(Table 1) Kerogen geochemistry at DSDP Leg 64 Holes

Twenty-seven kerogen samples from the Guaymas Basin were examined to determine the effects of dolerite sill intrusions on recently deposited organic matter. ESR spin density and line width were observed to pass through maxima during the course of alteration. ESR g value, however, showed no correlati...

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Simoneit, Bernd R T
Philp, R P
description Twenty-seven kerogen samples from the Guaymas Basin were examined to determine the effects of dolerite sill intrusions on recently deposited organic matter. ESR spin density and line width were observed to pass through maxima during the course of alteration. ESR g value, however, showed no correlation with maturity. Rather surprisingly, d13C decreased by 1 to 1.5 per mil in the vicinity of the sills at Sites 477 and 481. In addition, atomic N/C decreased only slightly with proximity to a smaller sill at Site 478. Differences in maturation behavior between Sites 477 and 481 and Site 478 are attributed to dissimilarities in thermal stress and to the chemical and isotopic heterogeneity of Guaymas Basin protokerogen.
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ESR spin density and line width were observed to pass through maxima during the course of alteration. ESR g value, however, showed no correlation with maturity. Rather surprisingly, d13C decreased by 1 to 1.5 per mil in the vicinity of the sills at Sites 477 and 481. In addition, atomic N/C decreased only slightly with proximity to a smaller sill at Site 478. 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ESR spin density and line width were observed to pass through maxima during the course of alteration. ESR g value, however, showed no correlation with maturity. Rather surprisingly, d13C decreased by 1 to 1.5 per mil in the vicinity of the sills at Sites 477 and 481. In addition, atomic N/C decreased only slightly with proximity to a smaller sill at Site 478. 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ESR spin density and line width were observed to pass through maxima during the course of alteration. ESR g value, however, showed no correlation with maturity. Rather surprisingly, d13C decreased by 1 to 1.5 per mil in the vicinity of the sills at Sites 477 and 481. In addition, atomic N/C decreased only slightly with proximity to a smaller sill at Site 478. Differences in maturation behavior between Sites 477 and 481 and Site 478 are attributed to dissimilarities in thermal stress and to the chemical and isotopic heterogeneity of Guaymas Basin protokerogen.</abstract><pub>PANGAEA</pub><doi>10.1594/pangaea.819025</doi><oa>free_for_read</oa></addata></record>
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identifier DOI: 10.1594/pangaea.819025
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subjects Calculated
Calculated, see reference(s)
Carbon, total
Comment
Deep Sea Drilling Project (DSDP)
Depth, bottom/max
Depth, reconstructed
DEPTH, sediment/rock
Depth, top/min
Drilling/drill rig
DSDP/ODP/IODP sample designation
Elevation of event
Event label
Glomar Challenger
Hydrogen/Carbon ratio
Latitude of event
Leg64
Longitude of event
Mass spectrometer Varian MAT 250
Nitrogen/Carbon ratio
Sample code/label
Sample code/label 2
Sample ID
see reference(s)
Standard deviation
δ13C, kerogen
title (Table 1) Kerogen geochemistry at DSDP Leg 64 Holes
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