Synthesis and Properties of Carbon Chain Polymers (Sintez i Svoistva Tsepnykh Polimerov Ugleroda)
A new allotropic modification of carbon, consisting of chains of two new crystalline forms -- polyine and cumulene, has been synthesized in a two stage process beginning with the oxidative polydehydro condensation of acetylene. The new substance differs from both graphite and diamond in having a hig...
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| creator | Sladkov,A. M Kasatochkin,V. I Kudryavtsev,Yu. P Korshak,V. V |
| description | A new allotropic modification of carbon, consisting of chains of two new crystalline forms -- polyine and cumulene, has been synthesized in a two stage process beginning with the oxidative polydehydro condensation of acetylene. The new substance differs from both graphite and diamond in having a higher heat capacity and a higher thermodynamic stability. Its molecular structure and properties are described. (Author)
Trans. of Akademiya Nauk SSSR. Izvestiya. Seriya Khimicheskaya, n12 p2697-2704 1968. |
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Trans. of Akademiya Nauk SSSR. Izvestiya. Seriya Khimicheskaya, n12 p2697-2704 1968.</abstract><oa>free_for_read</oa></addata></record> |
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| source | DTIC Technical Reports |
| subjects | CARBON CARBONIZATION CHEMICAL BONDS CRYSTAL STRUCTURE MOLECULAR STRUCTURE Polymer Chemistry POLYMERS SYNTHESIS(CHEMISTRY) THERMODYNAMICS TRANSLATIONS USSR |
| title | Synthesis and Properties of Carbon Chain Polymers (Sintez i Svoistva Tsepnykh Polimerov Ugleroda) |
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