A Fluorine-19 NMR Study of Some Fluorotitanium(IV) Complexes. III
The stereochemistry of a number of titanium (IV) fluoride complexes has been studied by means of low temperature fluorine-19 nmr. The following systems are examined in this technical report: TiF4--TiBr4--2,6-Dimethylpyridine-N-oxide; TiF4--TiCl4--Dioxane; TiF4--TiCl4--Thioxane; TiF4--TiCl4--Dithiane...
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| description | The stereochemistry of a number of titanium (IV) fluoride complexes has been studied by means of low temperature fluorine-19 nmr. The following systems are examined in this technical report: TiF4--TiBr4--2,6-Dimethylpyridine-N-oxide; TiF4--TiCl4--Dioxane; TiF4--TiCl4--Thioxane; TiF4--TiCl4--Dithiane; TiF4--H2O--Chloroacetonitrile; TiF4--H2O--Methylal; TiF4--TiCl4--H2O--1,2-Dimethoxyethane; TiF4--TiBr4--H2O--1,2-Dimethoxyethane; Structural assignments as well as chemical shift and coupling constant data are presented for each observed complex. In the systems involving water, species containing hydroxyl groups could not be detected although hydrolysis was clearly indicated by the formation of a white precipitate. (Author)
See also report dated May 72, AD-744 496. |
| format | Report |
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See also report dated May 72, AD-744 496.</abstract><oa>free_for_read</oa></addata></record> |
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| subjects | ACETONITRILE ACETONITRILE/CHLORO ADDITION COMPOUNDS BROMIDES CHEMICAL SHIFTS(NUCLEAR MAGNETIC RESONANCE) CHLORIDES COMPLEX COMPOUNDS DIOXANES DITHIANES FLUORIDES HETEROCYCLIC COMPOUNDS HYDRATES HYDROLYSIS Inorganic Chemistry MOLECULAR STRUCTURE NUCLEAR MAGNETIC RESONANCE SOLUTIONS(MIXTURES) STEREOCHEMISTRY TITANIUM COMPOUNDS WATER |
| title | A Fluorine-19 NMR Study of Some Fluorotitanium(IV) Complexes. III |
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