Ion-Pair Yields and Kinetic Behavior of Free Charges in Nonpolar Liquids
Yields of Ph3C(+) were determined by microsecond and nanosecond pulse radiolysis of triphenylmethylchloride solutions in five solvents (n-hexane, cyclohexane, 2,2,4-trimethylpentane, carbon tetrachloride, and carbon disulfide). These yields are in excellent agreement with the ion-pair yields determi...
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Report |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext bestellen |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | |
| container_start_page | |
| container_title | |
| container_volume | |
| creator | Capellos,Christos |
| description | Yields of Ph3C(+) were determined by microsecond and nanosecond pulse radiolysis of triphenylmethylchloride solutions in five solvents (n-hexane, cyclohexane, 2,2,4-trimethylpentane, carbon tetrachloride, and carbon disulfide). These yields are in excellent agreement with the ion-pair yields determined for the same solvents by conductivity methods. In addition, the triphenylmethylchloride method allows measurements of rate constants for proton-transfer and ion-recombination reactions, as well as the study of the reactivity of model compounds of explosives, or explosives themselves, towards the positive charge. (Author) |
| format | Report |
| fullrecord | <record><control><sourceid>dtic_1RU</sourceid><recordid>TN_cdi_dtic_stinet_AD0715391</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>AD0715391</sourcerecordid><originalsourceid>FETCH-dtic_stinet_AD07153913</originalsourceid><addsrcrecordid>eNrjZPDwzM_TDUjMLFKIzEzNSSlWSMxLUfDOzEstyUxWcErNSCzLzC9SyE9TcCtKTVVwzkgsSk8tVsjMU_DLzyvIz0ksUvDJLCzNTCnmYWBNS8wpTuWF0twMMm6uIc4euilAk-KLS0BGxju6GJgbmhpbGhoTkAYA86Mv_w</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>report</recordtype></control><display><type>report</type><title>Ion-Pair Yields and Kinetic Behavior of Free Charges in Nonpolar Liquids</title><source>DTIC Technical Reports</source><creator>Capellos,Christos</creator><creatorcontrib>Capellos,Christos ; PICATINNY ARSENAL DOVER N J</creatorcontrib><description>Yields of Ph3C(+) were determined by microsecond and nanosecond pulse radiolysis of triphenylmethylchloride solutions in five solvents (n-hexane, cyclohexane, 2,2,4-trimethylpentane, carbon tetrachloride, and carbon disulfide). These yields are in excellent agreement with the ion-pair yields determined for the same solvents by conductivity methods. In addition, the triphenylmethylchloride method allows measurements of rate constants for proton-transfer and ion-recombination reactions, as well as the study of the reactivity of model compounds of explosives, or explosives themselves, towards the positive charge. (Author)</description><language>eng</language><subject>Ammunition and Explosives ; CARBONIUM IONS ; ELECTRON IRRADIATION ; ELECTROSTATIC FIELDS ; EXPLOSIONS ; EXPLOSIVES ; FREE RADICALS ; IONS ; PENTANE/2-2-4-TRIMETHYL ; Radiation and Nuclear Chemistry ; RADIATION CHEMISTRY ; RADIOLYSIS ; REACTION KINETICS ; SOLUTIONS(MIXTURES)</subject><creationdate>1970</creationdate><rights>APPROVED FOR PUBLIC RELEASE</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,776,881,27544,27545</link.rule.ids><linktorsrc>$$Uhttps://apps.dtic.mil/sti/citations/AD0715391$$EView_record_in_DTIC$$FView_record_in_$$GDTIC$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Capellos,Christos</creatorcontrib><creatorcontrib>PICATINNY ARSENAL DOVER N J</creatorcontrib><title>Ion-Pair Yields and Kinetic Behavior of Free Charges in Nonpolar Liquids</title><description>Yields of Ph3C(+) were determined by microsecond and nanosecond pulse radiolysis of triphenylmethylchloride solutions in five solvents (n-hexane, cyclohexane, 2,2,4-trimethylpentane, carbon tetrachloride, and carbon disulfide). These yields are in excellent agreement with the ion-pair yields determined for the same solvents by conductivity methods. In addition, the triphenylmethylchloride method allows measurements of rate constants for proton-transfer and ion-recombination reactions, as well as the study of the