A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets

An extended polypyrazolyl ligand has been used to assemble Mn ions into high spin entities, in the form of one stable molecule composed of two well defined clusters. The slow relaxation of the magnetisation observed is demonstrated to arise from each "half-SMM" composing this molecular clu...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (10), p.1413-1415
Hauptverfasser: Costa, José Sánchez, Barrios, Leoní A, Craig, Gavin A, Teat, Simon J, Luis, Fernando, Roubeau, Olivier, Evangelisti, Marco, Camón, Agustín, Aromí, Guillem
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container_end_page 1415
container_issue 10
container_start_page 1413
container_title Chemical communications (Cambridge, England)
container_volume 48
creator Costa, José Sánchez
Barrios, Leoní A
Craig, Gavin A
Teat, Simon J
Luis, Fernando
Roubeau, Olivier
Evangelisti, Marco
Camón, Agustín
Aromí, Guillem
description An extended polypyrazolyl ligand has been used to assemble Mn ions into high spin entities, in the form of one stable molecule composed of two well defined clusters. The slow relaxation of the magnetisation observed is demonstrated to arise from each "half-SMM" composing this molecular cluster pair.
doi_str_mv 10.1039/c1cc15682a
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source MEDLINE; Royal Society Of Chemistry Journals 2008-; Recercat; Alma/SFX Local Collection
subjects Clusters
Clústers metàl·lics
Composing
Imants
Ligands
Magnets
Magnets - chemistry
Manganese
Manganese - chemistry
Metal clusters
Metal Nanoparticles - chemistry
Models, Molecular
Molecular clusters
Molecular Structure
Nanocomposites
Nanomaterials
Nanostructure
Nanotechnology
Nanotecnologia
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Pyrazoles - chemistry
Temperature
title A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets
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