Origin and chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta, Botswana
The origin and the chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta in semi-arid Botswana were investigated using DIC and major ion concentrations and stable oxygen, hydrogen and carbon isotopes (δD, δ18O and δ13CDIC). The δD and δ18O indicated...
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creator | Rawlings N. Akondi Atekwana, Eliot A. Loago Molwalefhe |
description | The origin and the chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta in semi-arid Botswana were investigated using DIC and major ion concentrations and stable oxygen, hydrogen and carbon isotopes (δD, δ18O and δ13CDIC). The δD and δ18O indicated that groundwater was recharged by evaporated river water and unevaporated rain. The river water and shallow ( |
doi_str_mv | 10.6084/m9.figshare.7480172 |
format | Dataset |
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Akondi ; Atekwana, Eliot A. ; Loago Molwalefhe</creator><creatorcontrib>Rawlings N. Akondi ; Atekwana, Eliot A. ; Loago Molwalefhe</creatorcontrib><description>The origin and the chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta in semi-arid Botswana were investigated using DIC and major ion concentrations and stable oxygen, hydrogen and carbon isotopes (δD, δ18O and δ13CDIC). The δD and δ18O indicated that groundwater was recharged by evaporated river water and unevaporated rain. The river water and shallow (<10 m) groundwater are Ca–Na–HCO3 type and the deep (≥10 m) groundwater is Na–K–HCO3 to HCO3–Cl–SO4 to Cl–SO4–HCO3. Compared to river water, the mean DIC concentrations were 2 times higher in shallow groundwater, 7 times higher in deep groundwater and 24 times higher in island groundwater. The δ13CDIC indicate that DIC production in groundwater is from organic matter oxidation and in island groundwater from organic matter oxidation and dissolution of sodium carbonate salts. The ionic and isotopic evolution of the groundwater relative to evaporated river water indicates two independent pools of DIC.</description><identifier>DOI: 10.6084/m9.figshare.7480172</identifier><language>eng</language><publisher>Taylor & Francis</publisher><subject>Biological Sciences not elsewhere classified ; Chemical Sciences not elsewhere classified ; Developmental Biology ; Ecology ; Environmental Sciences not elsewhere classified ; Evolutionary Biology ; FOS: Biological sciences ; FOS: Chemical sciences ; FOS: Earth and related environmental sciences ; Genetics ; Inorganic Chemistry ; Marine Biology ; Microbiology ; Molecular Biology ; Space Science</subject><creationdate>2018</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>776,1888</link.rule.ids><linktorsrc>$$Uhttps://commons.datacite.org/doi.org/10.6084/m9.figshare.7480172$$EView_record_in_DataCite.org$$FView_record_in_$$GDataCite.org$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Rawlings N. Akondi</creatorcontrib><creatorcontrib>Atekwana, Eliot A.</creatorcontrib><creatorcontrib>Loago Molwalefhe</creatorcontrib><title>Origin and chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta, Botswana</title><description>The origin and the chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta in semi-arid Botswana were investigated using DIC and major ion concentrations and stable oxygen, hydrogen and carbon isotopes (δD, δ18O and δ13CDIC). The δD and δ18O indicated that groundwater was recharged by evaporated river water and unevaporated rain. The river water and shallow (<10 m) groundwater are Ca–Na–HCO3 type and the deep (≥10 m) groundwater is Na–K–HCO3 to HCO3–Cl–SO4 to Cl–SO4–HCO3. Compared to river water, the mean DIC concentrations were 2 times higher in shallow groundwater, 7 times higher in deep groundwater and 24 times higher in island groundwater. The δ13CDIC indicate that DIC production in groundwater is from organic matter oxidation and in island groundwater from organic matter oxidation and dissolution of sodium carbonate salts. The ionic and isotopic evolution of the groundwater relative to evaporated river water indicates two independent pools of DIC.