Sampling and Analysis of Organophosphorus Compounds on a Thermoelectric Cold Plate Using Fourier Transform Infrared Emission Spectroscopy

This report documents findings of work performed under U.S. Army Chemical Research, Development and Engineering Center (CRDEC) Contract No. DAAA15-86-0020, by contractor personnel in conjunction with CRDEC scientists. This research addressed the sampling of organophosphorus compounds from the air an...

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Hauptverfasser: Whitbeck, M R, Carlon, Hugh R, Allan, Craig R
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description This report documents findings of work performed under U.S. Army Chemical Research, Development and Engineering Center (CRDEC) Contract No. DAAA15-86-0020, by contractor personnel in conjunction with CRDEC scientists. This research addressed the sampling of organophosphorus compounds from the air and their detection using Fourier transform infrared (FTIR) techniques with computer-aided pattern recognition. Vapor samples from a thermoelectrically- cooled plate, typically used as a liquid aerosol collector, were examined to determine the feasibility of recording infrared emission spectra directly from the plate. A comparison of this method was made with gas chromatography/infrared (GC/IR) spectroscopy analysis of samples that were first removed from the plate. Keywords: Infrared, FTIR, Malathion, Infrared emission, Infrared spectra, Pattern recognition, Infrared transmittance, Cold mirror/plate. Prepared in collaboration with Nevada Univ., Reno.
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source DTIC Technical Reports
subjects ARMY RESEARCH
AS553
CHEMISTRY
COMPUTER APPLICATIONS
CONTRACTORS
DETECTION
EMISSION
EMISSION SPECTRA
FOURIER TRANSFORMATION
GAS CHROMATOGRAPHY
INFRARED RADIATION
INFRARED SPECTRA
Inorganic Chemistry
MALATHION
ORGANIC PHOSPHORUS COMPOUNDS
PATTERN RECOGNITION
PE62706A
RECORDING SYSTEMS
SAMPLING
SPECTROSCOPY
TRANSMITTANCE
VAPORS
title Sampling and Analysis of Organophosphorus Compounds on a Thermoelectric Cold Plate Using Fourier Transform Infrared Emission Spectroscopy
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