Influence of carbon content on microstructure and properties of a steel matrix cermet
There is a marked correlation between the composition, microstructure and properties in TiCN-based cermets. In the case of using iron alloys as metallic matrix the carbon content is of particular significance, as not only influences the stoichiometry of ceramic phase but also induces phase transform...
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Veröffentlicht in: | International journal of refractory metals & hard materials 2018-09, Vol.75, p.78-84 |
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creator | Alvaredo, P. Bruna, P. Crespo, D. Gordo, E. |
description | There is a marked correlation between the composition, microstructure and properties in TiCN-based cermets. In the case of using iron alloys as metallic matrix the carbon content is of particular significance, as not only influences the stoichiometry of ceramic phase but also induces phase transformations in the steel matrix. However, such influence has been less studied in steel matrix cermets than in conventional Ni or Co ones, so the aim of this work is to contribute to the study of the influence of carbon content on the microstructure and properties of a steel matrix cermet containing fixed quantities of alloying elements. Samples were prepared by powder metallurgy and characterized combining different techniques as Transmission Mössbauer spectroscopy (TMS), X Ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM), to explain differences found in hardness and toughness.
•Large increase in hardness and toughness by increasing carbon content.•Appearance of austenite and increase of martensite by increasing carbon content.•Presence of solid solution (Ti,M)(C,N) resembling the typical core-rim structure. |
doi_str_mv | 10.1016/j.ijrmhm.2018.04.006 |
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•Large increase in hardness and toughness by increasing carbon content.•Appearance of austenite and increase of martensite by increasing carbon content.•Presence of solid solution (Ti,M)(C,N) resembling the typical core-rim structure.</description><identifier>ISSN: 0263-4368</identifier><identifier>EISSN: 2213-3917</identifier><identifier>DOI: 10.1016/j.ijrmhm.2018.04.006</identifier><language>eng</language><publisher>Shrewsbury: Elsevier Ltd</publisher><subject>Alloying elements ; Carbon ; Carbon content ; Cermets ; Electron microscopy ; Enginyeria dels materials ; Fe Cermets ; Ferrous alloys ; Field emission microscopy ; Microscòpia electrònica ; Microscòpia electrònica de transmissió ; Microstructure ; Mossbauer spectroscopy ; Nickel ; Phase transitions ; Powder metallurgy ; Properties (attributes) ; Scanning electron microscopy ; Steel ; Stoichiometry ; TiCN ; Titanium carbonitride ; Transmission electron microscopy ; Transmission Mössbauer spectroscopy ; X-ray diffraction ; Àrees temàtiques de la UPC</subject><ispartof>International journal of refractory metals & hard materials, 2018-09, Vol.75, p.78-84</ispartof><rights>2018 Elsevier Ltd</rights><rights>Copyright Elsevier BV Sep 2018</rights><rights>info:eu-repo/semantics/openAccess</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c422t-71008d13137d8d799d6d8250e70831f5dad4cee603cd1cfaf61da37e07822fb13</citedby><cites>FETCH-LOGICAL-c422t-71008d13137d8d799d6d8250e70831f5dad4cee603cd1cfaf61da37e07822fb13</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0263436818301343$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3537,26951,27901,27902,65534</link.rule.ids></links><search><creatorcontrib>Alvaredo, P.</creatorcontrib><creatorcontrib>Bruna, P.</creatorcontrib><creatorcontrib>Crespo, D.</creatorcontrib><creatorcontrib>Gordo, E.</creatorcontrib><title>Influence of carbon content on microstructure and properties of a steel matrix cermet</title><title>International journal of refractory metals & hard materials</title><description>There is a marked correlation between the composition, microstructure and properties in TiCN-based cermets. In the case of using iron alloys as metallic matrix the carbon content is of particular significance, as not only influences the stoichiometry of ceramic phase but also induces phase transformations in the steel matrix. However, such influence has been less studied in steel matrix cermets than in conventional Ni or Co ones, so the aim of this work is to contribute to the study of the influence of carbon content on the microstructure and properties of a steel matrix cermet containing fixed quantities of alloying elements. Samples were prepared by powder metallurgy and characterized combining different techniques as Transmission Mössbauer spectroscopy (TMS), X Ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM), to explain differences found in hardness and toughness.
