Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis

Influence of bulky yet flexible N-heterocyclic carbene ligands in gold catalysis

Three new Au(I) complexes of the formula [Au(NHC)(NTf2)] (NHC = N-heterocyclic carbene) bearing bulky and flexible ligands have been synthesised. The ligands studied are IPent, IHept and INon which belong to the 'ITent' ('Tent' for 'tentacular') family of NHC derivative...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Beilstein journal of organic chemistry 2015-10, Vol.11 (1), p.1809-1814
Hauptverfasser: Collado, Alba, Patrick, Scott R, Gasperini, Danila, Meiries, Sebastien, Nolan, Steven P
Format: Artikel
Sprache:eng
Schlagworte:
catalysis
Chemistry
flexible and bulky ligands
Full Research Paper
gold
ligand design
N-heterocyclic carbenes
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Three new Au(I) complexes of the formula [Au(NHC)(NTf2)] (NHC = N-heterocyclic carbene) bearing bulky and flexible ligands have been synthesised. The ligands studied are IPent, IHept and INon which belong to the 'ITent' ('Tent' for 'tentacular') family of NHC derivatives. The effect of these ligands in gold-promoted transformations has been investigated.
ISSN:1860-5397
1860-5397
DOI:10.3762/bjoc.11.196