NON-EQUILIBRIUM KINETICS: EXPLICIT TIME-DEPENDENCE OF PERTURBED DISTRIBUTION FUNCTIONS AND AUTO-CORRELATION EXPRESSIONS
The explicit time dependence of perturbed distribution functions is considered for a chemically reacting dilute gas mixture. The solutions obtained for the distribution functions approach in time the normal solutions of a Chapman-Enskog perturbation treatment within a few mean free times, and provid...
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| creator | Kapral,Raymond Hudson,Suzanne Ross,John |
| description | The explicit time dependence of perturbed distribution functions is considered for a chemically reacting dilute gas mixture. The solutions obtained for the distribution functions approach in time the normal solutions of a Chapman-Enskog perturbation treatment within a few mean free times, and provide an auto-correlation expression for the first non-equilibrium correction to the rate coefficient for a bimolecular gas phase reaction. To illustrate the results, explicit solutions are obtained for two model systems. (Author)
Prepared in cooperation with Massachusetts Inst. of Tech., Cambridge. |
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Prepared in cooperation with Massachusetts Inst. of Tech., Cambridge.</description><subject>CHEMICAL EQUILIBRIUM</subject><subject>CHEMICAL REACTIONS</subject><subject>GASES</subject><subject>Physical Chemistry</subject><subject>REACTION KINETICS</subject><subject>SQUID PROJECT</subject><subject>STATISTICAL MECHANICS</subject><fulltext>true</fulltext><rsrctype>report</rsrctype><creationdate>1970</creationdate><recordtype>report</recordtype><sourceid>1RU</sourceid><recordid>eNqFjDEKwkAQRdNYiHoDi7nAQkQhkm6zO8HBZDbuzoJdEI0QEJsEvL5G7K3eh_d58-TFjhWeIlVUeIo1HIlRyIQc8NxUZEhAqEZlsUG2yAbBldCgl-gLtGApiKciCjmGMrKZRgDNFnQUp4zzHiv91Z-ixxCmwzKZ3S-PoVv9uEjWJYo5qNvYX9th7J_d2GqbZps02-23f_QbiwU3pA</recordid><startdate>197007</startdate><enddate>197007</enddate><creator>Kapral,Raymond</creator><creator>Hudson,Suzanne</creator><creator>Ross,John</creator><scope>1RU</scope><scope>BHM</scope></search><sort><creationdate>197007</creationdate><title>NON-EQUILIBRIUM KINETICS: EXPLICIT TIME-DEPENDENCE OF PERTURBED DISTRIBUTION FUNCTIONS AND AUTO-CORRELATION EXPRESSIONS</title><author>Kapral,Raymond ; Hudson,Suzanne ; Ross,John</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-dtic_stinet_AD07107483</frbrgroupid><rsrctype>reports</rsrctype><prefilter>reports</prefilter><language>eng</language><creationdate>1970</creationdate><topic>CHEMICAL EQUILIBRIUM</topic><topic>CHEMICAL REACTIONS</topic><topic>GASES</topic><topic>Physical Chemistry</topic><topic>REACTION KINETICS</topic><topic>SQUID PROJECT</topic><topic>STATISTICAL MECHANICS</topic><toplevel>online_resources</toplevel><creatorcontrib>Kapral,Raymond</creatorcontrib><creatorcontrib>Hudson,Suzanne</creatorcontrib><creatorcontrib>Ross,John</creatorcontrib><creatorcontrib>PURDUE UNIV LAFAYETTE IND PROJECT SQUID HEADQUARTERS</creatorcontrib><collection>DTIC Technical Reports</collection><collection>DTIC STINET</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Kapral,Raymond</au><au>Hudson,Suzanne</au><au>Ross,John</au><aucorp>PURDUE UNIV LAFAYETTE IND PROJECT SQUID HEADQUARTERS</aucorp><format>book</format><genre>unknown</genre><ristype>RPRT</ristype><btitle>NON-EQUILIBRIUM KINETICS: EXPLICIT TIME-DEPENDENCE OF PERTURBED DISTRIBUTION FUNCTIONS AND AUTO-CORRELATION EXPRESSIONS</btitle><date>1970-07</date><risdate>1970</risdate><abstract>The explicit time dependence of perturbed distribution functions is considered for a chemically reacting dilute gas mixture. The solutions obtained for the distribution functions approach in time the normal solutions of a Chapman-Enskog perturbation treatment within a few mean free times, and provide an auto-correlation expression for the first non-equilibrium correction to the rate coefficient for a bimolecular gas phase reaction. To illustrate the results, explicit solutions are obtained for two model systems. (Author)
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| source | DTIC Technical Reports |
| subjects | CHEMICAL EQUILIBRIUM CHEMICAL REACTIONS GASES Physical Chemistry REACTION KINETICS SQUID PROJECT STATISTICAL MECHANICS |
| title | NON-EQUILIBRIUM KINETICS: EXPLICIT TIME-DEPENDENCE OF PERTURBED DISTRIBUTION FUNCTIONS AND AUTO-CORRELATION EXPRESSIONS |
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