Thermochemical Considerations in Self-Sustaining Synthesis of Refractory Compounds
Thermochemical relationships in synthesis of refractory compounds have been considered. The heat generated from elemental reactants in this synthesis process provides the thermal input for the gasless combustion process. Trends are shown that relate position of the elemental reactants in the periodi...
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Report |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext bestellen |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | |
| container_start_page | |
| container_title | |
| container_volume | |
| creator | Frankhouser,William L Sullivan,Stephen T |
| description | Thermochemical relationships in synthesis of refractory compounds have been considered. The heat generated from elemental reactants in this synthesis process provides the thermal input for the gasless combustion process. Trends are shown that relate position of the elemental reactants in the periodic table and gram molecular weight of the reacted products to a thermochemical potential factor (TPF). The TPF is obtained by dividing heat of reaction with adiabatic reaction temperature. Suggestions are made to perform laboratory scoping experiments with BeB2, ScH2, TiB2, and W2C to confirm the thermochemical relationships in self-sustaining synthesis. (Author)
Prepared in cooperation with Lawrence Livermore National Lab., Livermore, CA. |
| format | Report |
| fullrecord | <record><control><sourceid>dtic_1RU</sourceid><recordid>TN_cdi_dtic_stinet_ADA121254</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>ADA121254</sourcerecordid><originalsourceid>FETCH-dtic_stinet_ADA1212543</originalsourceid><addsrcrecordid>eNqFizEOwjAMALMwIOAHDPlAhxZ4QFVAzE33KkocYilxUOwO_T0d2JnupNPt1ThFqLm4CBmdTXooxOihWsHNNJI2kEJjFhaLhPTWZiWJwMi6BD1CqNZJqet25k9ZyPNR7YJNDKcfD-r8fEzDq_GCbmZBApn7e992bXe7Xv7kLzZTNcg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>report</recordtype></control><display><type>report</type><title>Thermochemical Considerations in Self-Sustaining Synthesis of Refractory Compounds</title><source>DTIC Technical Reports</source><creator>Frankhouser,William L ; Sullivan,Stephen T</creator><creatorcontrib>Frankhouser,William L ; Sullivan,Stephen T ; SYSTEM PLANNING CORP ARLINGTON VA</creatorcontrib><description>Thermochemical relationships in synthesis of refractory compounds have been considered. The heat generated from elemental reactants in this synthesis process provides the thermal input for the gasless combustion process. Trends are shown that relate position of the elemental reactants in the periodic table and gram molecular weight of the reacted products to a thermochemical potential factor (TPF). The TPF is obtained by dividing heat of reaction with adiabatic reaction temperature. Suggestions are made to perform laboratory scoping experiments with BeB2, ScH2, TiB2, and W2C to confirm the thermochemical relationships in self-sustaining synthesis. (Author)
Prepared in cooperation with Lawrence Livermore National Lab., Livermore, CA.</description><language>eng</language><subject>ADIABATIC CONDITIONS ; Atomic and Molecular Physics and Spectroscopy ; EXPERIMENTAL DATA ; HEAT OF REACTION ; LABORATORY TESTS ; MOLECULAR WEIGHT ; Organic Chemistry ; Refractory compounds ; REFRACTORY MATERIALS ; SELF OPERATION ; SYNTHESIS(CHEMISTRY) ; THERMAL PROPERTIES ; THERMOCHEMISTRY</subject><creationdate>1982</creationdate><rights>APPROVED FOR PUBLIC RELEASE</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,780,885,27567,27568</link.rule.ids><linktorsrc>$$Uhttps://apps.dtic.mil/sti/citations/ADA121254$$EView_record_in_DTIC$$FView_record_in_$$GDTIC$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Frankhouser,William L</creatorcontrib><creatorcontrib>Sullivan,Stephen T</creatorcontrib><creatorcontrib>SYSTEM PLANNING CORP ARLINGTON VA</creatorcontrib><title>Thermochemical Considerations in Self-Sustaining Synthesis of Refractory Compounds</title><description>Thermochemical relationships in synthesis of refractory compounds have been considered. The heat generated from elemental reactants in this synthesis process provides the thermal input for the gasless combustion process. Trends are shown that relate position of the elemental reactants in the periodic table and gram molecular weight of the reacted products to a thermochemical potential factor (TPF). The TPF is obtained by dividing heat of reaction with adiabatic reaction temperature. Suggestions are made to perform laboratory scoping experiments with BeB2, ScH2, TiB2, and W2C to confirm the thermochemical relationships in self-sustaining synthesis. (Author)
Prepared in cooperation with Lawrence Livermore National Lab., Livermore, CA.</description><subject>ADIABATIC CONDITIONS</subject><subject>Atomic and Molecular Physics and Spectroscopy</subject><subject>EXPERIMENTAL DATA</subject><subject>HEAT OF REACTION</subject><subject>LABORATORY TESTS</subject><subject>MOLECULAR WEIGHT</subject><subject>Organic Chemistry</subject><subject>Refractory compounds</subject><subject>REFRACTORY MATERIALS</subject><subject>SELF OPERATION</subject><subject>SYNTHESIS(CHEMISTRY)</subject><subject>THERMAL PROPERTIES</subject><subject>THERMOCHEMISTRY</subject><fulltext>true</fulltext><rsrctype>report</rsrctype><creationdate>1982</creationdate><recordtype>report</recordtype><sourceid>1RU</sourceid><recordid>eNqFizEOwjAMALMwIOAHDPlAhxZ4QFVAzE33KkocYilxUOwO_T0d2JnupNPt1ThFqLm4CBmdTXooxOihWsHNNJI2kEJjFhaLhPTWZiWJwMi6BD1CqNZJqet25k9ZyPNR7YJNDKcfD-r8fEzDq_GCbmZBApn7e992bXe7Xv7kLzZTNcg</recordid><startdate>198208</startdate><enddate>198208</enddate><creator>Frankhouser,William L</creator><creator>Sullivan,Stephen T</creator><scope>1RU</scope><scope>BHM</scope></search><sort><creationdate>198208</creationdate><title>Thermochemical Considerations in Self-Sustaining Synthesis of Refractory Compounds</title><author>Frankhouser,William L ; Sullivan,Stephen T</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-dtic_stinet_ADA1212543</frbrgroupid><rsrctype>reports</rsrctype><prefilter>reports</prefilter><language>eng</language><creationdate>1982</creationdate><topic>ADIABATIC CONDITIONS</topic><topic>Atomic and Molecular Physics and Spectroscopy</topic><topic>EXPERIMENTAL DATA</topic><topic>HEAT OF REACTION</topic><topic>LABORATORY TESTS</topic><topic>MOLECULAR WEIGHT</topic><topic>Organic Chemistry</topic><topic>Refractory compounds</topic><topic>REFRACTORY MATERIALS</topic><topic>SELF OPERATION</topic><topic>SYNTHESIS(CHEMISTRY)</topic><topic>THERMAL PROPERTIES</topic><topic>THERMOCHEMISTRY</topic><toplevel>online_resources</toplevel><creatorcontrib>Frankhouser,William L</creatorcontrib><creatorcontrib>Sullivan,Stephen T</creatorcontrib><creatorcontrib>SYSTEM PLANNING CORP ARLINGTON VA</creatorcontrib><collection>DTIC Technical Reports</collection><collection>DTIC STINET</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Frankhouser,William L</au><au>Sullivan,Stephen T</au><aucorp>SYSTEM PLANNING CORP ARLINGTON VA</aucorp><format>book</format><genre>unknown</genre><ristype>RPRT</ristype><btitle>Thermochemical Considerations in Self-Sustaining Synthesis of Refractory Compounds</btitle><date>1982-08</date><risdate>1982</risdate><abstract>Thermochemical relationships in synthesis of refractory compounds have been considered. The heat generated from elemental reactants in this synthesis process provides the thermal input for the gasless combustion process. Trends are shown that relate position of the elemental reactants in the periodic table and gram molecular weight of the reacted products to a thermochemical potential factor (TPF). The TPF is obtained by dividing heat of reaction with adiabatic reaction temperature. Suggestions are made to perform laboratory scoping experiments with BeB2, ScH2, TiB2, and W2C to confirm the thermochemical relationships in self-sustaining synthesis. (Author)
Prepared in cooperation with Lawrence Livermore National Lab., Livermore, CA.</abstract><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext_linktorsrc |
| identifier | |
| ispartof | |
| issn | |
| language | eng |
| recordid | cdi_dtic_stinet_ADA121254 |
| source | DTIC Technical Reports |
| subjects | ADIABATIC CONDITIONS Atomic and Molecular Physics and Spectroscopy EXPERIMENTAL DATA HEAT OF REACTION LABORATORY TESTS MOLECULAR WEIGHT Organic Chemistry Refractory compounds REFRACTORY MATERIALS SELF OPERATION SYNTHESIS(CHEMISTRY) THERMAL PROPERTIES THERMOCHEMISTRY |
| title | Thermochemical Considerations in Self-Sustaining Synthesis of Refractory Compounds |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-21T04%3A34%3A22IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-dtic_1RU&rft_val_fmt=info:ofi/fmt:kev:mtx:book&rft.genre=unknown&rft.btitle=Thermochemical%20Considerations%20in%20Self-Sustaining%20Synthesis%20of%20Refractory%20Compounds&rft.au=Frankhouser,William%20L&rft.aucorp=SYSTEM%20PLANNING%20CORP%20ARLINGTON%20VA&rft.date=1982-08&rft_id=info:doi/&rft_dat=%3Cdtic_1RU%3EADA121254%3C/dtic_1RU%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |