Progress of Non-Nucleophilic Electrolytes for Magnesium/Sulfur Battery
Non-nucleophilic magnesium electrolyte has attracted significant attention since the first non-nucleophilic organic aluminum magnesium salt with [Mg-2(mu-Cl)(3)(THF)(6)](+) as the cation of electrochemical active center for magnesium/sulfur (Mg/S) cells was reported by Muldoon group in 2011. In this...
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| Veröffentlicht in: | Hua hsüeh hsüeh pao 2021-05, Vol.79 (5), p.628-641 |
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| container_title | Hua hsüeh hsüeh pao |
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| creator | Li, Wanfei Li, Xin Fan, Haiyan Xiao, Jianhua Liu, Qianqian Cheng, Miao Hu, Jing Wei, Tao Wu, Zhengying Ling, Yun Liu, Bo Zhang, Yuegang |
| description | Non-nucleophilic magnesium electrolyte has attracted significant attention since the first non-nucleophilic organic aluminum magnesium salt with [Mg-2(mu-Cl)(3)(THF)(6)](+) as the cation of electrochemical active center for magnesium/sulfur (Mg/S) cells was reported by Muldoon group in 2011. In this work, we reviewed the synthesis, cation structure and electrochemical performance of non-nucleophilic magnesium electrolyte for Mg/S battery. The future research directions of non-nucleophilic Mg/S battery electrolyte are discussed. It is pointed out that in order to promote the industrialization of Mg/S battery, in addition to the development of non-nucleophilic electrolyte materials with high performance, low cost and simple structure, further mechanistic understanding for optimization of electrolyte composition and for better matching between the electrolyte with positive or negative electrode materials is also very important. |
| doi_str_mv | 10.6023/A21010038 |
| format | Article |
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In this work, we reviewed the synthesis, cation structure and electrochemical performance of non-nucleophilic magnesium electrolyte for Mg/S battery. The future research directions of non-nucleophilic Mg/S battery electrolyte are discussed. It is pointed out that in order to promote the industrialization of Mg/S battery, in addition to the development of non-nucleophilic electrolyte materials with high performance, low cost and simple structure, further mechanistic understanding for optimization of electrolyte composition and for better matching between the electrolyte with positive or negative electrode materials is also very important.</description><identifier>ISSN: 0567-7351</identifier><identifier>DOI: 10.6023/A21010038</identifier><language>eng</language><publisher>BEIJING: Science Press</publisher><subject>Chemistry ; Chemistry, Multidisciplinary ; Physical Sciences ; Science & Technology</subject><ispartof>Hua hsüeh hsüeh pao, 2021-05, Vol.79 (5), p.628-641</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>3</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000693686400007</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c194t-59524f557bd889f98ae2dc1348e7bfac4e247b1ba9b2a7a1ce808053958c10893</citedby><cites>FETCH-LOGICAL-c194t-59524f557bd889f98ae2dc1348e7bfac4e247b1ba9b2a7a1ce808053958c10893</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>315,781,785,27929,27930,39263</link.rule.ids></links><search><creatorcontrib>Li, Wanfei</creatorcontrib><creatorcontrib>Li, Xin</creatorcontrib><creatorcontrib>Fan, Haiyan</creatorcontrib><creatorcontrib>Xiao, Jianhua</creatorcontrib><creatorcontrib>Liu, Qianqian</creatorcontrib><creatorcontrib>Cheng, Miao</creatorcontrib><creatorcontrib>Hu, Jing</creatorcontrib><creatorcontrib>Wei, Tao</creatorcontrib><creatorcontrib>Wu, Zhengying</creatorcontrib><creatorcontrib>Ling, Yun</creatorcontrib><creatorcontrib>Liu, Bo</creatorcontrib><creatorcontrib>Zhang, Yuegang</creatorcontrib><title>Progress of Non-Nucleophilic Electrolytes for Magnesium/Sulfur Battery</title><title>Hua hsüeh hsüeh pao</title><addtitle>ACTA CHIM SINICA</addtitle><description>Non-nucleophilic magnesium electrolyte has attracted significant attention since the first non-nucleophilic organic aluminum magnesium salt with [Mg-2(mu-Cl)(3)(THF)(6)](+) as the cation of electrochemical active center for magnesium/sulfur (Mg/S) cells was reported by Muldoon group in 2011. In this work, we reviewed the synthesis, cation structure and electrochemical performance of non-nucleophilic magnesium electrolyte for Mg/S battery. The future research directions of non-nucleophilic Mg/S battery electrolyte are discussed. It is pointed out that in order to promote the industrialization of Mg/S battery, in addition to the development of non-nucleophilic electrolyte materials with high performance, low cost and simple structure, further mechanistic understanding for optimization of electrolyte composition and for better matching between the electrolyte with positive or negative electrode materials is also very important.