Synergistic Inhibition Effect of Chitosan and L-Cysteine for the Protection of Copper-Based Alloys against Atmospheric Chloride-Induced Indoor Corrosion

The protection of metals from atmospheric corrosion is a task of primary importance for many applications and many different products have been used, sometimes being toxic and harmful for health and the environment. In order to overcome drawbacks due to toxicity of the corrosion inhibitors and harmf...

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Veröffentlicht in:International journal of molecular sciences 2021-10, Vol.22 (19), p.10321, Article 10321
Hauptverfasser: Messina, Elena, Giuliani, Chiara, Pascucci, Marianna, Riccucci, Cristina, Staccioli, Maria Paola, Albini, Monica, Di Carlo, Gabriella
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Sprache:eng
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Zusammenfassung:The protection of metals from atmospheric corrosion is a task of primary importance for many applications and many different products have been used, sometimes being toxic and harmful for health and the environment. In order to overcome drawbacks due to toxicity of the corrosion inhibitors and harmful organic solvents and to ensure long-lasting protection, new organic compounds have been proposed and their corrosion inhibition properties have been investigated. In this work, we describe the use of a new environment-friendly anticorrosive coating that takes advantage of the synergism between an eco-friendly bio-polymer matrix and an amino acid. The corrosion inhibition of a largely used Copper-based (Cu-based) alloy against the chloride-induced indoor atmospheric attack was studied using chitosan (CH) as a biopolymer and l-Cysteine (Cy) as an amino acid. To evaluate the protective efficacy of the coatings, tailored accelerated corrosion tests were carried out on bare and coated Cu-based alloys, further, the nature of the protective film formed on the Cu-based alloy surface was analyzed by Fourier-transformed infrared spectroscopy (FTIR) while the surface modifications due to the corrosion treatments were investigated by optical microscopy (OM). The evaluation tests reveal that the Chitosan/l-Cysteine (CH/Cy) coatings exhibit good anti-corrosion properties against chloride attack whose efficiency increases with a minimum amount of Cy of 0.25 mg/mL.
ISSN:1661-6596
1422-0067
1422-0067
DOI:10.3390/ijms221910321