Thermolysis of 4-Methyl-4-phenyl Malonyl Peroxide: A New Oxygen Dependent Chemiluminescent Reaction

Thermolysis of 4-methyl-4-phenyl malonyl peroxide in acetonitrile is accelerated by electron donors, such as perylene. When both the perylene and oxygen are present in solution the reaction gives acetophenone and a small amount of light. Investigation of the mechanism of light generation reveals tha...

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Hauptverfasser:	Porter,Judith E, Schuster,Gary B
Format:	Report
Sprache:	eng
Schlagworte:	Acetonitrile Acetophenones Catalysis Chemiluminescence Cyclic compounds Electron donors Electron transfer Fragmentation Light Malonic acid Methyl radicals Organic Chemistry Oxygen Peroxide/4-methyl-4-phenyl malonyl Peroxides Peryene Phenyl radicals Physical Chemistry Pyrolysis Reaction kinetics Solutions(Mixtures) Tetroxides Thermochemistry Thermolysis WUNRO51616
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