Piezoelectric Properties of Sn-Doped (K,Na)NbO 3 Ceramics

It was previously reported that Ca-doped (K,Na)NbO 3 + ZrO 2 could be cofired with nickel inner electrodes in a reducing atmosphere. In the present study, the piezoelectric properties of Sn-doped (K,Na)NbO 3 + ZrO 2 ceramics were investigated. We prepared Sn-doped (K,Na)NbO 3 + ZrO 2 ceramics and Ca...

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Veröffentlicht in:Japanese Journal of Applied Physics 2013-09, Vol.52 (9S1), p.9
Hauptverfasser: Ishii, Hideki, Kawada, Shinichiro, Suzuki, Shoichiro, Honda, Atsushi, Higai, Shin'ichi, Hayashi, Hiroyuki, Okuzawa, Tadashi, Kimura, Masahiko, Omiya, Suetake, Kubodera, Noriyuki, Konoike, Takehiro
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container_issue 9S1
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container_title Japanese Journal of Applied Physics
container_volume 52
creator Ishii, Hideki
Kawada, Shinichiro
Suzuki, Shoichiro
Honda, Atsushi
Higai, Shin'ichi
Hayashi, Hiroyuki
Okuzawa, Tadashi
Kimura, Masahiko
Omiya, Suetake
Kubodera, Noriyuki
Konoike, Takehiro
description It was previously reported that Ca-doped (K,Na)NbO 3 + ZrO 2 could be cofired with nickel inner electrodes in a reducing atmosphere. In the present study, the piezoelectric properties of Sn-doped (K,Na)NbO 3 + ZrO 2 ceramics were investigated. We prepared Sn-doped (K,Na)NbO 3 + ZrO 2 ceramics and Ca-doped (K,Na)NbO 3 + ZrO 2 ceramics by doping with Sn 2+ and Ca 2+ under reducing calcination. The Curie temperature T c of the Sn-doped (K,Na)NbO 3 + ZrO 2 was 300 °C, which was the same as that of the Ca-doped (K,Na)NbO 3 + ZrO 2 . The tetragonal–orthorhombic phase transition temperature and piezoelectric constant d 33 of the Ca-doped (K,Na)NbO 3 + ZrO 2 were 130 °C and 130 pC/N while those of the Sn-doped (K,Na)NbO 3 + ZrO 2 were 50 °C and 190 pC/N, respectively. These results suggest that the piezoelectric d constant of (K,Na)NbO 3 -based multilayer ceramics with nickel inner electrodes can be increased by doping with Sn 2+ instead of Ca 2+ .
doi_str_mv 10.7567/JJAP.52.09KD06
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In the present study, the piezoelectric properties of Sn-doped (K,Na)NbO 3 + ZrO 2 ceramics were investigated. We prepared Sn-doped (K,Na)NbO 3 + ZrO 2 ceramics and Ca-doped (K,Na)NbO 3 + ZrO 2 ceramics by doping with Sn 2+ and Ca 2+ under reducing calcination. The Curie temperature T c of the Sn-doped (K,Na)NbO 3 + ZrO 2 was 300 °C, which was the same as that of the Ca-doped (K,Na)NbO 3 + ZrO 2 . The tetragonal–orthorhombic phase transition temperature and piezoelectric constant d 33 of the Ca-doped (K,Na)NbO 3 + ZrO 2 were 130 °C and 130 pC/N while those of the Sn-doped (K,Na)NbO 3 + ZrO 2 were 50 °C and 190 pC/N, respectively. 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title Piezoelectric Properties of Sn-Doped (K,Na)NbO 3 Ceramics
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