</description><subject>Chemistry</subject><subject>Chemistry, Multidisciplinary</subject><subject>Physical Sciences</subject><subject>Science & Technology</subject><issn>0567-7351</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>HGBXW</sourceid><recordid>eNqNj0FLwzAYhnNQcMwd_Ae9itR9aZomOc6yqTCnoJ5Lmn2Zga4ZSYr03zuZ7OzpfQ_P88JLyA2F-woKNl8UFCgAkxdkArwSuWCcXpFZjK4FoBRKKeSErN6C3wWMMfM22_g-3wymQ3_4cp0z2bJDk4LvxoQxsz5kL3rXY3TDfv4-dHYI2YNOCcN4TS6t7iLO_nJKPlfLj_opX78-PteLdW6oKlPOFS9Ky7lot1Iqq6TGYmsoKyWK1mpTYlGKlrZatYUWmhqUIIEzxaWhIBWbktvTrgk-xoC2OQS312FsKDS_v5vz7yMrT-w3tt5G47A3eOYBoFKsklV5bCBql3Ryvq_90Kejevd_lf0AZRds6w</recordid><startdate>20210515</startdate><enddate>20210515</enddate><creator>Li, Wanfei</creator><creator>Li, Xin</creator><creator>Fan, Haiyan</creator><creator>Xiao, Jianhua</creator><creator>Liu, Qianqian</creator><creator>Cheng, Miao</creator><creator>Hu, Jing</creator><creator>Wei, Tao</creator><creator>Wu, Zhengying</creator><creator>Ling, Yun</creator><creator>Liu, Bo</creator><creator>Zhang, Yuegang</creator><general>Science Press</general><scope>BLEPL</scope><scope>DTL</scope><scope>HGBXW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20210515</creationdate><title>Progress of Non-Nucleophilic Electrolytes for Magnesium/Sulfur Battery</title><author>Li, Wanfei ; Li, Xin ; Fan, Haiyan ; Xiao, Jianhua ; Liu, Qianqian ; Cheng, Miao ; Hu, Jing ; Wei, Tao ; Wu, Zhengying ; Ling, Yun ; Liu, Bo ; Zhang, Yuegang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c194t-59524f557bd889f98ae2dc1348e7bfac4e247b1ba9b2a7a1ce808053958c10893</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemistry</topic><topic>Chemistry, Multidisciplinary</topic><topic>Physical Sciences</topic><topic>Science & Technology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Wanfei</creatorcontrib><creatorcontrib>Li, Xin</creatorcontrib><creatorcontrib>Fan, Haiyan</creatorcontrib><creatorcontrib>Xiao, Jianhua</creatorcontrib><creatorcontrib>Liu, Qianqian</creatorcontrib><creatorcontrib>Cheng, Miao</creatorcontrib><creatorcontrib>Hu, Jing</creatorcontrib><creatorcontrib>Wei, Tao</creatorcontrib><creatorcontrib>Wu, Zhengying</creatorcontrib><creatorcontrib>Ling, Yun</creatorcontrib><creatorcontrib>Liu, Bo</creatorcontrib><creatorcontrib>Zhang, Yuegang</creatorcontrib><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>Web of Science - Science Citation Index Expanded - 2021</collection><collection>CrossRef</collection><jtitle>Hua hsüeh hsüeh pao</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Wanfei</au><au>Li, Xin</au><au>Fan, Haiyan</au><au>Xiao, Jianhua</au><au>Liu, Qianqian</au><au>Cheng, Miao</au><au>Hu, Jing</au><au>Wei, Tao</au><au>Wu, Zhengying</au><au>Ling, Yun</au><au>Liu, Bo</au><au>Zhang, Yuegang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Progress of Non-Nucleophilic Electrolytes for Magnesium/Sulfur Battery</atitle><jtitle>Hua hsüeh hsüeh pao</jtitle><stitle>ACTA CHIM SINICA</stitle><date>2021-05-15</date><risdate>2021</risdate><volume>79</volume><issue>5</issue><spage>628</spage><epage>641</epage><pages>628-641</pages><issn>0567-7351</issn><abstract>Non-nucleophilic magnesium electrolyte has attracted significant attention since the first non-nucleophilic organic aluminum magnesium salt with [Mg-2(mu-Cl)(3)(THF)(6)](+) as the cation of electrochemical active center for magnesium/sulfur (Mg/S) cells was reported by Muldoon group in 2011. In this work, we reviewed the synthesis, cation structure and electrochemical performance of non-nucleophilic magnesium electrolyte for Mg/S battery. The future research directions of non-nucleophilic Mg/S battery electrolyte are discussed. It is pointed out that in order to promote the industrialization of Mg/S battery, in addition to the development of non-nucleophilic electrolyte materials with high performance, low cost and simple structure, further mechanistic understanding for optimization of electrolyte composition and for better matching between the electrolyte with positive or negative electrode materials is also very important.</abstract><cop>BEIJING</cop><pub>Science Press</pub><doi>10.6023/A21010038</doi><tpages>14</tpages><oa>free_for_read</oa></addata></record> |
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| source | Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" />; Wiley Online Library All Journals |
| subjects | Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology |
| title | Progress of Non-Nucleophilic Electrolytes for Magnesium/Sulfur Battery |
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