Intermatrix Synthesis of Polymer−Copper Nanocomposites with Tunable Parameters by Using Copper Comproportionation Reaction
This paper describes the synthesis of copper nanoparticles (NPs) inside sulfonated polyetherether ketone (SPEEK) membranes, which serve both as reaction media for intermatrix synthesis (IMS) of Cu-NPs and as stabilizing matrices, preventing NPs aggregation and uncontrollable growth. The IMS techniqu...
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| Veröffentlicht in: | Chemistry of materials 2010-12, Vol.22 (24), p.6616-6623 |
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| container_title | Chemistry of materials |
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| creator | Ruiz, Patricia Muñoz, María Macanás, Jorge Muraviev, Dmitri N. |
| description | This paper describes the synthesis of copper nanoparticles (NPs) inside sulfonated polyetherether ketone (SPEEK) membranes, which serve both as reaction media for intermatrix synthesis (IMS) of Cu-NPs and as stabilizing matrices, preventing NPs aggregation and uncontrollable growth. The IMS technique involves the loading of the functional groups of the polymer with metal ions followed by their reduction inside the polymeric matrix. It has been shown that the repetitive metal loading-reduction cycle, in the case of copper, is accompanied by comproportionation reaction between Cu0 and Cu2+, leading to the formation of Cu+ ions. This, in turn, allows for doubling the NPs content in the SPEEK matrix along with the tuning of Cu-NPs size. |
| doi_str_mv | 10.1021/cm102122c |
| format | Article |
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The IMS technique involves the loading of the functional groups of the polymer with metal ions followed by their reduction inside the polymeric matrix. It has been shown that the repetitive metal loading-reduction cycle, in the case of copper, is accompanied by comproportionation reaction between Cu0 and Cu2+, leading to the formation of Cu+ ions. This, in turn, allows for doubling the NPs content in the SPEEK matrix along with the tuning of Cu-NPs size.</description><identifier>ISSN: 0897-4756</identifier><identifier>EISSN: 1520-5002</identifier><identifier>DOI: 10.1021/cm102122c</identifier><language>eng</language><publisher>American Chemical Society</publisher><subject>Copper ; Coure ; Enginyeria dels materials ; Enginyeria química ; Ions metàl·lics ; Materials plàstics i polímers ; Metal ions ; Nanomaterials (Nanops, Nanotubes, etc.) ; Nanoparticles ; Nanopartícules ; Polymeric Materials ; Polymers ; Polímers ; Àrees temàtiques de la UPC</subject><ispartof>Chemistry of materials, 2010-12, Vol.22 (24), p.6616-6623</ispartof><rights>Copyright © 2010 American Chemical Society</rights><rights>info:eu-repo/semantics/openAccess</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a301t-7d56ff4f797f202b950f8049a3590c4ed956d5e2230206d59a149888b26b9e6f3</citedby><cites>FETCH-LOGICAL-a301t-7d56ff4f797f202b950f8049a3590c4ed956d5e2230206d59a149888b26b9e6f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/cm102122c$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/cm102122c$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,776,780,881,2752,26951,27053,27901,27902,56713,56763</link.rule.ids></links><search><creatorcontrib>Ruiz, Patricia</creatorcontrib><creatorcontrib>Muñoz, María</creatorcontrib><creatorcontrib>Macanás, Jorge</creatorcontrib><creatorcontrib>Muraviev, Dmitri N.</creatorcontrib><title>Intermatrix Synthesis of Polymer−Copper Nanocomposites with Tunable Parameters by Using Copper Comproportionation Reaction</title><title>Chemistry of materials</title><addtitle>Chem. Mater</addtitle><description>This paper describes the synthesis of copper nanoparticles (NPs) inside sulfonated polyetherether ketone (SPEEK) membranes, which serve both as reaction media for intermatrix synthesis (IMS) of Cu-NPs and as stabilizing matrices, preventing NPs aggregation and uncontrollable growth. The IMS technique involves the loading of the functional groups of the polymer with metal ions followed by their reduction inside the polymeric matrix. It has been shown that the repetitive metal loading-reduction cycle, in the case of copper, is accompanied by comproportionation reaction between Cu0 and Cu2+, leading to the formation of Cu+ ions. This, in turn, allows for doubling the NPs content in the SPEEK matrix along with the tuning of Cu-NPs size.