Origin and chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta, Botswana

The origin and the chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta in semi-arid Botswana were investigated using DIC and major ion concentrations and stable oxygen, hydrogen and carbon isotopes (δD, δ18O and δ13CDIC). The δD and δ18O indicated...

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Atekwana, Eliot A.
Loago Molwalefhe
description The origin and the chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta in semi-arid Botswana were investigated using DIC and major ion concentrations and stable oxygen, hydrogen and carbon isotopes (δD, δ18O and δ13CDIC). The δD and δ18O indicated that groundwater was recharged by evaporated river water and unevaporated rain. The river water and shallow (
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Akondi ; Atekwana, Eliot A. ; Loago Molwalefhe</creator><creatorcontrib>Rawlings N. Akondi ; Atekwana, Eliot A. ; Loago Molwalefhe</creatorcontrib><description>The origin and the chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta in semi-arid Botswana were investigated using DIC and major ion concentrations and stable oxygen, hydrogen and carbon isotopes (δD, δ18O and δ13CDIC). The δD and δ18O indicated that groundwater was recharged by evaporated river water and unevaporated rain. The river water and shallow (&lt;10 m) groundwater are Ca–Na–HCO3 type and the deep (≥10 m) groundwater is Na–K–HCO3 to HCO3–Cl–SO4 to Cl–SO4–HCO3. Compared to river water, the mean DIC concentrations were 2 times higher in shallow groundwater, 7 times higher in deep groundwater and 24 times higher in island groundwater. The δ13CDIC indicate that DIC production in groundwater is from organic matter oxidation and in island groundwater from organic matter oxidation and dissolution of sodium carbonate salts. 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Akondi</creatorcontrib><creatorcontrib>Atekwana, Eliot A.</creatorcontrib><creatorcontrib>Loago Molwalefhe</creatorcontrib><collection>DataCite (Open Access)</collection><collection>DataCite</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Rawlings N. Akondi</au><au>Atekwana, Eliot A.</au><au>Loago Molwalefhe</au><format>book</format><genre>unknown</genre><ristype>DATA</ristype><title>Origin and chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta, Botswana</title><date>2018-12-18</date><risdate>2018</risdate><abstract>The origin and the chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta in semi-arid Botswana were investigated using DIC and major ion concentrations and stable oxygen, hydrogen and carbon isotopes (δD, δ18O and δ13CDIC). The δD and δ18O indicated that groundwater was recharged by evaporated river water and unevaporated rain. The river water and shallow (&lt;10 m) groundwater are Ca–Na–HCO3 type and the deep (≥10 m) groundwater is Na–K–HCO3 to HCO3–Cl–SO4 to Cl–SO4–HCO3. Compared to river water, the mean DIC concentrations were 2 times higher in shallow groundwater, 7 times higher in deep groundwater and 24 times higher in island groundwater. The δ13CDIC indicate that DIC production in groundwater is from organic matter oxidation and in island groundwater from organic matter oxidation and dissolution of sodium carbonate salts. The ionic and isotopic evolution of the groundwater relative to evaporated river water indicates two independent pools of DIC.</abstract><pub>Taylor &amp; Francis</pub><doi>10.6084/m9.figshare.7480172</doi><oa>free_for_read</oa></addata></record>
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identifier DOI: 10.6084/m9.figshare.7480172
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subjects Biological Sciences not elsewhere classified
Chemical Sciences not elsewhere classified
Developmental Biology
Ecology
Environmental Sciences not elsewhere classified
Evolutionary Biology
FOS: Biological sciences
FOS: Chemical sciences
FOS: Earth and related environmental sciences
Genetics
Inorganic Chemistry
Marine Biology
Microbiology
Molecular Biology
Space Science
title Origin and chemical and isotopic evolution of dissolved inorganic carbon (DIC) in groundwater of the Okavango Delta, Botswana
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