•Large increase in hardness and toughness by increasing carbon content.•Appearance of austenite and increase of martensite by increasing carbon content.•Presence of solid solution (Ti,M)(C,N) resembling the typical core-rim structure.</description><subject>Alloying elements</subject><subject>Carbon</subject><subject>Carbon content</subject><subject>Cermets</subject><subject>Electron microscopy</subject><subject>Enginyeria dels materials</subject><subject>Fe Cermets</subject><subject>Ferrous alloys</subject><subject>Field emission microscopy</subject><subject>Microscòpia electrònica</subject><subject>Microscòpia electrònica de transmissió</subject><subject>Microstructure</subject><subject>Mossbauer spectroscopy</subject><subject>Nickel</subject><subject>Phase transitions</subject><subject>Powder metallurgy</subject><subject>Properties (attributes)</subject><subject>Scanning electron microscopy</subject><subject>Steel</subject><subject>Stoichiometry</subject><subject>TiCN</subject><subject>Titanium carbonitride</subject><subject>Transmission electron microscopy</subject><subject>Transmission Mössbauer spectroscopy</subject><subject>X-ray diffraction</subject><subject>Àrees temàtiques de la UPC</subject><issn>0263-4368</issn><issn>2213-3917</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>XX2</sourceid><recordid>eNp9kEtLxDAUhYMoOD7-gYuA69abpJOkG0HEx4DgRtchJreYMm3HJBX996aM4M5FSALnnHvPR8gFg5oBk1d9Hfo4vA81B6ZraGoAeUBWnDNRiZapQ7ICLkXVCKmPyUlKPRRFK9mKvG7Gbjvj6JBOHXU2vk0jddOYccy0PIfg4pRynF2eI1I7erqL0w5jDpgWi6UpI27pYHMMX9RhHDCfkaPObhOe_96n5PX-7uX2sXp6ftjc3jxVruE8V4oBaM8EE8prr9rWS6_5GlCBFqxbe-sbhyhBOM9cZzvJvBUKQWnOuzcmTgnb57o0OxOxTHc2m8mGv89yOChuhJCgefFc7j2lx8eMKZt-muNY1iwyrVW75rwpquY3udRPETuzi2Gw8dswMAt005s9dLNAN9CYgrTYrvc2LK0_A0aTXFjo-lAWysZP4f-AH3e_jOQ</recordid><startdate>201809</startdate><enddate>201809</enddate><creator>Alvaredo, P.</creator><creator>Bruna, P.</creator><creator>Crespo, D.</creator><creator>Gordo, E.</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>XX2</scope></search><sort><creationdate>201809</creationdate><title>Influence of carbon content on microstructure and properties of a steel matrix cermet</title><author>Alvaredo, P. ; Bruna, P. ; Crespo, D. ; Gordo, E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-71008d13137d8d799d6d8250e70831f5dad4cee603cd1cfaf61da37e07822fb13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Alloying elements</topic><topic>Carbon</topic><topic>Carbon content</topic><topic>Cermets</topic><topic>Electron microscopy</topic><topic>Enginyeria dels materials</topic><topic>Fe Cermets</topic><topic>Ferrous alloys</topic><topic>Field emission microscopy</topic><topic>Microscòpia electrònica</topic><topic>Microscòpia electrònica de transmissió</topic><topic>Microstructure</topic><topic>Mossbauer spectroscopy</topic><topic>Nickel</topic><topic>Phase transitions</topic><topic>Powder metallurgy</topic><topic>Properties (attributes)</topic><topic>Scanning electron microscopy</topic><topic>Steel</topic><topic>Stoichiometry</topic><topic>TiCN</topic><topic>Titanium carbonitride</topic><topic>Transmission electron microscopy</topic><topic>Transmission Mössbauer spectroscopy</topic><topic>X-ray diffraction</topic><topic>Àrees temàtiques de la UPC</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Alvaredo, P.</creatorcontrib><creatorcontrib>Bruna, P.</creatorcontrib><creatorcontrib>Crespo, D.</creatorcontrib><creatorcontrib>Gordo, E.</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Recercat</collection><jtitle>International journal of refractory metals & hard materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Alvaredo, P.</au><au>Bruna, P.</au><au>Crespo, D.</au><au>Gordo, E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Influence of carbon content on microstructure and properties of a steel matrix cermet</atitle><jtitle>International journal of refractory metals & hard materials</jtitle><date>2018-09</date><risdate>2018</risdate><volume>75</volume><spage>78</spage><epage>84</epage><pages>78-84</pages><issn>0263-4368</issn><eissn>2213-3917</eissn><abstract>There is a marked correlation between the composition, microstructure and properties in TiCN-based cermets. In the case of using iron alloys as metallic matrix the carbon content is of particular significance, as not only influences the stoichiometry of ceramic phase but also induces phase transformations in the steel matrix. However, such influence has been less studied in steel matrix cermets than in conventional Ni or Co ones, so the aim of this work is to contribute to the study of the influence of carbon content on the microstructure and properties of a steel matrix cermet containing fixed quantities of alloying elements. Samples were prepared by powder metallurgy and characterized combining different techniques as Transmission Mössbauer spectroscopy (TMS), X Ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM), to explain differences found in hardness and toughness.
•Large increase in hardness and toughness by increasing carbon content.•Appearance of austenite and increase of martensite by increasing carbon content.•Presence of solid solution (Ti,M)(C,N) resembling the typical core-rim structure.</abstract><cop>Shrewsbury</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.ijrmhm.2018.04.006</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Alloying elements Carbon Carbon content Cermets Electron microscopy Enginyeria dels materials Fe Cermets Ferrous alloys Field emission microscopy Microscòpia electrònica Microscòpia electrònica de transmissió Microstructure Mossbauer spectroscopy Nickel Phase transitions Powder metallurgy Properties (attributes) Scanning electron microscopy Steel Stoichiometry TiCN Titanium carbonitride Transmission electron microscopy Transmission Mössbauer spectroscopy X-ray diffraction Àrees temàtiques de la UPC |
title | Influence of carbon content on microstructure and properties of a steel matrix cermet |
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