A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets
An extended polypyrazolyl ligand has been used to assemble Mn ions into high spin entities, in the form of one stable molecule composed of two well defined clusters. The slow relaxation of the magnetisation observed is demonstrated to arise from each "half-SMM" composing this molecular clu...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2012-01, Vol.48 (10), p.1413-1415 |
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container_title | Chemical communications (Cambridge, England) |
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creator | Costa, José Sánchez Barrios, Leoní A Craig, Gavin A Teat, Simon J Luis, Fernando Roubeau, Olivier Evangelisti, Marco Camón, Agustín Aromí, Guillem |
description | An extended polypyrazolyl ligand has been used to assemble Mn ions into high spin entities, in the form of one stable molecule composed of two well defined clusters. The slow relaxation of the magnetisation observed is demonstrated to arise from each "half-SMM" composing this molecular cluster pair. |
doi_str_mv | 10.1039/c1cc15682a |
format | Article |
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The slow relaxation of the magnetisation observed is demonstrated to arise from each "half-SMM" composing this molecular cluster pair.</description><subject>Clusters</subject><subject>Clústers metàl·lics</subject><subject>Composing</subject><subject>Imants</subject><subject>Ligands</subject><subject>Magnets</subject><subject>Magnets - chemistry</subject><subject>Manganese</subject><subject>Manganese - chemistry</subject><subject>Metal clusters</subject><subject>Metal Nanoparticles - chemistry</subject><subject>Models, Molecular</subject><subject>Molecular clusters</subject><subject>Molecular Structure</subject><subject>Nanocomposites</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Nanotechnology</subject><subject>Nanotecnologia</subject><subject>Organometallic Compounds - chemical synthesis</subject><subject>Organometallic Compounds - chemistry</subject><subject>Pyrazoles - chemistry</subject><subject>Temperature</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><sourceid>XX2</sourceid><recordid>eNp9kduK1EAQhhtZcWZHb3wAyd0uC9GuPqVzOYT1ACMiKAgiTaenMkQ66bG7wzpvb-KMemdBUQe-vyj4CXkO9CVQXr9y4BxIpZl9RNbAlSil0F-ull7WZcWFXJHrlL7TOUDqJ2TFGFCAmq7Jx20xBI9u8jYWX9-PIL4VLoS470eb-zAWzk8pYyw6tHmK_Xgo8kMokg8P_lRE9PbnshvtGAZ7GDGnp-RxZ33CZ5e6IZ9f339q3pa7D2_eNdtd6YTiuQTsUAg1FyH3CluugcnattWeou04zF9D5xirdCV1Na9aKbVUldOaCle3fEPgfNelyZmIDqOz2QTb_xuWZLRihkvKWD1rbs6aYww_JkzZDH1y6L0dMUzJ1KBASCHZTN7-lwSmeUWp0mpG7y6PxJBSxM4cYz_YeDJAzWKQaaBpfhu0neEXl7tTO-D-L_rHEf4LIi2Kmw</recordid><startdate>20120101</startdate><enddate>20120101</enddate><creator>Costa, José Sánchez</creator><creator>Barrios, Leoní A</creator><creator>Craig, Gavin A</creator><creator>Teat, Simon J</creator><creator>Luis, Fernando</creator><creator>Roubeau, Olivier</creator><creator>Evangelisti, Marco</creator><creator>Camón, Agustín</creator><creator>Aromí, Guillem</creator><general>Royal Society of Chemistry</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><scope>7X8</scope><scope>XX2</scope></search><sort><creationdate>20120101</creationdate><title>A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets</title><author>Costa, José Sánchez ; 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source | MEDLINE; Royal Society Of Chemistry Journals 2008-; Recercat; Alma/SFX Local Collection |
subjects | Clusters Clústers metàl·lics Composing Imants Ligands Magnets Magnets - chemistry Manganese Manganese - chemistry Metal clusters Metal Nanoparticles - chemistry Models, Molecular Molecular clusters Molecular Structure Nanocomposites Nanomaterials Nanostructure Nanotechnology Nanotecnologia Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Pyrazoles - chemistry Temperature |
title | A molecular [Mn14] coordination cluster featuring two slowly relaxing nanomagnets |
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