROPERTIES ; Inorganic Chemistry ; MAGNETIC PROPERTIES ; METALS ; MIXING ; NITRIDES ; OXIDATION ; PELLETS ; PHASE ; ROOM TEMPERATURE ; SHELLS(STRUCTURAL FORMS) ; SOLID STATE COMPOUNDS ; SYNTHESIS</subject><creationdate>1991</creationdate><rights>Approved for public release; distribution is unlimited.</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,780,885,27567,27568</link.rule.ids><linktorsrc>$$Uhttps://apps.dtic.mil/sti/citations/ADA236589$$EView_record_in_DTIC$$FView_record_in_$$GDTIC$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Chern, Ming Y</creatorcontrib><creatorcontrib>Vennos, D A</creatorcontrib><creatorcontrib>DiSalvo, F J</creatorcontrib><creatorcontrib>CORNELL UNIV ITHACA NY DEPT OF CHEMISTRY</creatorcontrib><title>Synthesis, Structure, and Properties of Anti-perovskite Nitrides Ca3MN, M=P,As,Sb,Bi,Ge,Sn, and Pb</title><description>A family of anti-perovskite nitrides of the formula Ca3MN, where M is a Group IV or a Group V element, is reported. Ca3BiN, synthesized by mixing and pressing powders of Ca3N2 and Bi into a pellet and subsequently heating the pellet at 1000 deg C in flowing, dry N2 gas, is prototypical of this family of compounds. The bismuth in Ca3BiN has an uncommon oxidation state of 3- as suggested by the properties (semiconducting and diamagnetic) of the compound. The anionic bismuth can be substituted for by other trivalent anions Sb3-, As3-, and P3- as expected. The structure of Ca3AsN and Ca3PN are distorted from the simple cubic anti-perovskite cell at room temperature because of the small size of As3- and P3-. More interestingly, Ca3N2 also reacts with Ge, Sn, and Pb at 1300 deg C to form similar anti-perovskites, resulting in metallic phases and the unusual open shell oxidation state of 3- for the Group IV elements.</description><subject>ANIONS</subject><subject>ANTI-PEROVSKITES</subject><subject>BISMUTH</subject><subject>ELECTRICAL PROPERTIES</subject><subject>Inorganic Chemistry</subject><subject>MAGNETIC PROPERTIES</subject><subject>METALS</subject><subject>MIXING</subject><subject>NITRIDES</subject><subject>OXIDATION</subject><subject>PELLETS</subject><subject>PHASE</subject><subject>ROOM TEMPERATURE</subject><subject>SHELLS(STRUCTURAL FORMS)</subject><subject>SOLID STATE COMPOUNDS</subject><subject>SYNTHESIS</subject><fulltext>true</fulltext><rsrctype>report</rsrctype><creationdate>1991</creationdate><recordtype>report</recordtype><sourceid>1RU</sourceid><recordid>eNqFjLsOgkAQAGksjPoHFvsBSyPRSGFx4quBkJw94WCJG81hbhcT_14KeqvJZJKZR85-vT5IWBCshqHRIRBC7VsoQ_-moEwCfQfGK8ej9x95shIUrIHbsWV1khcI-aFEI2gdHhmvhNZPF7eMZl39ElpNXETry_me3eJWualE2ZNW5mQ2yW67T5M_-Qe4PDgc</recordid><startdate>19910530</startdate><enddate>19910530</enddate><creator>Chern, Ming Y</creator><creator>Vennos, D A</creator><creator>DiSalvo, F J</creator><scope>1RU</scope><scope>BHM</scope></search><sort><creationdate>19910530</creationdate><title>Synthesis, Structure, and Properties of Anti-perovskite Nitrides Ca3MN, M=P,As,Sb,Bi,Ge,Sn, and Pb</title><author>Chern, Ming Y ; Vennos, D A ; DiSalvo, F J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-dtic_stinet_ADA2365893</frbrgroupid><rsrctype>reports</rsrctype><prefilter>reports</prefilter><language>eng</language><creationdate>1991</creationdate><topic>ANIONS</topic><topic>ANTI-PEROVSKITES</topic><topic>BISMUTH</topic><topic>ELECTRICAL PROPERTIES</topic><topic>Inorganic Chemistry</topic><topic>MAGNETIC PROPERTIES</topic><topic>METALS</topic><topic>MIXING</topic><topic>NITRIDES</topic><topic>OXIDATION</topic><topic>PELLETS</topic><topic>PHASE</topic><topic>ROOM TEMPERATURE</topic><topic>SHELLS(STRUCTURAL FORMS)</topic><topic>SOLID STATE COMPOUNDS</topic><topic>SYNTHESIS</topic><toplevel>online_resources</toplevel><creatorcontrib>Chern, Ming Y</creatorcontrib><creatorcontrib>Vennos, D A</creatorcontrib><creatorcontrib>DiSalvo, F J</creatorcontrib><creatorcontrib>CORNELL UNIV ITHACA NY DEPT OF CHEMISTRY</creatorcontrib><collection>DTIC Technical Reports</collection><collection>DTIC STINET</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Chern, Ming Y</au><au>Vennos, D A</au><au>DiSalvo, F J</au><aucorp>CORNELL UNIV ITHACA NY DEPT OF CHEMISTRY</aucorp><format>book</format><genre>unknown</genre><ristype>RPRT</ristype><btitle>Synthesis, Structure, and Properties of Anti-perovskite Nitrides Ca3MN, M=P,As,Sb,Bi,Ge,Sn, and Pb</btitle><date>1991-05-30</date><risdate>1991</risdate><abstract>A family of anti-perovskite nitrides of the formula Ca3MN, where M is a Group IV or a Group V element, is reported. Ca3BiN, synthesized by mixing and pressing powders of Ca3N2 and Bi into a pellet and subsequently heating the pellet at 1000 deg C in flowing, dry N2 gas, is prototypical of this family of compounds. The bismuth in Ca3BiN has an uncommon oxidation state of 3- as suggested by the properties (semiconducting and diamagnetic) of the compound. The anionic bismuth can be substituted for by other trivalent anions Sb3-, As3-, and P3- as expected. The structure of Ca3AsN and Ca3PN are distorted from the simple cubic anti-perovskite cell at room temperature because of the small size of As3- and P3-. More interestingly, Ca3N2 also reacts with Ge, Sn, and Pb at 1300 deg C to form similar anti-perovskites, resulting in metallic phases and the unusual open shell oxidation state of 3- for the Group IV elements.</abstract><oa>free_for_read</oa></addata></record> |
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| subjects | ANIONS ANTI-PEROVSKITES BISMUTH ELECTRICAL PROPERTIES Inorganic Chemistry MAGNETIC PROPERTIES METALS MIXING NITRIDES OXIDATION PELLETS PHASE ROOM TEMPERATURE SHELLS(STRUCTURAL FORMS) SOLID STATE COMPOUNDS SYNTHESIS |
| title | Synthesis, Structure, and Properties of Anti-perovskite Nitrides Ca3MN, M=P,As,Sb,Bi,Ge,Sn, and Pb |
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