Synthesis, Structure, and Properties of Ca2ZnN2
We report the synthesis and physical properties of the new ternary nitride Ca2ZnN2 (calcium zinc nitride), prepared by the reaction of Ca3N2 and Zn in N2 gas at 680 C. The structure, determined by x-ray powder diffraction and refined by Rietveld profile analysis, is tetragonal (I 4/m m m) with a=3.5...
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