Study of the Hydrothermal-Catalytic Influence on the Oil-Bearing Rocks of the Usinskoye Oil Field
In this work, a synthesis of an oil-soluble iron-based catalyst precursor was carried out and its efficiency was tested in a laboratory simulation of the aquathermolysis process at different temperatures. The rocks of the Usinskoe field from the Permian deposits of the Komi Republic, obtained by ste...
Gespeichert in:
Veröffentlicht in: | Catalysts 2022-10, Vol.12 (10), p.1268 |
---|---|
Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | In this work, a synthesis of an oil-soluble iron-based catalyst precursor was carried out and its efficiency was tested in a laboratory simulation of the aquathermolysis process at different temperatures. The rocks of the Usinskoe field from the Permian deposits of the Komi Republic, obtained by steam-gravity drainage, and the iron-based catalyst precursor, as well as the products of non-catalytic and catalytic aquathermolysis, were selected as the object of study. As a result, it was found that the content of alkanes in the samples after thermal steam treatment (TST) at 300 °C increased 8-fold compared to the original oil, and the content of cycloalkanes in the sample with the catalyst increased 2-fold compared to the control experience. This may indicate that not only the carbon-heteroatom bonds (C-S, N, O) but also the C-C bonds were broken. It also shows that increasing the iron tallate concentration at TST 300 °C leads to a decrease in the molecular mass of the oil compared to the control experiment. According to SEM, the catalyst is nanodisperse particles with a size of ≈60–80 nm, which are adsorbed on the rock surface, catalyst removal occurs at a small scale. |
---|---|
ISSN: | 2073-4344 2073-4344 |
DOI: | 10.3390/catal12101268 |