</description><subject>Biological Sciences not elsewhere classified</subject><subject>Chemical Sciences not elsewhere classified</subject><subject>Developmental Biology</subject><subject>Ecology</subject><subject>Environmental Sciences not elsewhere classified</subject><subject>Evolutionary Biology</subject><subject>FOS: Biological sciences</subject><subject>FOS: Chemical sciences</subject><subject>FOS: Earth and related environmental sciences</subject><subject>Genetics</subject><subject>Inorganic Chemistry</subject><subject>Marine Biology</subject><subject>Microbiology</subject><subject>Molecular Biology</subject><subject>Space Science</subject><fulltext>true</fulltext><rsrctype>dataset</rsrctype><creationdate>2018</creationdate><recordtype>dataset</recordtype><sourceid>PQ8</sourceid><recordid>eNo1kDtPwzAUhbMwoMIvYPEIEi2Ok9TOCC2PSpW6dI-OX6lFYleO24qB_04KZTr3nHPvHb4su8vpbE5F-dTXM-vaYYdoZrwUNOfsOvveRNc6T-A1UTvTO4Xu17ghpLB3iphj6A7JBU-CJdoNQ-iOZux9iC38uKAQ5djeL1eLhzEmbQwHr09IJp5P0s6QzSeO8G0gS9MlPJKXkIYTPG6yK4tuMLcXnWTbt9ft4mO63ryvFs_rqRY1m3LFrQCsLaFRspoyQ8fJSlaVAoWtwOZCGVlJgHIlUNGcMi1zDq6kLIpJVvy91UhQLplmH12P-NXktDmzafq6-WfTXNgUP_5aYyc</recordid><startdate>20181218</startdate><enddate>20181218</enddate><creator>Rawlings N. Akondi</creator><creator>Atekwana, Eliot A.</creator><creator>Loago Molwalefhe</creator><general>Taylor & Francis</general><scope>DYCCY</scope><scope>PQ8</scope></search><sort><creationdate>20181218</creationdate><title>Origin and chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta, Botswana</title><author>Rawlings N. Akondi ; Atekwana, Eliot A. ; Loago Molwalefhe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-d892-7c7f8aaff4ada42902e0adafb2548a3f5a268ceb5baa07c8a50102db17a7cbb33</frbrgroupid><rsrctype>datasets</rsrctype><prefilter>datasets</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Biological Sciences not elsewhere classified</topic><topic>Chemical Sciences not elsewhere classified</topic><topic>Developmental Biology</topic><topic>Ecology</topic><topic>Environmental Sciences not elsewhere classified</topic><topic>Evolutionary Biology</topic><topic>FOS: Biological sciences</topic><topic>FOS: Chemical sciences</topic><topic>FOS: Earth and related environmental sciences</topic><topic>Genetics</topic><topic>Inorganic Chemistry</topic><topic>Marine Biology</topic><topic>Microbiology</topic><topic>Molecular Biology</topic><topic>Space Science</topic><toplevel>online_resources</toplevel><creatorcontrib>Rawlings N. Akondi</creatorcontrib><creatorcontrib>Atekwana, Eliot A.</creatorcontrib><creatorcontrib>Loago Molwalefhe</creatorcontrib><collection>DataCite (Open Access)</collection><collection>DataCite</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Rawlings N. Akondi</au><au>Atekwana, Eliot A.</au><au>Loago Molwalefhe</au><format>book</format><genre>unknown</genre><ristype>DATA</ristype><title>Origin and chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta, Botswana</title><date>2018-12-18</date><risdate>2018</risdate><abstract>The origin and the chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta in semi-arid Botswana were investigated using DIC and major ion concentrations and stable oxygen, hydrogen and carbon isotopes (δD, δ18O and δ13CDIC). The δD and δ18O indicated that groundwater was recharged by evaporated river water and unevaporated rain. The river water and shallow (<10 m) groundwater are Ca–Na–HCO3 type and the deep (≥10 m) groundwater is Na–K–HCO3 to HCO3–Cl–SO4 to Cl–SO4–HCO3. Compared to river water, the mean DIC concentrations were 2 times higher in shallow groundwater, 7 times higher in deep groundwater and 24 times higher in island groundwater. The δ13CDIC indicate that DIC production in groundwater is from organic matter oxidation and in island groundwater from organic matter oxidation and dissolution of sodium carbonate salts. The ionic and isotopic evolution of the groundwater relative to evaporated river water indicates two independent pools of DIC.</abstract><pub>Taylor & Francis</pub><doi>10.6084/m9.figshare.7480172</doi><oa>free_for_read</oa></addata></record> |
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subjects | Biological Sciences not elsewhere classified Chemical Sciences not elsewhere classified Developmental Biology Ecology Environmental Sciences not elsewhere classified Evolutionary Biology FOS: Biological sciences FOS: Chemical sciences FOS: Earth and related environmental sciences Genetics Inorganic Chemistry Marine Biology Microbiology Molecular Biology Space Science |
title | Origin and chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta, Botswana |
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