reactivity of model compounds of explosives, or explosives themselves, towards the positive charge. (Author)</description><subject>Ammunition and Explosives</subject><subject>CARBONIUM IONS</subject><subject>ELECTRON IRRADIATION</subject><subject>ELECTROSTATIC FIELDS</subject><subject>EXPLOSIONS</subject><subject>EXPLOSIVES</subject><subject>FREE RADICALS</subject><subject>IONS</subject><subject>PENTANE/2-2-4-TRIMETHYL</subject><subject>Radiation and Nuclear Chemistry</subject><subject>RADIATION CHEMISTRY</subject><subject>RADIOLYSIS</subject><subject>REACTION KINETICS</subject><subject>SOLUTIONS(MIXTURES)</subject><fulltext>true</fulltext><rsrctype>report</rsrctype><creationdate>1970</creationdate><recordtype>report</recordtype><sourceid>1RU</sourceid><recordid>eNrjZPDwzM_TDUjMLFKIzEzNSSlWSMxLUfDOzEstyUxWcErNSCzLzC9SyE9TcCtKTVVwzkgsSk8tVsjMU_DLzyvIz0ksUvDJLCzNTCnmYWBNS8wpTuWF0twMMm6uIc4euilAk-KLS0BGxju6GJgbmhpbGhoTkAYA86Mv_w</recordid><startdate>197011</startdate><enddate>197011</enddate><creator>Capellos,Christos</creator><scope>1RU</scope><scope>BHM</scope></search><sort><creationdate>197011</creationdate><title>Ion-Pair Yields and Kinetic Behavior of Free Charges in Nonpolar Liquids</title><author>Capellos,Christos</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-dtic_stinet_AD07153913</frbrgroupid><rsrctype>reports</rsrctype><prefilter>reports</prefilter><language>eng</language><creationdate>1970</creationdate><topic>Ammunition and Explosives</topic><topic>CARBONIUM IONS</topic><topic>ELECTRON IRRADIATION</topic><topic>ELECTROSTATIC FIELDS</topic><topic>EXPLOSIONS</topic><topic>EXPLOSIVES</topic><topic>FREE RADICALS</topic><topic>IONS</topic><topic>PENTANE/2-2-4-TRIMETHYL</topic><topic>Radiation and Nuclear Chemistry</topic><topic>RADIATION CHEMISTRY</topic><topic>RADIOLYSIS</topic><topic>REACTION KINETICS</topic><topic>SOLUTIONS(MIXTURES)</topic><toplevel>online_resources</toplevel><creatorcontrib>Capellos,Christos</creatorcontrib><creatorcontrib>PICATINNY ARSENAL DOVER N J</creatorcontrib><collection>DTIC Technical Reports</collection><collection>DTIC STINET</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Capellos,Christos</au><aucorp>PICATINNY ARSENAL DOVER N J</aucorp><format>book</format><genre>unknown</genre><ristype>RPRT</ristype><btitle>Ion-Pair Yields and Kinetic Behavior of Free Charges in Nonpolar Liquids</btitle><date>1970-11</date><risdate>1970</risdate><abstract>Yields of Ph3C(+) were determined by microsecond and nanosecond pulse radiolysis of triphenylmethylchloride solutions in five solvents (n-hexane, cyclohexane, 2,2,4-trimethylpentane, carbon tetrachloride, and carbon disulfide). These yields are in excellent agreement with the ion-pair yields determined for the same solvents by conductivity methods. In addition, the triphenylmethylchloride method allows measurements of rate constants for proton-transfer and ion-recombination reactions, as well as the study of the reactivity of model compounds of explosives, or explosives themselves, towards the positive charge. (Author)</abstract><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext_linktorsrc |
| identifier | |
| ispartof | |
| issn | |
| language | eng |
| recordid | cdi_dtic_stinet_AD0715391 |
| source | DTIC Technical Reports |
| subjects | Ammunition and Explosives CARBONIUM IONS ELECTRON IRRADIATION ELECTROSTATIC FIELDS EXPLOSIONS EXPLOSIVES FREE RADICALS IONS PENTANE/2-2-4-TRIMETHYL Radiation and Nuclear Chemistry RADIATION CHEMISTRY RADIOLYSIS REACTION KINETICS SOLUTIONS(MIXTURES) |
| title | Ion-Pair Yields and Kinetic Behavior of Free Charges in Nonpolar Liquids |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-06T08%3A26%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-dtic_1RU&rft_val_fmt=info:ofi/fmt:kev:mtx:book&rft.genre=unknown&rft.btitle=Ion-Pair%20Yields%20and%20Kinetic%20Behavior%20of%20Free%20Charges%20in%20Nonpolar%20Liquids&rft.au=Capellos,Christos&rft.aucorp=PICATINNY%20ARSENAL%20DOVER%20N%20J&rft.date=1970-11&rft_id=info:doi/&rft_dat=%3Cdtic_1RU%3EAD0715391%3C/dtic_1RU%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |