STUDIES IN THE THERMOCHEMISTRY OF BORON-CONTAINING MOLECULES

A high precision semi-micro aneroid isothermal calorimeter was developed and is described. It may be used to investigate the calorimetry of a wide range of reacting systems including those where one component is a gas. Its heat capacity is 100 cal deg to the -1 power and, in conjunction with its anc...

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Hauptverfasser:	Mackle,Henry, Frisch,Margaret A
Format:	Report
Sprache:	eng
Schlagworte:	ARSINES CALORIMETERS CHEMICAL BONDS COMPLEX COMPOUNDS DIBORANES GASES HEAT OF REACTION INSTRUMENTATION LABORATORY EQUIPMENT LIQUIDS PHOSPHINE PHOSPHINE/TRIPHENYL SOLIDS THERMOCHEMISTRY
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creator	Mackle,Henry Frisch,Margaret A
description	A high precision semi-micro aneroid isothermal calorimeter was developed and is described. It may be used to investigate the calorimetry of a wide range of reacting systems including those where one component is a gas. Its heat capacity is 100 cal deg to the -1 power and, in conjunction with its ancillary equipment, it is capable of measuring heat outputs of the order of ten calories with a precision of plus or minus 0.1%. It has been used to study the heats of addition of diborane to the following organic bases of the group V elements: Mono-, di-, and tri-phenyl phosphine; triphenyl arsine. The results are tabulated in detail in the main body report. (Author)
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It may be used to investigate the calorimetry of a wide range of reacting systems including those where one component is a gas. Its heat capacity is 100 cal deg to the -1 power and, in conjunction with its ancillary equipment, it is capable of measuring heat outputs of the order of ten calories with a precision of plus or minus 0.1%. It has been used to study the heats of addition of diborane to the following organic bases of the group V elements: Mono-, di-, and tri-phenyl phosphine; triphenyl arsine. The results are tabulated in detail in the main body report. 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It may be used to investigate the calorimetry of a wide range of reacting systems including those where one component is a gas. Its heat capacity is 100 cal deg to the -1 power and, in conjunction with its ancillary equipment, it is capable of measuring heat outputs of the order of ten calories with a precision of plus or minus 0.1%. It has been used to study the heats of addition of diborane to the following organic bases of the group V elements: Mono-, di-, and tri-phenyl phosphine; triphenyl arsine. The results are tabulated in detail in the main body report. (Author)</description><subject>ARSINES</subject><subject>CALORIMETERS</subject><subject>CHEMICAL BONDS</subject><subject>COMPLEX COMPOUNDS</subject><subject>DIBORANES</subject><subject>GASES</subject><subject>HEAT OF REACTION</subject><subject>INSTRUMENTATION</subject><subject>LABORATORY EQUIPMENT</subject><subject>LIQUIDS</subject><subject>PHOSPHINE</subject><subject>PHOSPHINE/TRIPHENYL</subject><subject>SOLIDS</subject><subject>THERMOCHEMISTRY</subject><fulltext>true</fulltext><rsrctype>report</rsrctype><creationdate>1963</creationdate><recordtype>report</recordtype><sourceid>1RU</sourceid><recordid>eNrjZLAJDgl18XQNVvD0UwjxcAXhIF9_Zw9XX8_gkKBIBX83BSf_IH8_XWd_vxBHTz9PP3cFX38fV-dQH9dgHgbWtMSc4lReKM3NIOPmGuLsoZtSkpkcX1ySmZdaEu_oYmBiZGJobGxMQBoAhLcm1A</recordid><startdate>19630831</startdate><enddate>19630831</enddate><creator>Mackle,Henry</creator><creator>Frisch,Margaret A</creator><scope>1RU</scope><scope>BHM</scope></search><sort><creationdate>19630831</creationdate><title>STUDIES IN THE THERMOCHEMISTRY OF BORON-CONTAINING MOLECULES</title><author>Mackle,Henry ; Frisch,Margaret A</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-dtic_stinet_AD04241333</frbrgroupid><rsrctype>reports</rsrctype><prefilter>reports</prefilter><language>eng</language><creationdate>1963</creationdate><topic>ARSINES</topic><topic>CALORIMETERS</topic><topic>CHEMICAL BONDS</topic><topic>COMPLEX COMPOUNDS</topic><topic>DIBORANES</topic><topic>GASES</topic><topic>HEAT OF REACTION</topic><topic>INSTRUMENTATION</topic><topic>LABORATORY EQUIPMENT</topic><topic>LIQUIDS</topic><topic>PHOSPHINE</topic><topic>PHOSPHINE/TRIPHENYL</topic><topic>SOLIDS</topic><topic>THERMOCHEMISTRY</topic><toplevel>online_resources</toplevel><creatorcontrib>Mackle,Henry</creatorcontrib><creatorcontrib>Frisch,Margaret A</creatorcontrib><creatorcontrib>QUEEN'S UNIV BELFAST (NORTHERN IRELAND)</creatorcontrib><collection>DTIC Technical Reports</collection><collection>DTIC STINET</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Mackle,Henry</au><au>Frisch,Margaret A</au><aucorp>QUEEN'S UNIV BELFAST (NORTHERN IRELAND)</aucorp><format>book</format><genre>unknown</genre><ristype>RPRT</ristype><btitle>STUDIES IN THE THERMOCHEMISTRY OF BORON-CONTAINING MOLECULES</btitle><date>1963-08-31</date><risdate>1963</risdate><abstract>A high precision semi-micro aneroid isothermal calorimeter was developed and is described. 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subjects	ARSINES CALORIMETERS CHEMICAL BONDS COMPLEX COMPOUNDS DIBORANES GASES HEAT OF REACTION INSTRUMENTATION LABORATORY EQUIPMENT LIQUIDS PHOSPHINE PHOSPHINE/TRIPHENYL SOLIDS THERMOCHEMISTRY
title	STUDIES IN THE THERMOCHEMISTRY OF BORON-CONTAINING MOLECULES
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