</description><subject>Copper</subject><subject>Coure</subject><subject>Enginyeria dels materials</subject><subject>Enginyeria química</subject><subject>Ions metàl·lics</subject><subject>Materials plàstics i polímers</subject><subject>Metal ions</subject><subject>Nanomaterials (Nanops, Nanotubes, etc.)</subject><subject>Nanoparticles</subject><subject>Nanopartícules</subject><subject>Polymeric Materials</subject><subject>Polymers</subject><subject>Polímers</subject><subject>Àrees temàtiques de la UPC</subject><issn>0897-4756</issn><issn>1520-5002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>XX2</sourceid><recordid>eNptUMtKAzEUDaJgrS78g2xcuBi9yTyzlMFHoWjRdh0yaWJTOpMhSdEBP8C1n-iXOEOLblzce86Fcw7cg9A5gSsClFzLegBK5QEakZRClALQQzSCguVRkqfZMTrxfg1Ael0xQh-TJihXi-DMO37pmrBS3nhsNZ7ZTVcr9_35Vdq2VQ4_isZKW7fWm6A8fjNhhefbRlQbhWfCiVr1SR5XHV5407ziva3sLc621gVjGzEs_KyEHMgpOtJi49XZHsdocXc7Lx-i6dP9pLyZRiIGEqJ8mWZaJzpnuaZAK5aCLiBhIk4ZyEQtWZotU0VpDBR6xgRJWFEUFc0qpjIdjxHZ5Uq_ldwpqZwUgVth_o5hKOSUE0azLOk9l3uPs947pXnrTC1cxwnwoWP-W3WvvdhphfR8bbeu6b_5R_cDeNSAOQ</recordid><startdate>20101228</startdate><enddate>20101228</enddate><creator>Ruiz, Patricia</creator><creator>Muñoz, María</creator><creator>Macanás, Jorge</creator><creator>Muraviev, Dmitri N.</creator><general>American Chemical Society</general><scope>AAYXX</scope><scope>CITATION</scope><scope>XX2</scope></search><sort><creationdate>20101228</creationdate><title>Intermatrix Synthesis of Polymer−Copper Nanocomposites with Tunable Parameters by Using Copper Comproportionation Reaction</title><author>Ruiz, Patricia ; Muñoz, María ; Macanás, Jorge ; Muraviev, Dmitri N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a301t-7d56ff4f797f202b950f8049a3590c4ed956d5e2230206d59a149888b26b9e6f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Copper</topic><topic>Coure</topic><topic>Enginyeria dels materials</topic><topic>Enginyeria química</topic><topic>Ions metàl·lics</topic><topic>Materials plàstics i polímers</topic><topic>Metal ions</topic><topic>Nanomaterials (Nanops, Nanotubes, etc.)</topic><topic>Nanoparticles</topic><topic>Nanopartícules</topic><topic>Polymeric Materials</topic><topic>Polymers</topic><topic>Polímers</topic><topic>Àrees temàtiques de la UPC</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ruiz, Patricia</creatorcontrib><creatorcontrib>Muñoz, María</creatorcontrib><creatorcontrib>Macanás, Jorge</creatorcontrib><creatorcontrib>Muraviev, Dmitri N.</creatorcontrib><collection>CrossRef</collection><collection>Recercat</collection><jtitle>Chemistry of materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ruiz, Patricia</au><au>Muñoz, María</au><au>Macanás, Jorge</au><au>Muraviev, Dmitri N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Intermatrix Synthesis of Polymer−Copper Nanocomposites with Tunable Parameters by Using Copper Comproportionation Reaction</atitle><jtitle>Chemistry of materials</jtitle><addtitle>Chem. Mater</addtitle><date>2010-12-28</date><risdate>2010</risdate><volume>22</volume><issue>24</issue><spage>6616</spage><epage>6623</epage><pages>6616-6623</pages><issn>0897-4756</issn><eissn>1520-5002</eissn><abstract>This paper describes the synthesis of copper nanoparticles (NPs) inside sulfonated polyetherether ketone (SPEEK) membranes, which serve both as reaction media for intermatrix synthesis (IMS) of Cu-NPs and as stabilizing matrices, preventing NPs aggregation and uncontrollable growth. The IMS technique involves the loading of the functional groups of the polymer with metal ions followed by their reduction inside the polymeric matrix. It has been shown that the repetitive metal loading-reduction cycle, in the case of copper, is accompanied by comproportionation reaction between Cu0 and Cu2+, leading to the formation of Cu+ ions. This, in turn, allows for doubling the NPs content in the SPEEK matrix along with the tuning of Cu-NPs size.</abstract><pub>American Chemical Society</pub><doi>10.1021/cm102122c</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Chemistry of materials, 2010-12, Vol.22 (24), p.6616-6623 |
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| source | ACS Publications; Recercat |
| subjects | Copper Coure Enginyeria dels materials Enginyeria química Ions metàl·lics Materials plàstics i polímers Metal ions Nanomaterials (Nanops, Nanotubes, etc.) Nanoparticles Nanopartícules Polymeric Materials Polymers Polímers Àrees temàtiques de la UPC |
| title | Intermatrix Synthesis of Polymer−Copper Nanocomposites with Tunable Parameters by Using Copper Comproportionation Reaction |
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