Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks
Altres ajuts: "la Caixa" Foundation (ID 100010434) Metal-organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and host species in solution and are permanently porous in solid-state. These characteristics, together with the recent development of their orthogonal sur...
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| creator | Khobotov Bakishev, Akim Hernández-López, Laura von Baeckmann, Cornelia Albalad, Jorge Carné-Sánchez, Arnau Maspoch Comamala, Daniel |
| description | Altres ajuts: "la Caixa" Foundation (ID 100010434)
Metal-organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and host species in solution and are permanently porous in solid-state. These characteristics, together with the recent development of their orthogonal surface chemistry and the assembly of more stable cages, have awakened the latent potential of MOPs to be used as building blocks for the synthesis of extended porous networks. This review article focuses on exploring the key developments that make the extension of MOPs possible, highlighting the most remarkable examples of MOP-based soft materials and crystalline extended frameworks. Finally, the article ventures to offer future perspectives on the exploitation of MOPs in fields that still remain ripe toward the use of such unorthodox molecular porous platforms. |
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Metal-organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and host species in solution and are permanently porous in solid-state. These characteristics, together with the recent development of their orthogonal surface chemistry and the assembly of more stable cages, have awakened the latent potential of MOPs to be used as building blocks for the synthesis of extended porous networks. This review article focuses on exploring the key developments that make the extension of MOPs possible, highlighting the most remarkable examples of MOP-based soft materials and crystalline extended frameworks. Finally, the article ventures to offer future perspectives on the exploitation of MOPs in fields that still remain ripe toward the use of such unorthodox molecular porous platforms.</description><language>eng</language><subject>Gels ; Membranes ; Metal-organic frameworks ; Metal-organic polyhedra ; Porous networks ; Reticular chemistry</subject><creationdate>2022</creationdate><rights>open access Aquest document està subjecte a una llicència d'ús Creative Commons. Es permet la reproducció total o parcial, la distribució, la comunicació pública de l'obra i la creació d'obres derivades, fins i tot amb finalitats comercials, sempre i quan es reconegui l'autoria de l'obra original. https://creativecommons.org/licenses/by/4.0</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,780,885,26974</link.rule.ids><linktorsrc>$$Uhttps://recercat.cat/handle/2072/527451$$EView_record_in_Consorci_de_Serveis_Universitaris_de_Catalunya_(CSUC)$$FView_record_in_$$GConsorci_de_Serveis_Universitaris_de_Catalunya_(CSUC)$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Khobotov Bakishev, Akim</creatorcontrib><creatorcontrib>Hernández-López, Laura</creatorcontrib><creatorcontrib>von Baeckmann, Cornelia</creatorcontrib><creatorcontrib>Albalad, Jorge</creatorcontrib><creatorcontrib>Carné-Sánchez, Arnau</creatorcontrib><creatorcontrib>Maspoch Comamala, Daniel</creatorcontrib><title>Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks</title><description>Altres ajuts: "la Caixa" Foundation (ID 100010434)
Metal-organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and host species in solution and are permanently porous in solid-state. These characteristics, together with the recent development of their orthogonal surface chemistry and the assembly of more stable cages, have awakened the latent potential of MOPs to be used as building blocks for the synthesis of extended porous networks. This review article focuses on exploring the key developments that make the extension of MOPs possible, highlighting the most remarkable examples of MOP-based soft materials and crystalline extended frameworks. Finally, the article ventures to offer future perspectives on the exploitation of MOPs in fields that still remain ripe toward the use of such unorthodox molecular porous platforms.</description><subject>Gels</subject><subject>Membranes</subject><subject>Metal-organic frameworks</subject><subject>Metal-organic polyhedra</subject><subject>Porous networks</subject><subject>Reticular chemistry</subject><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>XX2</sourceid><recordid>eNrjZHD3TS1JzNH1L0pPzMtMVgjIz6nMSE0pSlRILFZwKs3MScnMS1dwyslPzi5WSMsvAiooyi8tVnCtKEnNS0lNUfBLLSnPL8ou5mFgTUvMKU7lhdLcDIZuriHOHrrJxaXJ8UWpyalFyYkl8fmJmQgOCBsZmBvFmxqZm5gaGpOjBwALHUC6</recordid><startdate>2022</startdate><enddate>2022</enddate><creator>Khobotov Bakishev, Akim</creator><creator>Hernández-López, Laura</creator><creator>von Baeckmann, Cornelia</creator><creator>Albalad, Jorge</creator><creator>Carné-Sánchez, Arnau</creator><creator>Maspoch Comamala, Daniel</creator><scope>XX2</scope></search><sort><creationdate>2022</creationdate><title>Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks</title><author>Khobotov Bakishev, Akim ; Hernández-López, Laura ; von Baeckmann, Cornelia ; Albalad, Jorge ; Carné-Sánchez, Arnau ; Maspoch Comamala, Daniel</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-csuc_recercat_oai_recercat_cat_2072_5274513</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Gels</topic><topic>Membranes</topic><topic>Metal-organic frameworks</topic><topic>Metal-organic polyhedra</topic><topic>Porous networks</topic><topic>Reticular chemistry</topic><toplevel>online_resources</toplevel><creatorcontrib>Khobotov Bakishev, Akim</creatorcontrib><creatorcontrib>Hernández-López, Laura</creatorcontrib><creatorcontrib>von Baeckmann, Cornelia</creatorcontrib><creatorcontrib>Albalad, Jorge</creatorcontrib><creatorcontrib>Carné-Sánchez, Arnau</creatorcontrib><creatorcontrib>Maspoch Comamala, Daniel</creatorcontrib><collection>Recercat</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Khobotov Bakishev, Akim</au><au>Hernández-López, Laura</au><au>von Baeckmann, Cornelia</au><au>Albalad, Jorge</au><au>Carné-Sánchez, Arnau</au><au>Maspoch Comamala, Daniel</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks</atitle><date>2022</date><risdate>2022</risdate><abstract>Altres ajuts: "la Caixa" Foundation (ID 100010434)
Metal-organic polyhedra (MOPs) are a subclass of coordination cages that can adsorb and host species in solution and are permanently porous in solid-state. These characteristics, together with the recent development of their orthogonal surface chemistry and the assembly of more stable cages, have awakened the latent potential of MOPs to be used as building blocks for the synthesis of extended porous networks. This review article focuses on exploring the key developments that make the extension of MOPs possible, highlighting the most remarkable examples of MOP-based soft materials and crystalline extended frameworks. Finally, the article ventures to offer future perspectives on the exploitation of MOPs in fields that still remain ripe toward the use of such unorthodox molecular porous platforms.</abstract><oa>free_for_read</oa></addata></record> |
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| subjects | Gels Membranes Metal-organic frameworks Metal-organic polyhedra Porous networks Reticular chemistry |
| title | Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks |
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